Velocity measurements by laser resonance fluorescence. [single atom diffusional motion

W. Berres, D. Rusb�ldt, Edward Hintz +1 more

C. Y. She, Ci‐Ling Pan, John V. Prodan +1 more

Ci‐Ling Pan, She, C. Y.

This thesis describes the laser resonance fluorescence correlation technique for single-atom velocity measurement. Using this technique, we have detected individual sodium atoms diffusing through a laser beam in a slow helium flow. From the width of the fluorescence bursts detected, the transit time for the diffusing atom is determined. This is the first measurement of the motion of a single atom in a buffer gas. A probability analysis was developed which allowed us to estimate the average burst size of emitted fluorescence photons by an atom traversing the laser beam. All these results were in general agreement with the theoretical predictions. With improvements, we will be able to measure the velocity of a single-atom either in a flow or in a vacuum. By averaging over many sodium atoms, the diffusion coefficients of sodium atoms in helium and argon buffer gases were investigated using this technique. The measured diffusion coefficients were found to be in reasonable agreement with theoretical predictions and previous experimental results. To our knowledge, this is the first application of resonance fluorescence correlation technique to the measurement of diffusion coefficient of fast moving atoms in gases.

W. M. Fairbank, Chenrui Pan, C. Y. She

John V. Prodan, Fairbank, William M., She, Chiao-Yao

Using Fluorescence Correlation Spectroscopy (FCS), the motion of atoms have been measured in real time. Single sodium atoms have been detected with this method and their flow velocity crudely measured. By averaging over many atoms, very clear signals were obtained and velocities up to 85 m/sec were measured. These velocities were determined by measuring the transit time of atoms across two resonantly tuned laser beams. Diffusion constants, D, of sodium in helium, neon and argon buffer gases were also measured using FCS. The products, Dp, where p is the pressure of the buffer gas, for these three cases were determined to be 427 ± 7 Torr cm2/sec, 277 ± 10 Torr cm2/sec and 200 ± 9 Torr cm2/sec, respectively. These numbers were obtained from measuring the average duration of the fluorescence burst from individual sodium atoms diffusing through the laser beam. Also measured was the diffusion constant for the excited sodium atom (2P3/2) in a helium buffer gas at 200 Torr pressure, with a result of 598 ± 84 Torr cm2/sec.

Vanderlei Salvador Bagnato, Sérgio Carlos Zílio, U. Sao Paulo