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arXiv:cond-mat/0305045 · New Journal of Physics

Chemical potential standard for atomic Bose–Einstein condensates

Sigmund Kohler, Fernando Sols

Published Jul 15, 2003• 36 citations
arXivHTMLPDF

Abstract

When subject to an external time-periodic perturbation of frequency f , a Josephson-coupled two-state Bose–Einstein condensate may respond with a constant chemical potential difference Δμ = khf , where h is Planck's constant and k is an integer. We propose an experimental procedure to produce ac-driven atomic Josephson devices that can be used to define a standard of chemical potential. We investigate how to circumvent some of the specific problems derived from the present lack of advanced atom circuit technology. We include the effect of dissipation due to quasiparticles, which is essential to help the system relax towards the exact Shapiro resonance, and set limits to the range of values which the various physical quantities must have in order to favour the achievement of a stable and accurate chemical potential difference between the macroscopic condensates.

DOI
10.1088/1367-2630/5/1/394

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When subject to an external time-periodic perturbation of frequency f , a Josephson-coupled two-state Bose–Einstein condensate may respond with a constant chemical potential difference Δμ = khf , where h is Planck's constant and k is an integer. We propose an experimental procedure to produce ac-driven atomic Josephson devices that can be used to define a standard of chemical potential. We investigate how to circumvent some of the specific problems derived from the present lack of advanced atom circuit technology. We include the effect of dissipation due to quasiparticles, which is essential to help the system relax towards the exact Shapiro resonance, and set limits to the range of values which the various physical quantities must have in order to favour the achievement of a stable and accurate chemical potential difference between the macroscopic condensates.
Bose–Einstein condensation (BEC) is discussed at the level of an advanced course of statistical thermodynamics, clarifying some formal and physical aspects that are usually not covered by the standard pedagogical literature. The non-conventional approach adopted starts by showing that the continuum limit, in certain cases, cancels out the crucial role of the bosonic ground level. If so, a correct treatment of the problem, including the ground level population N 0 by construction, leads to BEC in a straightforward way. For a density of states of the form G ( )∝ γ , the chemical potential µ is explicitly calculated as a function of the temperature T and of the number N of bosons, for various significant values of the positive exponent γ. In the thermodynamic limit, in which the boson number N diverges and BEC is a sharp process, the chemical potential µ is a singular function of T at the critical temperature T B , determined by an appropriate critical exponent. The condensate population N 0 is studied analytically and numerically as a function of the temperature, for various values of N and for different γ. This provides an accurate description of the way BEC approaches the character of a sharp phase transition. Some aspects of the real experiments on BEC, involving a finite number of bosons, are also illustrated.
We show that the orbital Josephson effect appears in a wide range of driven atomic Bose–Einstein condensed systems, including quantum ratchets, double wells and box potentials. We use three separate numerical methods: the Gross–Pitaevskii equation, exact diagonalization of the few-mode problem and the multi-configurational time-dependent Hartree for bosons algorithm. We establish the limits of mean-field and few-mode descriptions, demonstrating that the few-mode approximation represents the full many-body dynamics to high accuracy in the weak driving limit. Among other quantum measures, we compute the instantaneous particle current and the occupation of natural orbitals. We explore four separate dynamical regimes, the Rabi limit, chaos, the critical point and self-trapping; a favorable comparison is found even in the regimes of dynamical instabilities or macroscopic quantum self-trapping. Finally, we present an extension of the ( t , t ')-formalism to general time-periodic equations of motion, which permits a systematic description of the long-time dynamics of resonantly driven many-body systems, including those relevant to the orbital Josephson effect.
We show that the orbital Josephson effect appears in a wide range of driven atomic Bose-Einstein condensed systems, including quantum ratchets, double wells and box potentials. We use three separate numerical methods: the Gross-Pitaevskii equation, exact diagonalization of the few-mode problem and the multi-configurational time-dependent Hartree for bosons algorithm. We establish the limits of mean-field and few-mode descriptions, demonstrating that the few-mode approximation represents the full many-body dynamics to high accuracy in the weak driving limit. Among other quantum measures, we compute the instantaneous particle current and the occupation of natural orbitals. We explore four separate dynamical regimes, the Rabi limit, chaos, the critical point and self-trapping; a favorable comparison is found even in the regimes of dynamical instabilities or macroscopic quantum self-trapping. Finally, we present an extension of the (t, t')-formalism to general time-periodic equations of motion, which permits a systematic description of the long-time dynamics of resonantly driven many-body systems, including those relevant to the orbital Josephson effect.
The effects of quantal and thermal fluctuations beyond the BCS quasiparticle mean field on the chemical potential are studied within a model, which consists of NNN particles distributed amongst $\ensuremath{\Omega}$ doubly folded equidistant levels interacting via a pairing force with parameter GGG. The results obtained at zero and finite temperatures TTT within several approaches, which include the fluctuations beyond the BCS theory, are compared with the exact results. The chemical potential, defined as the Lagrangian multiplier to preserve the average number of particles, is compared with the corresponding quantity, which includes the effect from fluctuations of particle and quasiparticle numbers beyond the BCS quasiparticle mean field. The analysis of the results shows that the latter differs significantly from the former as functions of GGG and TTT. The chemical potential loses its physical meaning in the system with a fixed number of particles or after eliminating quantal fluctuations of particle (quasiparticle) numbers by means of particle number projection. The validity of the criterion for the signature of the transition to Bose-Einstein condensation, which occurs in infinite systems when the chemical potential hits the bottom of the energy spectrum, is reexamined for the finite multilevel model.
We consider a two-component weakly interacting Bose-Einstein condensate in the presence of an external field which couples the two components. We express the Hamiltonian in terms of the energy eigenstates of the single-body part of the Hamiltonian. These eigenstates are the atomic dressed states of quantum optics. When the energy difference between the two dressed states is much larger than the mean-field interactions, two-body interactions in the dressed state basis that do not conserve the number of atoms in each of the two dressed states are highly suppressed. The two-body interactions then take on a simplified form in the dressed basis with effective coupling constants that depend on the intensity and frequency of the external field. This implies that the chemical potential as well as the quasiparticle spectrum may be controlled experimentally in a simple manner. We demonstrate this by showing that one may achieve significant variations in the speed of sound in the condensate, a quantity which has been measured experimentally.