Optimally controlled field-free orientation of the kicked molecule (5 pages)

Brigitte F. Schmidt, Toni Kiljunen, N. Schwentner

Qian-Qian Hong, Zhe-Jun Zhang, Chuan‐Cun Shu +3 more

Alex Matos-Abiague

Carlos O Reinhold

Claude M. Dion, Arne Keller, Osman Atabek

Efficient and long-lived field-free molecular orientation is achieved using only two kicks appropriately delayed in time. The understanding of the mechanism rests upon a molecular target state providing the best efficiency versus persistence compromise. An optimal control scheme is referred to for fixing the free parameters (amplitudes and the time delay between them). The limited number of kicks, the robustness and the transposability to different molecular systems advocate in favor of the process, when considering its experimental feasibility.

Qian-Qian Hong, Zhenzhong Lian, Chuan‐Cun Shu +1 more

Generating field-free (non-stationary) orientation of molecules in space has been a longstanding goal in the field of quantum control of molecular rotation, which has significant applications in physical chemistry, chemical physics, strong-field physics, and quantum information science. In this Perspective, we review and examine several representative control schemes developed in recent years and implemented in theoretical and experimental areas for generating field-free orientation of molecules. By conducting numerical simulations of different control schemes on the same molecular system, we demonstrate that quantum coherent control, specifically targeting a limited number of the lowest-lying rotational levels to achieve an optimal superposition, can result in a high degree of orientation. To this end, we provide an overview of our latest developed analytical method, which enables the precise design of terahertz field parameters through resonant excitation. This design approach facilitates the attainment of desired field-free orientations by optimizing the amplitudes and phases of rotational wave functions for the selected rotational levels. Finally, we outlook the significance of such progress in multiple frontier research fields, highlighting its potential applications in ultracold physics, quantum computation, quantum simulation, and quantum metrology.