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Cambridge University Press eBooks

Quantum many-body theory: chemical approaches

Jorge José Kohanoff

Published Jun 29, 2006• 0 citations
Publisher
DOI
10.1017/cbo9780511755613.004

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Arrangement and chemical complexity in an NNN-body quantum system
We introduce and discuss the concept of \textit{arrangement}, traditionally found in the context of chemical reactions and few-body rearrangement collisions, in the general context of an NNN-body quantum system. We show that the ability for particles to attract and bind is a key source of complexity of an NNN-body quantum system, and \textit{arrangement} is an emergent concept necessitated by the description of this complexity. For an NNN-body system made of particles of which some or all can attract and bind, the concept of arrangement is not only necessary for a full characterization of its quantum states and processes, but it also provides a basis for the understanding and the description of the structure of its energy spectrum. We also discuss and formulate multiparticle separability in an NNN-body system, the mathematical foundation that underlies the arrangement concept in an NNN-body theory.
We construct a lattice theory describing a system of interacting nonrelativistic spin s=1/2 fermions at nonzero chemical potential. The theory is applicable whenever the interparticle separation is large compared to the range of the two-body potential and does not suffer from a sign problem. In particular, the theory could be useful in studying the thermodynamic limit of fermion systems for which the scattering length is much larger than the interparticle spacing, with applications to realistic atomic systems and dilute neutron gases.