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arXiv:cond-mat/0209647 · Physical Review Letters

Condensate Density and Superfluid Mass Density of a Dilute Bose-Einstein Condensate near the Condensation Transition

Markus Holzmann, Gordon Baym

Published Jan 30, 2003• 33 citations
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Abstract

We derive via diagrammatic perturbation theory the scaling behavior of the condensate and superfluid mass density of a dilute Bose gas just below the condensation temperature, T(c). Sufficiently below T(c) particle excitations are described by mean field (Bogoliubov). Near T(c), however, mean field fails, and the system undergoes a second order phase transition, rather than first order as predicted by Bogoliubov theory. Both condensation and superfluidity occur at the same T(c), and have similar scaling functions below T(c), but different finite size scaling at T(c) to leading order in the system size. A self-consistent two-loop calculation yields the condensate fraction critical exponent, 2beta approximately 0.66.

DOI
10.1103/physrevlett.90.040402

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We derive via diagrammatic perturbation theory the scaling behavior of the condensate and superfluid mass density of a dilute Bose gas just below the condensation temperature, T(c). Sufficiently below T(c) particle excitations are described by mean field (Bogoliubov). Near T(c), however, mean field fails, and the system undergoes a second order phase transition, rather than first order as predicted by Bogoliubov theory. Both condensation and superfluidity occur at the same T(c), and have similar scaling functions below T(c), but different finite size scaling at T(c) to leading order in the system size. A self-consistent two-loop calculation yields the condensate fraction critical exponent, 2beta approximately 0.66.
The behavior of a dilute Bose superfluid at low temperatures, $T<<{T}_{\ensuremath{\lambda}}$, is considered with emphasis on the superfluid density, ${\ensuremath{\rho}}_{s}(T)$. Many of the predictions of the Bogoliubov model are exact in this regime and are shown to lead to a scaling description of the crossover from ideal to interacting Bose gas behavior as the density is reduced. Combined with previous work on scaling near criticality, $T\ensuremath{\simeq}{T}_{\ensuremath{\lambda}}$, these results complete the crossover description of the dilute superfluid over the full temperature range. Diagrammatic perturbation theory in the superfluid phase is outlined and previous results from the helium literature are summarized. The various divergences encountered have previously been shown to arise from nonanalyticities in the self-energy functions at zero momentum, and these are related to the spin-wave nature of the superfluid phase. A full renormalization-group fixed-point picture is presented summarizing the zero-temperature and finite-temperature regimes and the flows connecting them.
A system with Bose-Einstein condensate is considered in the frame of the self-consistent mean-field approximation, which is conserving, gapless, and applicable for arbitrary interaction strengths and temperatures. The main attention is paid to the thorough analysis of the condensate and superfluid fractions in the whole range of the interaction strength, between zero and infinity, and for all temperatures between zero and the critical point Tc{T}_{c}Tc​. The normal and the anomalous averages are shown to be of the same order for almost all interactions and temperatures, except the close vicinity of Tc{T}_{c}Tc​. But even in the vicinity of the critical temperature, the anomalous average cannot be neglected, since only in the presence of the latter the phase transition at Tc{T}_{c}Tc​ becomes of second order, as it should be. Increasing temperature influences the condensate and superfluid fractions in a similar way, by diminishing them; but their behavior with respect to the interaction strength is very different. For all temperatures, the superfluid fraction is larger than the condensate fraction. These coincide only at Tc{T}_{c}Tc​ or under zero interactions. For asymptotically strong interactions, the condensate is almost completely depleted, even at low temperatures, while the superfluid fraction can be close to one.
We derive the Josephson relation for a dilute Bose gas in the framework of an auxiliary-field (AF) resummation of the theory in terms of the normal- and anomalous-density condensates. In the leading order of the AF loop expansion (LOAF) we find two critical temperatures in the phase diagram: the critical temperature Tc{T}_{c}Tc​, where the atom Bose-Einstein condensate (BEC) appears first, and the temperature ${T}^{\ensuremath{\star}}>{T}_{c}$, which indicates the onset of superfluidity and the appearance of a diatom condensate in the system. In this context, the Josephson relation shows that the superfluid density is related to the square of a second-order parameter, the anomalous density, $\ensuremath{\langle}A\ensuremath{\rangle}\ensuremath{\langle}\ensuremath{\varphi}\ensuremath{\varphi}\ensuremath{\rangle}$, which can be thought of as a diatom condensate analogous to the Cooper-pair condensate discussed in the BCS approach to dilute Fermi gases. This is in contrast with the corresponding result in the Bose gas theory without a diatom condensate, which predicts that the superfluid density is proportional to the square of the usual atom BEC condensate, $\ensuremath{\langle}\ensuremath{\varphi}\ensuremath{\rangle}$. In the region between Tc{T}_{c}Tc​ and ${T}^{\ensuremath{\star}}$ the anomalous-density Green's function contains a zero energy-momentum state corresponding to a Goldstone state. This is a two-particle state with U(1) charge two. Our findings are consistent with the prediction that in the temperature range between Tc{T}_{c}Tc​ and ${T}^{\ensuremath{\star}}$ a fraction of the system is in the superfluid state in the absence of the usual atom BEC condensate. This situation is similar to the case of dilute Fermi gases, where the superfluid density is proportional to the square of the gap parameter. The Josephson relation relies on the existence of zero energy and momentum excitations showing the intimate relationship between superfluidity and the Goldstone theorem.
The crossover from ideal-Bose-gas behavior to nonclassical, XY-like criticality in a dilute, interacting Bose fluid is considered in detail with emphasis on the superfluid density, ${\ensuremath{\rho}}_{s}$(T), below the transition. A general discussion of crossover scaling in constrained systems shows that ${\ensuremath{\rho}}_{s}$ and other temperature-dependent thermodynamic functions at controlled overall density can be expressed in terms of universal scaling functions. The finite-temperature Green's function formalism is used to calculate the associated linear scaling fields and the crossover exponent exactly for all dimensionalities d>2, scaling predictions, including logarithmic singularities just at d=3, being checked via second-order computations. A mapping of the Bose problem onto the classical s4{s}^{4}s4 spin model is achieved which is asymptotically exact in the critical region. In this way, previously known renormalization-group results are used to calculate the scaling functions for ${\ensuremath{\rho}}_{s}$, for the off-diagonal susceptibility, etc., to first order in \ensuremath{\epsilon}=4-d. Good agreement is found with the experimental measurements by Reppy and co-workers of ${\ensuremath{\rho}}_{s}$(T) for helium absorbed at low coverages in Vycor glass (of pore size 50--80 A\r{}). An effective-mass ratio m∗{m}^{\mathrm{*}}m∗/m\ensuremath{\simeq}1.5, and an effective-scattering-length ratio a∗{a}^{\mathrm{*}}a∗/a\ensuremath{\simeq}1.3 are indicated for mobile helium in the Vycor (although the irregular character of Vycor has not, at this point, been fully allowed for in the theory). Other approaches in the literature to computing the critical behavior of quantum-mechanical systems are reviewed and related to the present analysis.
We consider the thermodynamics of a homogeneous superfluid dilute Bose gas in the presence of weak quenched disorder. Following the zero-temperature approach of Huang and Meng, we diagonalize the Hamiltonian of a dilute Bose gas in an external random $\ensuremath{\delta}$-correlated potential by means of a Bogoliubov transformation. We extend this approach to finite temperature by combining the Popov and the many-body TTT-matrix approximations. This approach permits us to include the quasiparticle interactions within this temperature range. We derive the disorder-induced shifts of the Bose-Einstein critical temperature and of the temperature for the onset of superfluidity by approaching the transition points from below, i.e., from the superfluid phase. Our results lead to a phase diagram consistent with that of the finite-temperature theory of Lopatin and Vinokur which was based on the replica method, and in which the transition points were approached from above.
We derive the scaling structure of the Kosterlitz-Thouless-Berezinskii (KTB) transition temperature of a homogeneous Bose gas in two dimensions within diagrammatic perturbation theory. Approaching the system from above the transition, we calculate the critical temperature, TKTT_{KT}TKT​, and show how the superfluid mass density emerges from Josephson's relation as an interplay between the condensate density in a finite size system, and the infrared structure of the single particle Green's function. We then discuss the trapped two-dimensional Bose gas, where the interaction changes the transition qualitatively from Bose-Einstein in an ideal gas to a KTB transition in the thermodynamic limit. We show that the transition temperature lies below the ideal Bose-Einstein transition temperature, and calculate the first correction in terms of the interparticle interactions. The jump of the total superfluid mass at the transition is suppressed in a trapped system.