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arXiv:cond-mat/0110489

Quantum Mechanical Description of A Quasi-Sratic Process and An Application to Change of Temperatures

Kobayashi, T.

Published Oct 23, 2001• 0 citations
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Abstract

A quasi-static process is realized in a purely quantum-mechanical model which is described by oscillator (or particle) systems having relative-phase interactions. Time development of a mixture of two oscillator (or particle) systems which have different temperatures is investigated in the quantum mechanical framework. We study how they go to a thermal equilibrium. Time dependence of the temperature of the object is numerically studied and the difference of the time dependence between classical objects and quantum objects is clearly pointed out.

DOI
10.48550/arxiv.cond-mat/0110489

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A quasi-static process is realized in a purely quantum-mechanical model which is described by oscillator (or particle) systems having relative-phase interactions. Time development of a mixture of two oscillator (or particle) systems which have different temperatures is investigated in the quantum mechanical framework. We study how they go to a thermal equilibrium. Time dependence of the temperature of the object is numerically studied and the difference of the time dependence between classical objects and quantum objects is clearly pointed out.
A quasi-static process is realized in a purely quantum-mechanical model which is described by oscillator (or particle) systems having relative-phase interactions. Time development of a mixture of two oscillator (or particle) systems which have different temperatures is investigated in the quantum mechanical framework. We study how they go to a thermal equilibrium. Time dependence of the temperature of the object is numerically studied and the difference of the time dependence between classical objects and quantum objects is clearly pointed out.
A decoherence mechanism in the transition from pure quantum- mechanical systems to thermodynamical systems is proposed. We see that a quantum-mechanical expression of temperature is derived and the expression for boson systems and that for fermion systems are different. An application to the calculation of change of temperatures is investigated in a quasi-static process and numerical analyses for mixing of two gases with different temperatures are carried out. Considerations in terms of ultra-power representations of nonstandard-analysis are also presented.
This work studies the relationship between parametric amplification (or particle creation), adiabaticity and irreversibility in the non-quasi-static regime of a time-dependent quantum harmonic oscillator (TDHO) that evolves unitarily. We provide analytical results for the evolution of the TDHO valid for any functional value of the frequency, which enables us to monitor the behavior of the thermodynamical magnitudes in the non-quasi-static regime. In the latter, the largest modes of the energy eigenstates commonly undergo a process of spontaneous thermalization, where the concept of temperature naturally arises from the unitary evolution of the oscillator, i.e. without relation to any external source of temperature or thermal bath. As the evolution is unitary, this thermalization process can be reversible. We extend the standard definitions of quantum heat and work to account for the change in the populations of the energy levels and relate it to the diagonal entropy to obtain an effective temperature from the associated second principle of thermodynamics. The qualitative behavior of this temperature is similar to the temperature of the largest modes and is only significant in the non quasi-static region, returning to the original value T→0T\rightarrow 0T→0 afterwards. This effect is briefly analyzed in the case of a periodically driven quantum system, where the energy eigenstate mixing and the temperature grow and return to the original value periodically.
By using the quasi-equilibrium Helmholtz energy, which is defined as the thermodynamic work in a quasi-static process, we investigate the thermal properties of both an isothermal process and a transition process between the adiabatic and isothermal states (adiabatic transition). Here, the work is defined by the change in energy from a steady state to another state under a time-dependent perturbation. In particular, the work for a quasi-static change is regarded as thermodynamic work. We employ a system-bath model that involves time-dependent perturbations in both the system and the system-bath interaction. We conduct numerical experiments for a three-stroke heat machine (a Kelvin-Planck cycle). For this purpose, we employ the hierarchical equations of motion (HEOM) approach. These experiments involve an adiabatic transition field that describes the operation of an adiabatic wall between the system and the bath. Thermodynamic-work diagrams for external fields and their conjugate variables, similar to the P-V diagram, are introduced to analyze the work done for the system in the cycle. We find that the thermodynamic efficiency of this machine is zero because the field for the isothermal processes acts as a refrigerator, whereas that for the adiabatic wall acts as a heat engine. This is a numerical manifestation of the Kelvin-Planck statement, which states that it is impossible to derive the mechanical effects from a single heat source. These HEOM simulations serve as a rigorous test of thermodynamic formulations because the second law of thermodynamics is only valid when the work involved in the operation of the adiabatic wall is treated accurately.
In this dissertation, we studied the generation of squeezed states induced by a timedependent interaction and the in uence of temperature on the strength of the squeezing in a condensed matter model. The model studied comprised two quantum harmonic oscillators, with a time-dependent, non-linear coupling between them. The in uence of the thermal bath on the non-equilibrium dynamics of the model was represented in terms of non-Hamiltonian thermostats and a collection of independent harmonic oscillators with Ohmic spectral density. The equations of motion were studied in the Wigner representation, which introduces a phase space description for the model. The representation of the system in quantum phase space allowed us to investigate the di erence between purely classical evolution and the relative importance of quantum corrections with respect to the dynamics. The dynamics was studied by means of computer simulation techniques. The numerical simulation of the non-equilibrium statistical mechanics of both time-dependent and non-linear interactions allowed us to investigate conditions beyond those in recent literature [1, 2].
Simulations are performed of a small quantum system interacting with a quantum environment. The system consists of various initial states of two harmonic oscillators coupled to give normal modes. The environment is "designed" by its level pattern to have a thermodynamic temperature. A random coupling causes the system and environment to become entangled in the course of time evolution. The approach to a Boltzmann distribution is observed, and effective fitted temperatures close to the designed temperature are obtained. All initial pure states of the system are driven to equilibrium at very similar rates, with quick loss of memory of the initial state. The time evolution of the von Neumann entropy is calculated as a measure of equilibration and of quantum coherence. It is pointed out using spatial density distribution plots that quantum interference is eliminated only with maximal entropy, which corresponds thermally to infinite temperature. Implications of our results for the notion of "classicalizing" behavior in the approach to thermal equilibrium are briefly considered.