This article is aimed at a pedagogical introduction to the physics of quantum phase transitions that is unique to metallic systems. It has been recognized for some time that quantum criticality can result in a breakdown of Landau's Fermi liquid theory. Its converse, however, has not been appreciated until very recently: non-Fermi liquid behavior can in turn lead to new classes of quantum phase transition. A concrete example is provided by ``local quantum critical points''. I summarize the theoretical reasoning and experimental evidence for local quantum criticality, in the context of heavy fermion metals. The underlying physics is likely to be relevant to other correlated electron systems including doped Mott insulators.
This article is aimed at a pedagogical introduction to the physics of quantum phase transitions that is unique to metallic systems. It has been recognized for some time that quantum criticality can result in a breakdown of Landau's Fermi liquid theory. Its converse, however, has not been appreciated until very recently: non-Fermi liquid behavior can in turn lead to new classes of quantum phase transition. A concrete example is provided by ``local quantum critical points''. I summarize the theoretical reasoning and experimental evidence for local quantum criticality, in the context of heavy fermion metals. The underlying physics is likely to be relevant to other correlated electron systems including doped Mott insulators.
In these lecture notes, recent theoretical and experimental work on quantum phase transitions, in particular, in metals with strong electronic interactions will be reviewed. After an introduction to classical and quantum phase transitions, we will briefly discuss the standard model of metals, i.e., the Landau Fermi‐liquid theory, and routes to non‐Fermi‐liquid behavior. We will then focus on two different types of quantum phase transitions, magnetic quantum phase transitions in heavy‐fermion systems, and metal‐insulator transitions in heavily doped semiconductors.
In this brief overview, I address some of the fundamental topics related to the physics of strongly correlated fermions, which have been also the subject of my research. After addressing the question why the field has a fundamental meaning, we next turn to the specific problems with their simple theoretical description. Those topics are: (i) the concept of spindependent masses of heavy particles and its subsequent experimental verification; (ii) the correlated metal–insulator transitions of the Mott–Hubbardtype; (iii) real space pairing and its subsequent experimental verification for high-temperature superconducting cuprates. I mention also the persistence of quantum spin and charge excitations in the superconducting phase. All those phenomena confirm the view that the strongly correlated fermionic \nsystems represent a new class of quantum liquids, with some properties quantitatively different than those of the Landau Fermi liquids. Namely, they can be classified as those that fall in between those of the anomalous Landau Fermi liquid and localized-magnetic-moment system.
In recent years, quantum phase transitions have attracted the interest of both theorists and experimentalists in condensed matter physics. These transitions, which are accessed at zero temperature by variation of a non-thermal control parameter, can influence the behaviour of electronic systems over a wide range of the phase diagram. Quantum phase transitions occur as a result of competing ground state phases. The cuprate superconductors which can be tuned from a Mott insulating to a d -wave superconducting phase by carrier doping are a paradigmatic example. This review introduces important concepts of phase transitions and discusses the interplay of quantum and classical fluctuations near criticality. The main part of the article is devoted to bulk quantum phase transitions in condensed matter systems. Several classes of transitions will be briefly reviewed, pointing out, e.g., conceptual differences between ordering transitions in metallic and insulating systems. An interesting separate class of transitions is boundary phase transitions where only degrees of freedom of a subsystem become critical; this will be illustrated in a few examples. The article is aimed at bridging the gap between high-level theoretical presentations and research papers specialized in certain classes of materials. It will give an overview on a variety of different quantum transitions, critically discuss open theoretical questions, and frequently make contact with recent experiments in condensed matter physics.
In this thesis, several cases of non-equilibrium phenomena and quantum phase transitions in strongly correlated electron systems are analyzed. The unconventional critical behavior near magnetic quantum phase transitions in various heavy-fermion metals has triggered proposals on the breakdown of the Kondo effect at the critical point. In part I, we investigate, within one specific scenario, the fate of such a zero-temperature transition upon coupling of the electronic to lattice degrees of freedom. We study a Kondo-Heisenberg model with volume-dependent Kondo coupling � this model displays both Kondo volume collapse and Kondo-breakdown transitions. Within a large-N treatment, we find that the Kondo breakdown transition remains of second order except for very soft lattices. Finally, we relate our findings to current heavy-fermion experiments. Using non-equilibrium Green�s functions, we derive transport equations for the degrees of freedom participating in the quantum critical region of the Kondo breakdown transition. We discuss conditions under which the transport of electrical charge is described by the independent motion of conduction electrons and auxiliary bosons. Under these conditions, we derive a semiclassical transport equation for the bosons and quantitatively discuss the electrical conductivity of the whole system. Motivated by pressure experiments on FeAs-122 superconductors, in part II we propose a scenario based on local-moment physics to explain salient features at the magnetic phase boundary of CaFe2As2. In this scenario, the low-pressure magnetic phase derives from Fe moments, which become screened in the paramagnetic high-pressure phase. The quantum phase transition can be described as an orbital-selective Mott transition, which is rendered first order by coupling to the lattice. These ideas are illustrated by a suitable mean-field analysis of an Anderson lattice model. An analytical description of non-equilibrium phenomena in interacting quantum systems is rarely possible. In part III we present one example where such a description can be achieved, namely the ferromagnetic Kondo model. In equilibrium, this model is tractable via perturbative renormalization-group techniques. We employ a recently developed extension of the flow-equation method to calculate the non-equilibrium decay of the local magnetization at zero temperature. The flow equations admit analytical solutions which become exact at short and long times, in the latter case revealing that the system always retains a memory of its initial state. Finally, in part IV we analyze the Nernst effect resulting from normal state quasiparticles in the cuprates in presence of various types of translational symmetry breaking. In the electron-doped cuprates, the Nernst signal resulting from a reconstruction of the Fermi surface due to spin density wave order is discussed. An order parameter consistent with the reconstruction of the Fermi surface detected in electron-doped materials is shown to sharply enhance the Nernst signal close to optimal doping. Within a semiclassical treatment, the obtained magnitude and position of the enhanced Nernst signal agrees with Nernst measurements in electron-doped cuprates. In the hole-doped cuprates, we discuss relations between the normal-state Nernst effect and stripe order. We find that Fermi pockets caused by translational symmetry breaking lead to a strongly enhanced Nernst signal with a sign depending on the modulation period of the ordered state and other details of the Fermi surface. This implies differences between antiferromagnetic and charge-only stripes. We compare our findings with recent data from La1.6−xNd0.4SrxCuO4 and YBa2Cu3Oy.
Abstract: The metal–insulator transition (MIT) constitutes one of the most profound and persistent problems in condensed matter physics, sitting at the intersection of electronic structure theory, many-body physics, and emergent quantum phenomena. Conventional band theory, which successfully classifies materials as metals or insulators according to the filling of their electronic bands, fails dramatically when confronted with a class of compounds transition metal oxides chief among them that ought to be metallic by band-counting arguments yet are robustly insulating in the laboratory. The resolution of this paradox required abandoning the independent-electron picture entirely and recognizing that strong Coulomb repulsion between electrons can, by itself, drive localization. This insight, formalized by Mott and later distilled into the Hubbard model, established correlation-driven insulation as a phenomenon distinct from band insulation. The present paper offers a theoretical exploration of the MIT problem, tracing its conceptual development from the Mott criterion through the Hubbard Hamiltonian, the Brinkman–Rice scenario of quasiparticle mass divergence, and the watershed development of dynamical mean-field theory (DMFT), which rendered the Mott transition quantitatively tractable for the first time. We argue that the competition between the electronic bandwidth and the on-site interaction encoded in the ratio U/W provides the unifying organizing principle for the field. Building toward the modern frontier, we examine how the Mott transition connects to quantum phase transitions and quantum criticality, where zero-temperature instabilities governed by quantum rather than thermal fluctuations produce non-Fermi-liquid behavior and anomalous scaling. Case studies of vanadium oxides, rare-earth nickelates, and doped cuprates illustrate the diversity and subtlety of real correlated materials. We conclude that the MIT remains a central and unresolved problem whose continued study is increasingly entangled with the development of quantum materials and quantum technologies. Keywords: Metal–Insulator Transition; Mott Insulator; Strongly Correlated Electrons; Hubbard Model; DMFT; Quantum Criticality; Quantum Materials; Condensed Matter Physics
The Landau theory of phase and phase transition, which describes the state of matter by the spontaneous symmetry breaking, and the Fermi liquid theory of interacting Fermi systems are the two corner stones of contemporary condensed matter physics. They act as our starting points to understand the structure, excitations and phase transitions of any condensed matter system. According to such a Landau paradigm, an interacting Fermi system will behave just as non-interacting Fermi gas system at sufficient low energy, if the interaction is not strong enough to induce a symmetry breaking phase transition in the system. In such a case, the perturbation expansion in the interaction strength is assumed to converge and the low energy excitation can be connected to that of a Fermi gas system adiabatically. In strongly correlated electron systems, such as the high temperature superconductors and quantum antiferromagnets, a pertubative picture on the interaction effect usually fails. The correlation effect between the electrons can induce new forms of order that are beyond the Landau symmetry breaking paradigm. Non-Fermi liquid behavior can emerge in the fully symmetric correlated phases. The Mott insulating phase and the quantum spin liquid phase are the most prominent example of such exotic state of matter. After about three decades of intensive studies, people find that the quantum non-locality effect is at the heart of such new forms of order. The quantum non-locality effect manifests itself in the emergence of gauge degree of freedom in the low energy physics of such strongly correlated system. Such emergent gauge filed is not only important for the characterization and classification of the ground state structure, but is also directly responsible for the non-Fermi liquid behavior of the system. The Landau paradigm should be extended to accommodate such new forms of order and the related new form of excitations and new universal class of phase transitions. Such an extension will elevate our understanding of the structure of matter to the level of quantum wave function. Unlike the conventional symmetry breaking order, which is characterized by the correlation functions between local physical observables, the new form of orders, which are commonly called quantum order (with the topological order as one of its typical example), can be better characterized by the entanglement property in the quantum wave function. From a mathematical point of view, the new form of order is closely related to the projective representation theory of the symmetry group, while the conventional symmetry breaking order is well described by the linear representation theory of the symmetry group.