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arXiv:cond-mat/0411745 · Computer Physics Communications

Resonating valence bond wave function: from lattice models to realistic systems

Michele Casula, Seiji Yunoki, Claudio Attaccalite, Sandro Sorella

Published Apr 16, 2005• 9 citations
arXivHTMLPDF
DOI
10.1016/j.cpc.2005.03.086

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We relate properties of nearest-neighbor resonating valence-bond (NNRVB) wave functions for SU(g)SU(g)SU(g) spin systems on two-dimensional bipartite lattices to those of fully packed interacting classical dimer models on the same lattice. The interaction energy can be expressed as a sum of nnn-body potentials Vn{V}_{n}Vn​, which are recursively determined from the NNRVB wave function on finite subgraphs of the original lattice. The magnitude of the nnn-body interaction Vn{V}_{n}Vn​ (n>1n>1n>1) is of order $\mathcal{O}({g}^{\ensuremath{-}(n\ensuremath{-}1)})$ for small ${g}^{\ensuremath{-}1}$. The leading term is a two-body nearest-neighbor interaction V2(g){V}_{2}(g)V2​(g) favoring two parallel dimers on elementary plaquettes. For SU(2)SU(2)SU(2) spins, using our calculated value of V2(g=2){V}_{2}(g=2)V2​(g=2), we find that the long-distance behavior of the bond-energy correlation function is dominated by an oscillatory term that decays as $1/|\stackrel{\ensuremath{\rightarrow}}{r}{|}^{\ensuremath{\alpha}}$ with $\ensuremath{\alpha}\ensuremath{\approx}1.22$. This result is in remarkable quantitative agreement with earlier direct numerical studies of the corresponding wave function, which give $\ensuremath{\alpha}\ensuremath{\approx}1.20$.
We study bond and spin correlations of the nearest-neighbor resonating valence bond (RVB) wave function for a SU(2) symmetric S=1/2S=1/2S=1/2 antiferromagnet on the honeycomb lattice. We find that spin correlations in this wave function are short ranged, while the bond energy correlation function takes on an oscillatory power-law form $D(\stackrel{P\vec}{r})\ensuremath{\sim}cos(\mathbf{Q}\ifmmode\cdot\else\textperiodcentered\fi{}\stackrel{P\vec}{r})/{|\stackrel{P\vec}{r}|}^{{\ensuremath{\eta}}_{w}(2)}$, where $\mathbf{Q}=(2\ensuremath{\pi}/3,\ensuremath{-}2\ensuremath{\pi}/3)$ is the wave vector corresponding to ``columnar'' valence-bond solid order on the honeycomb lattice, and ${\ensuremath{\eta}}_{w}(2)\ensuremath{\approx}1.49(3)$. We use a recently introduced large-ggg expansion approach to relate bond-energy correlators of the SU(g)\mathrm{SU}(g)SU(g) wave function to dimer correlations of an interacting fully packed dimer model with a three-dimer interaction of strength $V(g)=\ensuremath{-}ln(1+1/{g}^{2})$. Putting g=2g=2g=2, we find numerically that the dimer correlation function ${D}^{d}(\stackrel{P\vec}{r})$ of this dimer model has power-law behavior ${D}^{d}(\stackrel{P\vec}{r})\ensuremath{\sim}cos(\mathbf{Q}\ifmmode\cdot\else\textperiodcentered\fi{}\stackrel{P\vec}{r})/{|\stackrel{P\vec}{r}|}^{{\ensuremath{\eta}}_{d}(2)}$ with ${\ensuremath{\eta}}_{d}(2)\ensuremath{\approx}1.520(15)$, in rather good agreement with the wave function results. We also study the same quantities for g=3,4,10g=3,4,10g=3,4,10 and find that the bond-energy correlations in the SU(g)\mathrm{SU}(g)SU(g) wave function are consistently well reproduced by the corresponding dimer correlations in the interacting dimer model.