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arXiv:cond-mat/0410662 · Journal of Low Temperature Physics

Energy and Structure of Hard-Sphere Bose Gases in three and two dimensions

F. Mazzanti, A. Polls, A. Fabrocini

Published Feb 1, 2005• 0 citations
arXivHTMLPDF
DOI
10.1007/s10909-005-2295-y

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The energy and structure of dilute gases of hard spheres in three dimensions is discussed, together with some aspects of the corresponding 2D systems. A variational approach in the framework of the Hypernetted Chain Equations (HNC) is used starting from a Jastrow wavefunction that is optimized to produce the best two–body correlation factor with the appropriate long range. Relevant quantities describing static properties of the system are studied as a function of the gas parameter x = ρa d where ρ, a and d are the density, s–wave scattering length of the potential and dimensionality of the space, respectively. The occurrence of a maximum in the radial distribution function and in the momentum distribution is a natural effect of the correlations when x increases. Some aspects of the asymptotic behavior of the functions characterizing the structure of the systems are also investigated. PACS numbers: 03.75.Hh, 05.30.Jp, 67.40.Db. 1.
In this paper, we calculate the equations of state and the thermodynamic quantities for two- and three-dimensional hard-sphere Bose and Fermi gases in finite-size containers. The approach we used to deal with interacting gases is to convert the effect of interparticle hard-sphere interaction to a kind of boundary effect, and then the problem of a confined hard-sphere quantum gas is converted to the problem of a confined ideal quantum gas with a complex boundary. For this purpose, we first develop an approach for calculating the boundary effect on d-dimensional ideal quantum gases and then calculate the equation of state for confined quantum hard-sphere gases. The thermodynamic quantities and their low-temperature and high-density expansions are also given. In higher-order contributions, there are cross terms involving both the influences of the boundary and of the interparticle interaction. We compare the effect of the boundary and the effect of the interparticle interaction. Our result shows that, at low temperatures and high densities, the ratios of the effect of the boundary to the effect of the interparticle interaction in two dimensions are essentially different to those in three dimensions: in two dimensions, the ratios for Bose systems and for Fermi systems are the same and are independent of temperatures, while in three dimensions, the ratio for Bose systems depends on temperatures, but the ratio for Fermi systems is independent of temperatures. Moreover, for three-dimensional Fermi cases, compared with the contributions from the boundary, the contributions from the interparticle interaction to entropies and specific heats are negligible.
We prove the equivalence between the hard-sphere Bose gas and a system with momentum-dependent zero-range interactions in one spatial dimension, which we call extended hard-sphere Bose gas. The two-body interaction in the latter model has the advantage of being a regular pseudopotential. The most immediate consequence is the existence of its Fourier transform, permitting the formulation of the problem in momentum space, not possible with the original hard-core interaction. In addition, in the extended system, interactions are defined in terms of the scattering length, positive or negative, identified with the hard-sphere diameter only when it is positive. We are then able to obtain, directly in the thermodynamic limit, the ground-state energy of the strongly repulsive Lieb-Liniger gas and, more importantly, the energy of the lowest-lying super Tonks-Girardeau gas state with finite, strongly attractive interactions, in perturbation theory from the novel extended hard-sphere Bose gas.