There was a time when the newspapers said that only twelve men understood the theory of relativity. I do not believe there ever was such a time. There might have been a time when only one man did, because he was the only guy who caught on, before he wrote his paper. But after people read the paper a lot of people understood the theory of relativity in some way or other, certainly more than twelve. On the other hand I think I can safely say that nobody understands quantum mechanics. Richard P. Feynman Introduction: the quantum theory The quantum theory was born in 1900, with the twentieth century, and future centuries will list it among our own's most remarkable achievements. Designed to account for the puzzling behavior of matter at the submicroscopic scale of individual atoms, the theory has enjoyed phenomenal success. It has accounted in a quantitative way for atomic phenomena with a numerical precision never before achieved in any field of science. When it was subsequently applied within the atom to the atomic nucleus – an object some hundred thousand times smaller – no further modification in the theory was needed. More recently, when applied within the particles making up the nucleus to describe their own internal structure – an investigation on a scale as much smaller than atoms as atoms are smaller than us – the quantum theory still shows no signs of requiring extension or revision.
There was a time when the newspapers said that only twelve men understood the theory of relativity. I do not believe there ever was such a time. There might have been a time when only one man did, because he was the only guy who caught on, before he wrote his paper. But after people read the paper a lot of people understood the theory of relativity in some way or other, certainly more than twelve. On the other hand I think I can safely say that nobody understands quantum mechanics. Richard P. Feynman Introduction: the quantum theory The quantum theory was born in 1900, with the twentieth century, and future centuries will list it among our own's most remarkable achievements. Designed to account for the puzzling behavior of matter at the submicroscopic scale of individual atoms, the theory has enjoyed phenomenal success. It has accounted in a quantitative way for atomic phenomena with a numerical precision never before achieved in any field of science. When it was subsequently applied within the atom to the atomic nucleus – an object some hundred thousand times smaller – no further modification in the theory was needed. More recently, when applied within the particles making up the nucleus to describe their own internal structure – an investigation on a scale as much smaller than atoms as atoms are smaller than us – the quantum theory still shows no signs of requiring extension or revision.
Even the experts do not understand it the way they would like to, and it is perfectly reasonable that they should not, because all of direct, human experience and of human intuition applies to large objects. Richard P. Feynman Two great intellectual triumphs occurred in the first quarter of the twentieth century: the invention of the theory of relativity, and the rather more labored arrival of quantum mechanics. The former largely embodies the ideas, and almost exclusively the vision, of Albert Einstein; the latter benefited from many creative minds, and from a constant interplay between theory and experiment. Probability plays no direct role in relativity, which is thus outside the purview and purpose of this book. However, Einstein will make an appearance in the following pages, in what some would claim was his most revolutionary role – as diviner of the logical and physical consequences of every idea that was put forward in the formative stages of quantum mechanics. It is one of the ironies of the history of science that Einstein, who contributed so importantly to the task of creating this subject, never accepted that the job was finished when a majority of physicists did. As a consequence, he participated only indirectly in the great adventure of the second quarter of the century: the use of quantum mechanics to explain the structure of atoms, nuclei, and matter.
The early twentieth century was a revolutionary time in the history of physics. People often think of Einstein's special theory of relativity of 1905, which changed our conceptions of time and space. But among physicists, quantum mechanics is usually regarded as an even more radical change in our thinking about the physical world. Quantum mechanics, which was developed between 1900 and 1926, began as a theory of atoms and light but has now become the framework in terms of which all basic physical theories are expected to be cast. We need quantum ideas not only to understand atoms, molecules, and elementary particles, but also to understand the electronic properties of solids and even certain astronomical phenomena such as the stability of white dwarf stars. The theory was radical in part because it introduced probabilistic behavior as a fundamental aspect of the world, but even more because it seems to allow mutually exclusive situations to exist simultaneously in a “quantum superposition.” We will see later that the possibility of quantum superposition is largely responsible for a quantum computer's distinctive advantage over an ordinary computer. The present chapter is devoted to introducing the basic principles of quantum mechanics. There are essentially four components of the mathematical structure of quantum mechanics. We need to know how to represent (i) states, (ii) measurements, (iii) reversible transformations, and (iv) composite systems. We will develop the first three in stages, starting with a very simple case – linear polarization of photons – and working toward the most general case.
Unlike special relativity, quantum mechanics was not the inspired product of one mind. It developed, in fits and starts, over a period of 25 years (1900–1925), and many cooks stirred the broth. Even now, a century later, quantum mechanics raises profound conceptual questions. Every competent physicist can “do” quantum mechanics, and the predictions it makes are in spectacularly good agreement with experimental results; there can be little doubt that quantum mechanics is “right.” On the other hand, as Richard Feynman once remarked, “nobody understands quantum mechanics.” I'll tell the story in two parts. First the history (how the essential pieces of the puzzle were assembled), and then the implications (what the finished picture has to say about our world). Photons Like relativity, quantum mechanics began with the study of light. In both cases, this historical association is misleading. Relativity, really, has nothing to do with light – to be sure, it involves that magic speed limit, c , and of course the most familiar thing that travels at speed c is light. So light is a convenient vehicle for introducing the subject. But it is perfectly possible to imagine a universe in which there is no such thing as light, and yet relativity might still be valid. Quantum mechanics, too, starts with light – in this case the “quantum” of light (the photon). But, as it turns out, this is just one rather specialized example of much more general principles – in fact, a rather bad example, because photons are by their nature relativistic (they travel at the speed of light), and it would be more natural to begin with the quantum mechanics of slow-moving objects, in analogy with Newtonian mechanics.
[I] think I can safely say that nobody understands quantum mechanics. Richard Feynman, The Character of Physical Law Quantum mechanics [is] that mysterious, confusing discipline, which none of us really understands but which we know how to use. It works perfectly, as far as we can tell, in describing physical reality, but it is a ‘counter-intuitive discipline’… Murray Gell-Mann, Questions for the Future [The quantum] postulate implies a renunciation as regards the causal space-time co-ordination of atomic processes. Niels Bohr, Atomic Theory and the Description of Nature It should be emphasized, however, that the probability function does not in itself represent a course of events in the course of time. It represents a tendency for events and our knowledge of events. The probability function can be connected with reality only if one essential condition is fulfilled: if a new measurement is made to determine a certain property of the system. [T]he idea of an objective real world whose smallest parts exist objectively in the same sense as stones or trees exist, independently of whether or not we observe them…is impossible … Werner Heisenberg, Physics and Philosophy [In] quantum theory it is the principle of causality , or more accurately that of determinism , which must be dropped and replaced by something else.… We now have a new form of the law of causality.… It is as follows: if in a certain process the initial conditions are determined as accurately as the uncertainty relations permit, then the probabilities of all possible subsequent states are governed by exact laws. Max Born, The Restless Universe
Applications of quantum mechanics have led to many successful predictions and explanations of puzzling phenomena, and we now apply quantum mechanics to gain, process, and communicate information in novel ways. We can understand quantum mechanics by understanding how we have applied it. We should not seek agreement on the nature of the world it represents, because this theory does not itself represent the physical world (though its applications do help us to represent it better). When applied to a quantum state, quantum mechanics yields probabiities for physical events: both state and probability are objective--not because they represent elements of phyiscal reality, but because each exerts norrmative authority over the beliefs of anyone who accepts quantum mechanics and applies it relative to a physical situation they may (but need not) occupy. These events may be described by statements that are meaningful in an appropriate environmental context, and quantum mechanics can help one to say when that is. Measurement creates an appropriate context, so here the Born rule indirectly yields probabilities of measurement outcomes. The quantum state of a system does not "collapse" on measurement: a new state must be assigned relative to a physical situation in which information about the outcome is accessible. Understood this way, there is no measurement problem, and violations of Bell inequalities does not demonstrate "spooky" non-local action. Quantum field theories have no physical ontology of their own: a quantum field is a mathematical object in a model whose application helps us to improve and extend our descriptions of the world in other terms. We cannot realise the scenario of Wigner's friend and its recent extensions: but the data that provide overwhelming evidence for quantum mechanics are objective in the same sense as the relative measurement outcomes described in those scenarios.
The difficulties of the old quantum theory were largely dispelled by the development of quantum mechanics in the 1920s. First Heisenberg (1925) developed the rather abstract matrix mechanics and soon after Schro¨dinger (1926; see also Eckart, 1926) developed the physically more appealing wave mechanics. Subsequently he showed them to be mathematically equivalent. The physicists were greatly relieved; now they had once again a mathematical formalism that enabled the results of experiments to be calculated. It was possible to move forward. It is certainly a very elegant and indeed beautiful formalism, and does enable the results of many physical measurements to be calculated with great accuracy. It is used daily by atomic and nuclear physicists; there is no other way to make calculations. From the earliest days there has been intense debate about the interpretation of quantum mechanics, and it shows no signs of being settled; if anything it is becoming more intense over the years. As Penrose has remarked, no one understands quantum mechanics. Feynman (1967; see also Sykes, 1994) also admitted that ‘nobody understands quantum mechanics’, and Einstein once remarked: ‘I have thought a hundred times as much about the quantum problems as I have about general relativity theory’ (Pais, 1994, p. 57). It should therefore be evident that the most that can be done here is to try to show where the real difficulties lie, and how the failure to recognize that quantum mechanics is an essentially statistical theory has led to a series of confusing quantum paradoxes. It is just these paradoxes that have often been used to support theological speculations. It is useful to ask what ‘understanding quantum mechanics’ actually means. Certainly it means being able to calculate the results of many measurements. The same applies to Newton’s theory of gravitation, which we understand in the sense that we can use it as a basis of calculation, although we do not really understand the gravitational force itself. Very often, especially in modern physics, the mathematical formalism does not give us the sort of intuitive physical feeling for what is going on that we often obtain from classical mechanics. Perhaps we can never achieve more than this for quantum mechanics. In classical mechanics we can assume that a property that is measured objectively exists prior to the interaction of the measuring apparatus with the observed system. Quantum mechanics, however, ‘is incompatible with the proposition that measurement discovers some unknown but pre-existing property’ (Peres, 1997, p. 14). There is an important distinction between mysteries and absurdities. We may be forced to live with mysteries, but there is no reason why we should put up with absurdities such as the wave-particle duality, tunnelling through potential barriers, acausal events and the collapse of the wave function. These are the quantum paradoxes that will be discussed later on. They arise within the Copenhagen interpretation of quantum mechanics and are solved by other interpretations. These alternative interpretations enable us to make conjectures about what is going on, even though we cannot understand it in detail. This is acceptable and a stimulus to further research. It is certainly difficult enough to understand quantum mechanics, but there is no need to try to visualize logical absurdities in the effort to do so. Quantum mechanics is a mathematical formalism that makes it possible to calculate the results of some experiments. Anything more than this, such as questions about the interpretation of what is measured and whether it tells us what is actually going on in the system being studied, belongs to philosophy. Thus we are concerned here with what is essentially a philosophical debate; if it were just a matter of physics the debate would have been settled long ago. One of the difficulties is that it invokes the results of experiments and uses the language of quantum mechanics. Inevitably this language uses philosophical terms and then it is easy to give the impression that the philosophical propositions are in some way entailed by the physical results. These in turn can influence theological thinking. In order to be quite clear which arguments are justified and which are not, it is essential to separate the three levels of discourse: physical, philosophical and theological. Our task is to relate these together, and this immediately raises the traditional problems of the philosophy of science, including the relation of experiment to theory, and of theory to explanation. We begin by discussing experiments, distinguishing between those that are real and those that are imaginary.