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arXiv:cond-mat/0408144 · Physical Review Letters

Spontaneous Dissociation of R85b Feshbach Molecules

Sarah T. Thompson, E. Hodby, Carl Wieman

Published Jan 18, 2005• 59 citations
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Abstract

The spontaneous dissociation of 85Rb dimers in the highest lying vibrational level has been observed in the vicinity of the Feshbach resonance that was used to produce them. The molecular lifetime shows a strong dependence on magnetic field, varying by 3 orders of magnitude between 155.5 G and 162.2 G. Our measurements are in good agreement with theoretical predictions in which molecular dissociation is driven by inelastic spin relaxation. Molecule lifetimes of tens of milliseconds can be achieved within approximately a 1 G wide region directly above the Feshbach resonance.

DOI
10.1103/physrevlett.94.020401

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The spontaneous dissociation of 85Rb dimers in the highest lying vibrational level has been observed in the vicinity of the Feshbach resonance that was used to produce them. The molecular lifetime shows a strong dependence on magnetic field, varying by 3 orders of magnitude between 155.5 G and 162.2 G. Our measurements are in good agreement with theoretical predictions in which molecular dissociation is driven by inelastic spin relaxation. Molecule lifetimes of tens of milliseconds can be achieved within approximately a 1 G wide region directly above the Feshbach resonance.
We study the spontaneous dissociation of diatomic molecules produced in cold atomic gases via magnetically tunable Feshbach resonances. We provide a universal formula for the lifetime of these molecules that relates their decay to the scattering length and the loss rate constant for inelastic spin relaxation. Our universal treatment as well as our exact coupled channels calculations for 85Rb dimers predict a suppression of the decay over several orders of magnitude when the scattering length is increased. Our predictions are in good agreement with recent measurements of the lifetime of 85Rb(2).
The variation of a magnetic field in the vicinity of a zero-energy resonance allows highly vibrationally excited molecules (‘Feshbach molecules’) to be produced from an ultracold atomic gas. In this thesis, we study the dynamics of this process. We begin by studying the dissociation of Feshbach molecules, showing that in the limit of a sudden jump the shape of the spectrum of dissociated atoms can act as a probe of the zero-energy resonance. For some resonances, such jumps are within reach of current experiments. We also study the intermediate region between sudden jumps and asymptotically wide, linear ramps. It is shown from a precise derivation how the latter limit leads to a universal spectrum with a shape independent of the implementation of the two-body physics, provided that the near-resonant scattering properties are correctly modelled. We then turn to the dynamics of Feshbach molecule production from thermal and condensed gases. Our microscopic quantum dynamics approach includes the exact twobody evolution as an input to the many-body calculations. We show that in the long-time limit, and the Markov limit for the interactions, the non-Markovian Boltzmann equation (NMBE) we derive for the one-body density matrix reduces to the normal Boltzmann equation. In the limit of short times and small depletion of the atomic gas, the molecule production efficiency can be calculated by thermally averaging the two-body transition probability density. This thermal averaging technique is applied to studies of the formation of Feshbach molecules using a magnetic field modulation that is near-resonant with the molecular bound state energy. The continuum is shown to have a significant effect on both the dynamics and efficiency of this process. We examine the dependence of the molecule production efficiency on the duration, amplitude and frequency of the modulation, as well as the temperature and density of the gas. This method of producing molecules is effective for a wide range of bound state energies, but requires sufficient variation of the two-body energy levels with magnetic field. Lastly, we implement the NMBE for the case of a fast linear ramp across a Feshbach resonance. The solution of this equation is made feasible by including a large part of the required computation in the kernel, which is calculated in advance. The NMBE allows predictions of the molecule production efficiency which go beyond the thermal averaging technique by accounting for the depletion and rethermalisation of the continuum. In the limit of small depletions, the two approaches give the same results. As the depletion increases, the two approaches differ due to many-body effects limiting the maximum possible molecule production efficiency. We have observed this in our simulations by considering higher-density gases. We have therefore shown the suitability and practicability of this beyond mean-field approach for application to further problems in the production of Feshbach molecules from ultracold gases.
Recent Feshbach-resonance experiments with 85Rb Bose-Einstein condensates have led to a host of unexplained results: dramatic losses of condensate atoms for an across-resonance sweep of the magnetic field, a collapsing condensate with a burst of atoms emanating from the remnant condensate, increased losses for decreasing interaction times, and coherent oscillations between remnant and burst atoms. Using a simple yet realistic mean-field model, we find that rogue dissociation, molecular dissociation to noncondensate atom pairs, is strongly implicated as the physical mechanism responsible for these observations.
The dissociation of ultracold molecules was studied by ramping an external magnetic field through a Feshbach resonance. The observed dissociation energies directly yielded the strength of the atom-molecule coupling. They showed nonlinear dependence on the ramp speed. This was explained by a Wigner threshold law which predicts that the decay rate of the molecules above threshold increases with the density of states. In addition, inelastic molecule-molecule and molecule-atom collisions were characterized.
Recent Feshbach-resonance experiments with 85Rb Bose-Einstein condensates have led to a host of unexplained results: dramatic losses of condensate atoms for an across-resonance sweep of the magnetic field, a collapsing condensate with a burst of atoms emanating from the remnant condensate, increased losses for decreasing interaction times--until very short times are reached, and coherent oscillations between remnant and burst atoms. In particular, the amplitude of the remnant-burst oscillations, and the corresponding missing atoms, have prompted speculation as to the formation of a molecular condensate. Using a minimal mean-field model, we find that rogue dissociation, molecular dissociation to noncondensate atom pairs, is qualitatively implicated as the physical mechanism responsible for these observations, although very little molecular condensate is formed. Refining the model provides excellent quantitative agreement with the experimental remnant-burst oscillations, and the fraction of molecular condensate accounts almost entirely for the measured atom loss.
We examine collective magnetoassociation of a Bose-Einstein condensate (BEC), focusing on rapid adiabatic passage from atoms to molecules induced by a sweep of the magnetic field across a wide (>~ 10 G) Feshbach resonance in 85Rb. This problem raises an interest because strong magnetoassociation is expected to favor the creation of molecular-dissociated atom pairs over the formation of molecular BEC [Javanainen and Mackie, Phys. Rev. Lett. 88, 090403 (2002)]. Nevertheless, the conversion to atom pairs is found to depend on the direction of the sweep, so that a system initially above threshold (open dissociation channel) may in fact give near-complete conversion to molecules.