We consider the
O(3) nonlinear sigma model with the $\ensuremath{\theta}$ term and its linear counterpart in 1+1D. The model has discrete time-reflection and space-reflection symmetries at any $\ensuremath{\theta}$, and enjoys the periodicity in $\ensuremath{\theta}\ensuremath{\rightarrow}\ensuremath{\theta}+2\ensuremath{\pi}$. At $\ensuremath{\theta}=0,\ensuremath{\pi}$ it also has a charge-conjugation
C symmetry. Gauging the discrete space-time reflection symmetries is interpreted as putting the theory on the nonorientable
RP2 manifold, after which the $2\ensuremath{\pi}$ periodicity of $\ensuremath{\theta}$ and the
C symmetry at $\ensuremath{\theta}=\ensuremath{\pi}$ are lost. We interpret this observation as a mixed 't Hooft anomaly among charge-conjugation
C, parity
P, and time-reversal
T symmetries when $\ensuremath{\theta}=\ensuremath{\pi}$. Anomaly matching implies that in this case the ground state cannot be trivially gapped, as long as
C,P, and
T are all good symmetries of the theory. We make several consistency checks with various semiclassical regimes, and with the exactly solvable XYZ model. We interpret this anomaly as an anomaly of the corresponding spin-half chains with translational symmetry, parity, and time reversal [but not involving the SO(3)-spin symmetry], requiring that the ground state is never trivially gapped, even if SO(3) spin symmetry is explicitly and completely broken. We also consider generalizations to $\mathbb{C}{P}^{N\ensuremath{-}1}$ models and show that the $C\text{\ensuremath{-}}P\text{\ensuremath{-}}T$ anomaly exists for even
N.
The ground-state and thermodynamic properties of quantum mixed-spin chains of 1/2-1/2-1-1 and 3/2-3/2-1-1 are investigated by a quantum Monte Carlo simulation with the loop-cluster algorithm. For 1/2-1/2-1-1 chain, we find it has two phases separated by an energy-gap vanishing point in the ground-state. For 3/2-3/2-1-1 chain, the numerical results show two energy-gap vanishing points isolated by different phases in its ground-state. Our calculations indicate that all these ground state phases can be understood by means of valence-bond-solid picture, and the thermodynamic behavior at finite temperatures is continuous as a function of parameter .