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arXiv:cond-mat/0304388

Antiferromagnetism and d-wave superconductivity in (doped) Mott insulators: A wave function approach

Zheng-Yu Weng, Yongquan Zhou, V. N. Muthukumar

Published Apr 17, 2003• 0 citations
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Abstract

We propose a class of wave functions that provide a unified description of antiferromagnetism and d-wave superconductivity in (doped) Mott insulators. The wave function has a Jastrow form and prohibits double occupancies. In the absence of holes, the wave function describes antiferromagnetism accurately. Off diagonal long range order develops at finite doping and the superconducting order parameter has d-wave symmetry. We also show how nodal quasiparticles and neutral spin excitations can be constructed from this wave function.

DOI
10.48550/arxiv.cond-mat/0304388

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We propose a class of wave functions that provide a unified description of antiferromagnetism and d-wave superconductivity in (doped) Mott insulators. The wave function has a Jastrow form and prohibits double occupancies. In the absence of holes, the wave function describes antiferromagnetism accurately. Off diagonal long range order develops at finite doping and the superconducting order parameter has d-wave symmetry. We also show how nodal quasiparticles and neutral spin excitations can be constructed from this wave function.
New trial wave functions, constructed explicitly from the unique Mott insulating state with antiferromagnetic order, are proposed to describe the ground state of a Mott insulator slightly doped with holes or electrons. A rigid band is observed as charged quasiparticles with well-defined momenta being realized in these states. These states have much less superconducting correlations than previously studied ones. Small Fermi patches obtained are consistent with recent experiments on high T(c) cuprates doped lightly with holes or electrons.
We propose a class of ground states for doped Mott insulators in the electron second quantization representation. They are obtained from a bosonic resonating valence bond (RVB) theory of the $t\text{\penalty1000-\hskip0pt}J$ model. At half filling, the ground state describes spin correlations of the S=1∕2S=1∕2S=1∕2 Heisenberg model very accurately. Its spin degrees of freedom are characterized by RVB pairing of spins, the size of which decreases continuously as holes are doped into the system. Charge degrees of freedom emerge upon doping and are described by twisted holes in the RVB background. We show that the twisted holes exhibit an off diagonal long range order (ODLRO) in the pseudogap ground state, which has a finite pairing amplitude, but is short of phase coherence. Unpaired spins in such a pseudogap ground state behave as free vortices, preventing superconducting phase coherence. The existence of nodal quasiparticles is also ensured by such a hidden ODLRO in the ground state, which is non-Fermi liquidlike in the absence of superconducting phase coherence. Two distinct types of spin excitations can also be constructed. The superconducting instability of the pseudogap ground state is discussed and a ddd-wave superconducting ground state is obtained. This class of pseudogap and superconducting ground states unifies antiferromagnetism, pseudogap, superconductivity, and Mott physics into a new state of matter.
Using a simple variational ansatz, we estimate the pair wave function of a superconductor obtained by doping a Mott insulator with short-range antiferromagnetic spin correlations. The pairing symmetry is generically d wave. The so-called ``anyon superconductors'' are related to traditional BCS states with d-wave order parameters that break parity and time-reversal invariance. The transition between a tetragonal normal metal and a superconductor of this type generically proceeds through an intermediate phase with either superconducting order or broken time reversal, but not both.
SU(4) dynamical symmetry is shown to imply a no-double-occupancy constraint on the minimal symmetry description of antiferromagnetism and ddd-wave superconductivity. This implies a maximum doping fraction of 14\frac{1}{4}41​ for cuprates and provides a microscopic critique of the projected SO(5) model. We propose that SU(4) superconductors are representative of a class of compounds that we term non-Abelian superconductors. We further suggest that non-Abelian superconductors may exist having SU(4) symmetry and therefore cupratelike dynamics, but without ddd-wave hybridization.
Proximity to a Mott insulating phase is likely to be an important physical ingredient of a theory that aims to describe high-temperature superconductivity in the cuprates. Quantum cluster methods are well suited to describe the Mott phase. Hence, as a step toward a quantitative theory of the competition between antiferromagnetism and ddd-wave superconductivity in the cuprates, we use cellular dynamical mean-field theory to compute zero-temperature properties of the two-dimensional square lattice Hubbard model. The ddd-wave order parameter is found to scale like the superexchange coupling JJJ for on-site interaction UUU comparable to or larger than the bandwidth. The order parameter also assumes a dome shape as a function of doping, while, by contrast, the gap in the single-particle density of states decreases monotonically with increasing doping. In the presence of a finite second neighbor hopping ${t}^{\ensuremath{'}}$, the zero-temperature phase diagram displays the electron-hole asymmetric competition between antiferromagnetism and superconductivity that is observed experimentally in the cuprates. Adding realistic third neighbor hopping ${t}^{\ensuremath{''}}$ improves the overall agreement with the experimental phase diagram. Since band parameters can vary depending on the specific cuprate considered, the sensitivity of the theoretical phase diagram to band parameters challenges the commonly held assumption that the doping vs Tc∕Tcmax{T}_{c}∕{T}_{c}^{\mathit{max}}Tc​∕Tcmax​ phase diagram of the cuprates is universal. The calculated angle-resolved photoemission spectrum displays the observed electron-hole asymmetry. The tendency to homogeneous coexistence of the superconducting and antiferromagnetic order parameters is stronger than observed in most experiments but consistent with many theoretical results and with experiments in some layered high-temperature superconductors. Clearly, our calculations reproduce important features of ddd-wave superconductivity in the cuprates that would otherwise be considered anomalous from the point of view of the standard Bardeen--Cooper--Schrieffer approach. At strong coupling, ddd-wave superconductivity and antiferromagnetism naturally appear as two equally important competing instabilities of the normal phase of the same underlying Hamiltonian.
We study the properties of a spin-density-wave antiferromagnetic mean-field ground state with d-wave superconducting correlations. This ground state always gains energy by Cooper pairing. It would fail to superconduct at half-filling due to the antiferromagnetic gap although its particle-like excitations would be Bogolyubov-BCS quasiparticles consisting of coherent mixtures of electrons and holes. More interesting and relevant to the superconducting cuprates is the case when antiferromagnetic order is turned on weakly on top of the superconductivity. This would correspond to the onset of antiferromagnetism at a critical doping. In such a case a small gap proportional to the weak antiferromagnetic gap opens up for nodal quasiparticles, and the quasiparticle peak would be discernible. We evaluate numerically the absorption by nodal quasiparticles and the local density of states for several ground states with antiferromagnetic and d-wave superconducting correlations.