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arXiv:cond-mat/0105089 · Journal of Physics A Mathematical and General

Gases in two dimensions: universal thermodynamics and its consequences

Dragoş-Victor Anghel

Published Aug 13, 2002• 28 citations
arXivHTMLPDF

Abstract

I discuss ideal and interacting quantum gases obeying general fractional exclusion statistics. For systems with constant density of single-particle states, described in the mean field approximation, the entropy depends neither on the microscopic exclusion statistics, nor on the interaction. Such systems are called thermodynamically equivalent and I show that the microscopic reason for this equivalence is a one-to-one correspondence between the excited states of these systems. This provides a method, different from the bosonization technique, of transforming between systems of different exclusion statistics. In the last section the macroscopic aspects of this method are discussed. In appendix A, I calculate the fluctuation of the ground-state population of a condensed Bose gas in a grand-canonical ensemble and mean field approximation, while in appendix B I show a situation where although the system exhibits fractional exclusion properties on microscopic energy intervals, a rigorous calculation of the population of single-particle states reveals a condensation phenomenon. This also implies a malfunction of the usual and simplified calculation technique of the most probable statistical distributions.

DOI
10.1088/0305-4470/35/34/302

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I discuss ideal and interacting quantum gases obeying general fractional exclusion statistics. For systems with constant density of single-particle states, described in the mean field approximation, the entropy depends neither on the microscopic exclusion statistics, nor on the interaction. Such systems are called thermodynamically equivalent and I show that the microscopic reason for this equivalence is a one-to-one correspondence between the excited states of these systems. This provides a method, different from the bosonization technique, of transforming between systems of different exclusion statistics. In the last section the macroscopic aspects of this method are discussed. In appendix A, I calculate the fluctuation of the ground-state population of a condensed Bose gas in a grand-canonical ensemble and mean field approximation, while in appendix B I show a situation where although the system exhibits fractional exclusion properties on microscopic energy intervals, a rigorous calculation of the population of single-particle states reveals a condensation phenomenon. This also implies a malfunction of the usual and simplified calculation technique of the most probable statistical distributions.
Abstract Chapter 11 presents a statistical mechanical treatment of the quantum ideal gases, i.e., the ideal Boltzmann, fermion, and boson gases. The discussion begins with the microscopic description and the solution of the eigenvalue problem for a quantum ideal gas. It is argued that calculating the partition function is most readily accomplished in the grand canonical ensemble using a second-quantized formulation. When the particles are distinguishable, the equation of state is identical to that of a classical ideal gas. For fermions and bosons, however, the problem of computing thermodynamic properties is significantly more complex and can only be solved exactly in certain limits. Away from these limits approximations are needed and are discussed in detail. The relevant distributions - the Fermi-Dirac and Bose-Einstein distributions are derived. The local density approximation of density functional theory is derived for the ideal electron gas. For the ideal boson gas, the phenomenon of Bose-Einstein condensation is discussed
We show that fractional exclusion statistics is manifested in general in interacting systems and we discuss the conjecture recently introduced (J. Phys. A: Math. Theor. 40, F1013, 2007), according to which if in a thermodynamic system the mutual exclusion statistics parameters are not zero, then they have to be proportional to the dimension of the Hilbert space on which they act. By using simple, intuitive arguments, but also concrete calculations in interacting systems models, we show that this conjecture is not some abstract consequence of unphysical modeling, but is a natural--and for a long time overlooked--property of fractional exclusion statistics. We show also that the fractional exclusion statistics is the consequence of interaction between the particles of the system and it is due to the change from the description of the system in terms of free-particle energies, to the description in terms of the quasi-particle energies. From this result, the thermodynamic equivalence of systems of the same, constant density of states, but any exclusion statistics follows immediately.
We describe a mean field interacting particle system in any number of dimensions and in a generic external potential as an ideal gas with fractional exclusion statistics (FES). We define the FES quasiparticle energies, we calculate the FES parameters of the system and we deduce the equations for the equilibrium particle populations. The FES gas is "ideal," in the sense that the quasiparticle energies do not depend on the other quasiparticle levels' populations and the sum of the quasiparticle energies is equal to the total energy of the system. We prove that the FES formalism is equivalent to the semiclassical or Thomas Fermi limit of the self-consistent mean-field theory and the FES quasiparticle populations may be calculated from the Landau quasiparticle populations by making the correspondence between the FES and the Landau quasiparticle energies. The FES provides a natural semiclassical ideal gas description of the interacting particle gas.
We generalize the method introduced in J. Phys. A: Math. Gen. 35, 7255 (2002) based on the concept of thermodynamic equivalence and we transform a Fermi system of general density of states into a thermodynamically equivalent Bose system. This consists of mapping configurations of fermions from the original system onto configurations of bosons, the initial and final configurations having the same energy above the many-body ground state energy. In this way we obtain two systems of particles of different exclusion statistics, but which have the same entropies--and therefore identical canonical thermodynamic properties. This method enables one in general to calculate the system properties in either of the bosonic and fermionic representations. We check the method here in microscopic detail by calculating the equilibrium particle distributions in the two representations using the entropy maximization at fixed particle number and fixed ``fermionic'' and ``bosonic'' energies, respectively. Analytical calculations seem difficult to do, but we check the results numerically and we find them equal within the numerical accuracy.
I present briefly the concept of fractional exclusion statistics (FES) and I analyze two models of interacting particle systems. After I show that the models are equivalent by transforming one into the other by redefining some terms in the Hamiltonians, I calculate the heat capacity of the system and compare it with the heat capacity of an ideal Bose or Fermi gas. I show that under certain conditions the heat capacities may not be equal. I show that the interacting particle system may always be described as an ideal gas obeying FES and I show the method to construct such a gas.