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arXiv:cond-mat/0310460 · Comptes Rendus Physique

Bose–Einstein transition temperature in a dilute repulsive gas

Markus Holzmann, Jean-Noël Fuchs, Gordon Baym, Jean-Paul Blaizot, Franck Laloë

Published Jan 1, 2004• 34 citations

Abstract

We discuss certain specific features of the calculation of the critical temperature of a dilute repulsive Bose gas. Interactions modify the critical temperature in two different ways. First, for gases in traps, temperature shifts are introduced by a change of the density profile, arising itself from a modification of the equation of state of the gas (reduced compressibility); these shifts can be calculated simply within mean field theory. Second, even in the absence of a trapping potential (homogeneous gas in a box), temperature shifts are introduced by the interactions; they arise from the correlations introduced in the gas, and thus lie inherently beyond mean field theory – in fact, their evaluation requires more elaborate, non-perturbative, calculations. One illustration of this non-perturbative character is provided by the solution of self-consistent equations, which relate together non-linearly the various energy shifts of the single particle levels k . These equations predict that repulsive interactions shift the critical temperature (at constant density) by an amount which is positive, and simply proportional to the scattering length a ; nevertheless, the numerical coefficient is difficult to compute. Physically, the increase of the temperature can be interpreted in terms of the reduced density fluctuations introduced by the repulsive interactions, which facilitate the propagation of large exchange cycles across the sample.

DOI: 10.1016/j.crhy.2004.01.003

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We discuss certain specific features of the calculation of the critical temperature of a dilute repulsive Bose gas. Interactions modify the critical temperature in two different ways. First, for gases in traps, temperature shifts are introduced by a change of the density profile, arising itself from a modification of the equation of state of the gas (reduced compressibility); these shifts can be calculated simply within mean field theory. Second, even in the absence of a trapping potential (homogeneous gas in a box), temperature shifts are introduced by the interactions; they arise from the correlations introduced in the gas, and thus lie inherently beyond mean field theory – in fact, their evaluation requires more elaborate, non-perturbative, calculations. One illustration of this non-perturbative character is provided by the solution of self-consistent equations, which relate together non-linearly the various energy shifts of the single particle levels k . These equations predict that repulsive interactions shift the critical temperature (at constant density) by an amount which is positive, and simply proportional to the scattering length a ; nevertheless, the numerical coefficient is difficult to compute. Physically, the increase of the temperature can be interpreted in terms of the reduced density fluctuations introduced by the repulsive interactions, which facilitate the propagation of large exchange cycles across the sample.

A lower bound is derived on the free energy (per unit volume) of a homogeneous Bose gas at density and temperature T. In the dilute regime, i.e., when a 3 ≪ 1, where a denotes the scattering length of the pair-interaction potential, our bound differs to leading order from the expression for non-interacting particles by the term 4πa(2 2 −[−c] 2 +). Here, c(T) denotes the critical density for Bose-Einstein condensation (for the non-interacting gas), and [ ·]+ = max { · , 0} denotes the positive part. Our bound is uniform in the temperature up to temperatures of the order of the critical temperature, i.e., T ∼ 2/3 or smaller. One of the key ingredients in the proof is the use of coherent states to extend the method introduced in [17] for estimating correlations to temperatures below the critical one. 1 Introduction and Main Result The advance of experimental techniques for studying ultra-cold atomic gases

We show that the critical temperature of a uniform dilute Bose gas increases linearly with the

s

-wave scattering length describing the repulsion between the particles. Because of infrared divergences, the magnitude of the shift cannot be obtained from perturbation theory, even in the weak coupling regime; rather, it is proportional to the size of the critical region in momentum space. By means of a self-consistent calculation of the quasiparticle spectrum at low momenta at the transition, we find an estimate of the effect in reasonable agreement with numerical simulations.

The leading-order effect of interactions on a homogeneous Bose gas is theoretically predicted to shift the critical temperature by an amount $\ensuremath{\Delta}{T}_{c}\ensuremath{\simeq}{\mathrm{ca}}_{\mathrm{sc}}{n}^{1/3}{T}_{0}$ from the ideal gas result

{T}_{0}

, where

{a}_{\mathrm{sc}}

is the scattering length,

n

is the density, and

c

is a pure number. There have been several different theoretical estimates for

c

. We claim to settle the issue by measuring the numerical coefficient in a lattice simulation of O(2) ${\ensuremath{\varphi}}^{4}$ field theory in three dimensions---an effective theory which, as observed previously in the literature, can be systematically matched to the dilute Bose gas problem to reproduce nonuniversal quantities such as the critical temperature. We find $c\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}1.32\ifmmode\pm\else\textpm\fi{}0.02$.

The topic of Bose–Einstein condensation in a uniform, non-interacting gas of bosons is treated in most textbooks on statistical mechanics. In the present chapter we discuss the properties of a non-interacting Bose gas in a trap. We shall calculate equilibrium properties of systems in a semi-classical approximation, in which the energy spectrum is treated as a continuum. For this approach to be valid the temperature must be large compared with Δ∈/ k , where Δ∈ denotes the separation between neighbouring energy levels. As is well known, at temperatures below the Bose–Einstein condensation temperature, the lowest energy state is not properly accounted for if one simply replaces sums by integrals, and it must be included explicitly. The statistical distribution function is discussed in Sec. 2.1, as is the single-particle density of states, which is a key ingredient in the calculations of thermo dynamic properties. Calculations of the transition temperature and the fraction of particles in the condensate are described in Sec. 2.2. In Sec. 2.3 the semi-classical distribution function is introduced, and from this we determine the density profile and the velocity distribution of particles. Thermodynamic properties of Bose gases are calculated as functions of the temperature in Sec. 2.4. The final two sections are devoted to effects not captured by the simplest version of the semi-classical approximation: corrections to the transition temperature due to a finite particle number (Sec. 2.5), and thermodynamic properties of gases in lower dimensions (Sec. 2.6).

The topic of Bose–Einstein condensation in a uniform, non-interacting gas of bosons is treated in most textbooks on statistical mechanics. In the present chapter we discuss the properties of a non-interacting Bose gas in a trap. We shall calculate equilibrium properties of systems in a semi-classical approximation, in which the energy spectrum is treated as a continuum. For this approach to be valid the temperature must be large compared with Δ∊/ k , where Δ∊ denotes the separation between neighbouring energy levels. As is well known, at temperatures below the Bose–Einstein condensation temperature, the lowest-energy state is not properly accounted for if one simply replaces sums by integrals, and it must be included explicitly. The statistical distribution function is discussed in Sec. 2.1, as is the single-particle density of states, which is a key ingredient in the calculations of thermodynamic properties. Calculations of the transition temperature and the fraction of particles in the condensate are described in Sec. 2.2. In Sec. 2.3 the semi-classical distribution function is introduced. From this we obtain the density profile and the velocity distribution of particles, and use these to determine the shape of an anisotropic cloud after free expansion. Thermodynamic properties of Bose gases are calculated as functions of the temperature in Sec. 2.4. Finally, Sec. 2.5 treats corrections to the transition temperature due to a finite particle number.

The transition temperature for a dilute, homogeneous, three-dimensional Bose gas has the expansion ${T}_{\mathrm{c}}{=T}_{0}{{1+c}_{1}{\mathrm{an}}^{1/3}+[{c}_{2}^{\ensuremath{'}}\mathrm{ln}{(an}^{1/3}{)+c}_{2}^{\ensuremath{''}}]{a}^{2}{n}^{2/3}{+O(a}^{3}n)},$ where a is the scattering length, n the number density, and

{T}_{0}

the ideal gas result. The first-order coefficient

{c}_{1}

depends on nonperturbative physics. In this paper, we show that the coefficient ${c}_{2}^{\ensuremath{'}}$ may be computed perturbatively. We also show that the remaining second-order coefficient ${c}_{2}^{\ensuremath{''}}$ depends on non-perturbative physics but may be related, by a perturbative calculation, to quantities that have previously been measured using lattice simulations of three-dimensional

O(2)

scalar field theory. Making use of those simulation results, we find ${T}_{\mathrm{c}}\ensuremath{\simeq}{T}_{0}{1+(1.32\ifmmode\pm\else\textpm\fi{}0.02){\mathrm{an}}^{1/3}+[19.7518\mathrm{ln}{(an}^{1/3})+(75.7\ifmmode\pm\else\textpm\fi{}0.4)]{a}^{2}{n}^{2/3}{+O(a}^{3}n)}.$