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arXiv:cond-mat/0009457 · Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Relaxation in kinetic models on alternating linear chains

L.L. Gonçalves, M. López de Haro, J. Tagüeña-Martı́nez

Published Jan 25, 2001• 7 citations
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Abstract

A restricted dynamics, previously introduced in a kinetic model for relaxation phenomena in linear polymer chains, is used to study the dynamic critical exponent of one-dimensional Ising models. Both an alternating isotopic chain and an alternating-bond chain are considered. In contrast with what occurs for Glauber dynamics, in these two models the dynamic critical exponent turns out to be the same. The alternating isotopic chain with the restricted dynamics is shown to lead to Nagel scaling for temperatures above some critical value. Further support is given relating the Nagel scaling to the existence of multiple (simultaneous) relaxation processes, the dynamics apparently not playing the most important role in determining such scaling.

DOI
10.1103/physreve.63.026114

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A restricted dynamics, previously introduced in a kinetic model for relaxation phenomena in linear polymer chains, is used to study the dynamic critical exponent of one-dimensional Ising models. Both an alternating isotopic chain and an alternating-bond chain are considered. In contrast with what occurs for Glauber dynamics, in these two models the dynamic critical exponent turns out to be the same. The alternating isotopic chain with the restricted dynamics is shown to lead to Nagel scaling for temperatures above some critical value. Further support is given relating the Nagel scaling to the existence of multiple (simultaneous) relaxation processes, the dynamics apparently not playing the most important role in determining such scaling.
The dynamic critical exponent and the frequency and wave-vector dependent susceptibility of the kinetic Ising model with Glauber dynamics on an alternating isotopic chain are examined. The analysis provides to our knowledge the first connection between a microscopic model and the Nagel scaling curve originally proposed to describe dielectric susceptibility measurements of several glass-forming liquids. While support is given to the hypothesis relating the Nagel scaling to multiple relaxation processes, it is also found that the scaling function may also exhibit plateau regions and does not hold for low temperatures.
The dynamic critical exponent and the frequency and wave-vector dependent susceptibility of the kinetic Ising model on an alternating isotopic chain with Glauber dynamics are examined. The analysis provides a connection between a microscopic model and the Nagel scaling curve originally proposed to describe dielectric susceptibility measurements of several glass-forming liquids. While support is given to the hypothesis relating the Nagel scaling to multiple relaxation processes, it is also found that the scaling function may exhibit plateau regions and does not hold for all temperatures.
Nonuniversal dynamic critical exponents are obtained for both the Glauber and Kawasaki dynamics of the Ising chain with alternating near-neighbor interactions, J1{J}_{1}J1​, J2{J}_{2}J2​, with the exponents related to the ratio of the two interaction strengths. We expand upon the recent work of Droz et al. [Phys. Lett. 115A, 448 (1986)] for the ferromagnetic system (J1{J}_{1}J1​>0,J2{J}_{2}J2​>0). For Glauber (spin-flip) dynamics we obtain the exact exponent z=1+\ensuremath{\rho} (\ensuremath{\rho}\ensuremath{\equiv}\ensuremath{\Vert}J1{J}_{1}J1​/J2{J}_{2}J2​\ensuremath{\Vert}) which generalizes the result of Droz et al. and is valid irrespective of the signs of J1{J}_{1}J1​ and J2{J}_{2}J2​, where it is assumed that \ensuremath{\Vert}J1{J}_{1}J1​\ensuremath{\Vert}>\ensuremath{\Vert}J2{J}_{2}J2​\ensuremath{\Vert} (\ensuremath{\rho}\ensuremath{\ge}1). For Kawasaki (spin-exchange) dynamics, we obtain dynamic critical exponents from conventional theory which provides a rigorous lower bound for the exponent z. For the case of the conserved (ferromagnetic) order parameter, however, we present arguments that the conventional exponent is exact. We obtain z=4+\ensuremath{\rho} in this case. For J1{J}_{1}J1​>0,${J}_{2}$0 we derive the conventional exponent z=1+\ensuremath{\rho}, whereas for ${J}_{1}$0 we find z=2 irrespective of J2{J}_{2}J2​. A key aspect of this system is the narrowing of the dynamic critical region as compared with the isotropic system (J1{J}_{1}J1​=J2{J}_{2}J2​). The extra bond periodicity splits the isotropic order parameter into components such that only comparatively closer to criticality does the order parameter become the dominant slow mode. The nonuniversal critical dynamics is intrinsically linked to the nonuniform bond distribution, being shown to arise from a kinetic coefficient which vanishes with a nonuniversal critical exponent. Nonuniversality of the dynamic exponent for Ising systems with inhomogeneous couplings is argued to be specific to zero-temperature critical points.