In this paper we revisit the problem of finding hidden symmetries in quantum mechanical systems. Our interest in this problem was renewed by nontrivial degeneracies of a simple spin Hamiltonian used to model spin relaxation in alkali-metal vapours. We consider this spin Hamiltonian in detail and use this example to outline a general approach to finding symmetries when eigenvalues and eigenstates of the Hamiltonian are known. We extract all nontrivial symmetries responsible for the degeneracy and show that the symmetry group of the Hamiltonian is SU (2). The symmetry operators have a simple meaning which becomes transparent in the limit of large spin. As an additional example we apply the method to the hydrogen atom.
In this paper we revisit the problem of finding hidden symmetries in quantum mechanical systems. Our interest in this problem was renewed by nontrivial degeneracies of a simple spin Hamiltonian used to model spin relaxation in alkali-metal vapours. We consider this spin Hamiltonian in detail and use this example to outline a general approach to finding symmetries when eigenvalues and eigenstates of the Hamiltonian are known. We extract all nontrivial symmetries responsible for the degeneracy and show that the symmetry group of the Hamiltonian is SU (2). The symmetry operators have a simple meaning which becomes transparent in the limit of large spin. As an additional example we apply the method to the hydrogen atom.
Certain Hamiltonians, based on two coupled quantum mechanical spins, exhibit degenerate eigenvalues despite having no obvious non-Abelian symmetries.Operators acting to permute the degenerate states do not have a simple form when expressed as polynomials of the generators of rotations for the respective spins.As observed in [3], one such Hamiltonian helps explain resonances in the spin relaxation rate of optically pumped Rb 2 , as a function of applied magnetic field.We give an explanation of why the degeneracies exist, based on properties of the commutator and anti-commutator of the Hamiltonian and its image under magnetic field reversal.
Certain Hamiltonians based on two coupled quantum mechanical spins exhibit degenerate eigenvalues despite having no obvious non-abelian symmetries. Operators acting to permute the degenerate states do not have a simple form when expressed as polynomials of the generators of rotations for the respective spins. As observed in [1], one such Hamiltonian helps explain resonances in the spin relaxation rate of optically pumped Rb_2, as a function of applied magnetic field. We give an explanation of why the degeneracies exist, based on properties of the commutator and anti-commutator of the Hamiltonian and its image under magnetic field reversal.
Symmetry is a cornerstone of modern physics, offering profound insights into the fundamental laws governing the universe. In quantum mechanics, symmetries lead to conserved quantities and simplify the resolution of complex systems. This paper explores the universal symmetries inherent in three paradigmatic quantum mechanical systems: the one-dimensional quantum harmonic oscillator, the hydrogen atom, and the angular momentum operator. While renowned for their exact solvability, their underlying symmetry structures extend beyond explicit Hamiltonian invariances. We examine both geometric and dynamical (hidden) symmetries, which arise from non-trivial conserved quantities and often explain ``accidental'' degeneracies in energy spectra. For the quantum harmonic oscillator, we delve into the SU(1,1) or SU(2) dynamical symmetry associated with its creation and annihilation operators. The hydrogen atom's unique SO(4) symmetry, stemming from the conservation of the Runge-Lenz vector in addition to angular momentum, is thoroughly investigated. The Lie algebra of angular momentum operators forms the basis of SO(3) or SU(2) symmetry, governing rotational invariance. By employing Lie groups and Lie algebras, we reveal the deep mathematical unity underpinning these seemingly disparate systems. This comparative analysis demonstrates how these universal symmetry principles not only explain solvability and degeneracy patterns but also offer a general framework for understanding quantum phenomena. The paper hypothesizes that the recurring algebraic structures of su(2) and its extensions across these systems signify a deeper, universal blueprint for quantum system behavior, serving as a foundational guide for understanding both exactly solvable and inherently non-solvable quantum phenomena through the lens of symmetry breaking or approximation. This exploration provides a robust foundation for advanced topics in quantum field theory and particle physics.
The Schrödinger equation does not account for the 2n2 degeneracy of the hydrogen atom, which it dismisses as an “accidental” degeneracy. The factor of “2” in the 2n2 degeneracy is well-accounted-for in the relativistic formulation by the two spin states of the electron. The n2 degeneracy is nevertheless not quite an “accident”; it is due to the SO(4), rather than SO(3), symmetry of the hydrogen atom. This result is well known, but is inadequately commented upon in most courses in quantum mechanics and atomic physics, leaving the student wondering about the origins of the n2 degeneracy of the hydrogen atom. A pedagogical analysis of this interesting aspect, which highlights the fundamental principles of quantum mechanics, is presented in this article. While doing so, not only is the n2 degeneracy of the hydrogen atom explained, but its energy spectrum and eigenfunctions are obtained without even using the Schrödinger equation, employing only the fundamental principles of quantum mechanics rather than the Schrödinger equation.
In the problem of inverse-square force, there exists a hidden SO(4) symmetry, which is manifested as a conserved quantity the Laplace-Runge-Lenz vector in the classical Kepler problem, and as the degeneracy of hydrogen atom energy levels beyond the three-dimensional rotational symmetry in quantum mechanics. This paper presents a more intuitive representation of this hidden symmetry through geometric imagery. Additionally, the paper derives in detail the relevant formulas for the raising and lowering operators corresponding to this symmetry in quantum mechanics.
In this paper, we present various well-studied examples of quantum systems, and discuss how they might be analysed algebraically. We analyse the harmonic oscillator, hydrogenic atom, optical components, and particle spin using multiple algebraic methods, and highlight the central importance of algebraic relationships between operators in determining the physical character of the system. In particular, we show: the ubiquity of the Lie algebra so(2,1)≅su(1,1) as the ``spectrum generating algebra''; the role of su(2) and su(1,1) in determining the action of optical components; that an elementary algebraic approach to particle spin offers novel insights into its nature versus the usual approaches; and how understanding the full (often hidden) symmetry of a problem enables it to be solved immediately without the need to solve differential equations. We hope this work will serve as a gentle introduction to algebraic methods in quantum mechanics for the interested reader --- we therefore signpost active areas of research within the community.