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arXiv:cond-mat/0501665

Consequences of the Pauli exclusion principle for the Bose-Einstein condensation of atoms and excitons

S. Rombouts, Lode Pollet, Kris Van Houcke

Published Jan 27, 2005• 0 citations
arXivHTMLPDF

Abstract

The bosonic atoms used in present day experiments on Bose-Einstein condensation are made up of fermionic electrons and nucleons. In this Letter we demonstrate how the Pauli exclusion principle for these constituents puts an upper limit on the Bose-Einstein-condensed fraction. Detailed numerical results are presented for hydrogen atoms in a cubic volume and for excitons in semiconductors and semiconductor bilayer systems. The resulting condensate depletion scales differently from what one expects for bosons with a repulsive hard-core interaction. At high densities, Pauli exclusion results in significantly more condensate depletion. These results also shed a new light on the low condensed fraction in liquid helium II.

DOI
10.48550/arxiv.cond-mat/0501665

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The bosonic atoms used in present day experiments on Bose-Einstein condensation are made up of fermionic electrons and nucleons. In this Letter we demonstrate how the Pauli exclusion principle for these constituents puts an upper limit on the Bose-Einstein-condensed fraction. Detailed numerical results are presented for hydrogen atoms in a cubic volume and for excitons in semiconductors and semiconductor bilayer systems. The resulting condensate depletion scales differently from what one expects for bosons with a repulsive hard-core interaction. At high densities, Pauli exclusion results in significantly more condensate depletion. These results also shed a new light on the low condensed fraction in liquid helium II.
Abstract This book bridges the gap between two major fields in condensed matter physics: semiconductors and superconductors. Through an original perspective that their key particles, excitons and Cooper pairs, are composite bosons (cobosons), the book raises fundamental questions: how does the Pauli exclusion principle affect the fermionic components of bosonic particles at the microscopic level, and how does this appear in the coboson many-body physics at the macroscopic level? What insights would the study of Wannier excitons, Frenkel excitons, and Cooper pairs provide about the “bosonic condensation” of composite bosons and how it differs from the Bose-Einstein condensation of elementary bosons? The book starts from a solid mathematical and physical foundation to derive excitons and Cooper pairs and introduces Shiva diagrams as a graphic support to grasp the many-body physics induced by fermion exchange in the absence of fermion-fermion interaction–a mechanism not visualized in standard Feynman diagrams. The book also covers composite bosons related to excitons: trions, biexcitons, and polaritons. The last part of the book is devoted to composite boson condensation, from the prototypical Bose-Einstein condensation of free elementary bosons and the consequence of interaction, to interacting electrons in the dense regime, to electron-hole pairs in the dense and dilute regimes. Advanced undergraduate and graduate students in physics, with no prior background, will benefit from this book, as numerous appendices provide the materials required to follow the various chapters. The concepts and formalism presented should also prove useful in research on ultracold atomic gases, polariton condensation, and quantum information.
This thesis is devoted to the rigorous study of dilute Bose gases with two-body and three-body interactions at zero temperature in two and three dimensions. Bose gases are many-body quantum systems composed of bosons, which notably do not obey the Pauli exclusion principle. As a consequence, at extremely low temperatures, a macroscopic fraction of the particles can occupy the same one-body quantum state. This phenomenon, known as Bose–Einstein condensation, was predicted in the 1920s by Bose and Einstein for noninteracting Bose gases, and first realised experimentally by the groups of Cornell and Wieman, and Ketterle, earning them the Nobel Prize for Physics in 2001. However, proving the occurrence of Bose–Einstein condensation in general interacting bosonic systems remains a major open problem and constitutes a central theme in this thesis. Another important property of bosonic matter is that it is generally more unstable than fermionic matter. In particular, for systems interacting via the Coulomb force, the Pauli exclusion principle is essential for explaining the stability of the second kind, which states that the energy and volume scale linearly with the number of particles. Nonetheless, bosonic systems with attractive but less singular interactions can also be stable, and the rigorous proof of this fact forms a second focus of this thesis. In three dimensions, we consider predominantly repulsive interactions. Firstly, we prove a leading order upper bound on the thermodynamic ground state energy of Bose gases with hard-core three-body interactions, which matches an existing lower bound. In addition, we obtain a simpler proof for integrable potentials. Secondly, we derive the leading order of the thermodynamic ground state energy of Bose gases with combined two-body and three-body interactions. More specifically, we show that, at the leading order, the ground state energy is entirely characterised by the scattering length of the two-body potential and the scattering hypervolume of the three-body potential. Thirdly, we study the time evolution of Bose–Einstein condensates with three-body interactions in the so-called Gross–Pitaevskii regime. We show that Bose–Einstein condensation is preserved under many-body evolution and that the condensate wavefunction evolves according to the quintic Gross–Pitaevskii equation. In particular, we show that the effective coupling constant is universal in the sense that it depends only on the scattering hypervolume of the interaction potential. As a by-product of our proof, we derive a stability of the second kind result for Bose gases with attractive two-body interactions and repulsive three-body interactions. In two dimensions, we consider trapped Bose gases with mean-field-type interactions, including the purely attractive case. We prove the stability of the second kind of the system and the convergence of the ground state energy per particle to that of a non-linear Schrödinger energy functional. As a consequence of the stability of the second kind, we also obtain Bose–Einstein condensation for the many-body ground states.
Any experimental realization of Bose-Einstein condensation (BEC) deals with composite bosons (cobosons), which are quasi-particles made of fermion pairs that suffer Pauli blocking. We evidence that the prime consequence of the Pauli exclusion principle is to prevent cobosons from having their centers of mass located at the same position within their spatial extension. We moreover predict a many-body effect induced by Pauli blocking that leads to high interference wave modes resulting from fermion exchanges between two colliding coboson condensates. These two effects can be detected by measuring spatial correlation functions. We here propose an original procedure to exactly derive such correlation functions for Frenkel-like cobosons characterized by just their momentum. We physically extend the obtained results to more complex Wannier-like cobosons that have an additional relative motion index. In addition to revealing the physics involved in results previously obtained for elementary boson condensates, we use Shiva diagrams to show how it is changed for cobosons. The predictions we here present, established for matter bosons, are directly applicable to experiments.
We consider the Bose-Einstein condensation of atoms in a trap where the density of particles is so high that the low-density approach of Gross [J. Math. Phys. (N.Y.) 4, 195 (1963)] and Pitaevskii (((V. L. Ginsburg and L. P. Pitaevskii, Zh. \'Eksp. Teor. Fiz. 34, 1240 (1958) [Sov. Phys. JETP 7, 1858 (1958)]))) will not be applicable. For this purpose we use the slave boson representation which is valid for hard-core bosons at any density. This description leads to the same results as the Gross-Pitaevskii approach in the low-density limit, but for higher densities, it predicts the depletion of the condensate in the regions where the density of the atomic cloud is high.
Bose-Einstein condensation of excitons is a unique effect in which the electronic states of a solid can self-organize to acquire quantum phase coherence. The phenomenon is closely linked to Bose-Einstein condensation in other systems such as liquid helium and laser-cooled atomic gases. This is the first book to provide a comprehensive survey of this field, covering theoretical aspects as well as recent experimental work. After setting out the relevant basic physics of excitons, the authors discuss exciton-phonon interactions as well as the behaviour of biexcitons. They cover exciton phase transitions and give particular attention to nonlinear optical effects including the optical Stark effect and chaos in excitonic systems. The thermodynamics of equilibrium, quasi-equilibrium, and nonequilibrium systems are examined in detail. The authors interweave theoretical and experimental results throughout the book, and it will be of great interest to graduate students and researchers in semiconductor and superconductor physics, quantum optics, and atomic physics.
The mathematical description of B.E. (Bose-Einstein) condensation is generalized so as to be applicable to a system of interacting particles. B.E. condensation is said to be present whenever the largest eigenvalue of the one-particle reduced density matrix is an extensive rather than an intensive quantity. Some transformations facilitating the practical use of this definition are given.An argument based on first principles is given, indicating that liquid belium II in equilibrium shows B.E. condensation. For absolute zero, the argument is based on properties of the ground-state wave function derived from the assumption that there is no "long-range configurational order." A crude estimate indicates that roughly 8% of the atoms are "condensed" (note that the fraction of condensed particles need not be identified with $\frac{{\ensuremath{\rho}}_{s}}{\ensuremath{\rho}}$). Conversely, it is shown why one would not expect B.E. condensation in a solid. For finite temperatures Feynman's theory of the lambda-transition is applied: Feynman's approximations are shown to imply that our criterion of B.E. condensation is satisfied below the lambda-transition but not above it.