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arXiv:cond-mat/0409578

Anomalous relaxation in quantum systems and the non-Markovian stochastic Liouville equation

Anatoly I. Shushin

Published Sep 22, 2004• 0 citations
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Abstract

The kinetics of relaxation in quantum systems induced by anomalous fluctuating noise is studied in detail. In this study two processes are considered, as examples: (1) relaxation in two-level system caused by external noise with slowly decaying correlation function P (t) ~ (wt)^{-alpha}, where 0 < alpha < 1, and (2) anomalous-diffusion controlled radical pair recombination in which relaxation results from the reaction with slowly fluctuating reaction rate whose fluctuations are governed by subdiffusive relative motion of radicals in a potential well. Analysis of these two processes is made within continuous time random walk approach (CTRWA). Rigorous CTRWA-treatment of the processes under study results in the non-Markovian stochastic Liouville equation (SLE) for the density matrix of the systems. This SLE predicts important specific features of relaxation kinetics of quantum systems in the presence of the above mentioned anomalous noise.

DOI
10.48550/arxiv.cond-mat/0409578

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The kinetics of relaxation in quantum systems induced by anomalous fluctuating noise is studied in detail. In this study two processes are considered, as examples: (1) relaxation in two-level system caused by external noise with slowly decaying correlation function P (t) ~ (wt)^{-alpha}, where 0 < alpha < 1, and (2) anomalous-diffusion controlled radical pair recombination in which relaxation results from the reaction with slowly fluctuating reaction rate whose fluctuations are governed by subdiffusive relative motion of radicals in a potential well. Analysis of these two processes is made within continuous time random walk approach (CTRWA). Rigorous CTRWA-treatment of the processes under study results in the non-Markovian stochastic Liouville equation (SLE) for the density matrix of the systems. This SLE predicts important specific features of relaxation kinetics of quantum systems in the presence of the above mentioned anomalous noise.
We analyze within the continuous-time random walk approach, the kinetics of phase and population relaxation in quantum systems induced by noise with the anomalously slowly decaying correlation function P ( t ) ∝ ( wt ) -α , where 0 < α < 1. The relaxation kinetics is shown to be anomalously slow. Moreover, for α < 1, in the limit of a short characteristic time of fluctuations w -1 , the kinetics is independent of w . As α → 1, the relaxation regime changes from the static limit to narrowing of fluctuation. Simple analytical expressions are obtained that describe the specific features of the kinetics.
Time evolution of a quantum system which is influenced by a stochastically fluctuating environment is studied by means of the stochastic Liouville equation. The two different types of the stochastic Liouville equation and their relation are discussed. The stochastic Liouville equation is shown to be derived from the quantum master equation of the Lindblad under certain conditions. Relaxation processes of single and bipartite quantum systems which are initially correlated with a stochastic environment are investigated. It is shown the possibility that the stochastic fluctuation can create coherence and entanglement of a quantum system with the assistance of the initial correlation. The results are examined in the pure dephasing processes of qubits, which are caused by the nonstationary Gauss-Markov process and two-state jump Markov process.
Half century has past since the pioneering works of Anderson and Kubo on the stochastic theory of spectral line shape were published in J. Phys. Soc. Jpn. 9 (1954) 316 and 935, respectively. In this review, we give an overview and extension of the stochastic Liouville equation focusing on its theoretical background and applications to help further the development of their works. With the aid of path integral formalism, we derive the stochastic Liouville equation for density matrices of a system. We then cast the equation into the hierarchy of equations which can be solved analytically or computationally in a nonperturbative manner including the effect of a colored noise. We elucidate the applications of the stochastic theory from the unified theoretical basis to analyze the dynamics of a system as probed by experiments. We illustrate this as a review of several experimental examples including NMR, dielectric relaxation, Mössbauer spectroscopy, neutron scattering, and linear and nonlinear laser spectroscopies. Following the summary of the advantage and limitation of the stochastic theory, we then derive a quantum Fokker–Planck equation and a quantum master equation from a system–bath Hamiltonian with a suitable spectral distribution producing a nearly Markovian random perturbation. By introducing auxiliary parameters that play a role as stochastic variables in an expression for reduced density matrix, we obtain the stochastic Liouville equation including temperature correction terms. The auxiliary parameters may also be interpreted as a random noise that allows us to derive a quantum Langevin equation for non-Markovian noise at any temperature. The results afford a basis for clarifying the relationship between the stochastic and dynamical approaches. Analytical as well as numerical calculations are given as examples and discussed.
Dynamical decoupling as a quantum control strategy aims at suppressing quantum decoherence adopting the popular philosophy that the disorder in the unitary evolution of the open quantum system caused by environmental noises should be neutralized by a sequence of ordered or well-designed external operations acting on the system. This work studies the solution of quantum-state-diffusion equations by mixing two channels of environmental noises, i.e., relaxation (dissipation) and dephasing. It is interesting to find in two-level and three-level atomic systems that a non-Markovian relaxation or dissipation process can be suppressed by a Markovian dephasing noise. The discovery results in an anomalous control strategy by coordinating relaxation and dephasing processes. Our approach opens an avenue of noise control strategy with no artificial manipulation over the open quantum systems.
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When a dynamical system has a perturbation which is considered as a stochastic process, the Liouville equation for the system in the phase space or the space of quantum-mechanical density operators is a sort of stochastic equation. The ensemble average of its formal integral defines the relaxation operator Φ(t) of the system. By the definition Φ(t) = exp K(t), the cumulant function K(t) may be introduced. Some general properties are first discussed for a simple example of an oscillator with random frequency modulation and then, concepts of slow and fast modulation are considered. These concepts can be generalized to more general types of stochastic Liouville equations. It is shown that by various possibilities of defining generalized exponential functions, this approach may be useful to understand some essential features of the problem from an unified point of view.