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The Quantum Theoretical Harmonic Oscillator: Mathematical Structures

Haiko Schmarsow

Published Jan 1, 1997• 0 citations
OpenAlex

Abstract

The following text develops a new method of solving the eigenvalue problem of the quantum mechanical harmonic oscillator. Thereby are introduced new notions, like that of a reduced basis or that of a huge algebra. Furthermore are presented formulas for iterated commutation relations. Commutation Relation and Hamilton Function Oscillatory properties of a diatomic molecule, a carbon-monoxide molecule for example, can be modelled by a linear elastic oscillator. The observables for describing the oscillatory states of the oscillator are taken to be the dis- �� location from the equilibrium state and the relative momentum of the two masses.

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•Mar 3, 2017•1 citation
The following text develops a new method of solving the eigenvalue problem of the quantum mechanical harmonic oscillator. Thereby are introduced new notions, like that of a reduced basis or that of a huge algebra. Furthermore are presented formulas for iterated commutation relations. Commutation Relation and Hamilton Function Oscillatory properties of a diatomic molecule, a carbon-monoxide molecule for example, can be modelled by a linear elastic oscillator. The observables for describing the oscillatory states of the oscillator are taken to be the dis- �� location from the equilibrium state and the relative momentum of the two masses.
Until this point, we have been solving problems that involve just two states or are reducible to two-state problems. While we could examine a plethora of complex quantum phenomena, it is not sufficient to describe the behavior of electrons in atoms or how quantum particles interact with each other. That all changes now as we work to set-up the quantum mechanics of the atom. There is much for us to do before we get to the hydrogen atom. We start, in this chapter, with the simple harmonic oscillator in one dimension. We show how to determine the canonical commutation relation between position and momentum from the fact that atomic spectra have sharp lines and then move into describing free particles and free particles on a circle. We introduce two of our operator identities, the Hadamard lemma and the Baker-Campbell-Hausdorff formula and we revisit exponential disentangling, now for the symplectic group Sp(2). Then we show how to solve the harmonic oscillator energy eigenstates using operator algebra, discuss Heisenberg uncertainty, determine harmonic oscillator wavefunctions, and examine coherent and squeezed states. We end with a discussion of applications of the simple harmonic oscillator.
This original and innovative textbook takes the unique perspective of introducing and solving problems in quantum mechanics using linear algebra methods, to equip readers with a deeper and more practical understanding of this fundamental pillar of contemporary physics. Extensive motivation for the properties of quantum mechanics, Hilbert space, and the Schrödinger equation is provided through analysis of the derivative, while standard topics like the harmonic oscillator, rotations, and the hydrogen atom are covered from within the context of operator methods. Advanced topics forming the basis of modern physics research are also included, such as the density matrix, entropy, and measures of entanglement. Written for an undergraduate audience, this book offers a unique and mathematically self-contained treatment of this hugely important topic. Students are guided gently through the text by the author's engaging writing style, with an extensive glossary provided for reference and numerous homework problems to expand and develop key concepts. Online resources for instructors include a fully worked solutions manual and lecture slides.
The harmonic oscillator is a useful model for the interpretation of many physical phenomena. It is used as a first approximation to the vibration of molecules and crystal lattices and for the quantization of electromagnetic fields, among other applications. One can solve the time-independent Schrodinger equation for the harmonic oscillator in many different ways; operator methods give rise to recurrence relations and generating functions for the stationary states. The coordinate representation renders the coordinate operator diagonal. In this particular representation the eigenvectors of the harmonic oscillator are functions of the coordinate that are commonly expressed in terms of Hermite polynomials. The chapter shows that calculation with the eigenfunctions of the harmonic oscillator is remarkably simple in the realm of the Lie algebras. The application of the bosonic algebra in theoretical physics and chemistry is so vast that it is impossible even to give a reasonable summary. An important application of the bosonic algebra is the modeling of simple quantum-mechanical systems.
Harmonic oscillator model,the physical method of which enjoys wide application in other related courses is the simplest but the most important model in quantum mechanics.On one hand,profound understanding of harmonic oscillator model through various ways is crucial to understand the essence of quantum mechanics and research into micro physical models by means of quantum mechanics;on the other hand,the application of algebraic approach to solve the eigenvalues and wave function of mechanics is the main means to solve the actual problems in quantum mechanics.This paper will take harmonic oscillator as an example,and apply algebraic approach to firstly present wave function of one-dimensional harmonic oscillator,and then multi-dimensional harmonic oscillator,and also combine corresponding commutator relations of operator to present Hermite polynomials and its recursion relations,which will avoid the process of using series to solve the equation of Heimite.Meanwhile,it will improve some shortcomings revealed in the same paper.
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend
The study of quantum properties of the harmonic oscillator is important in physics as many real-world systems oscillate harmonically. Motion of systems in a confined space is often modeled as being a quantized harmonic motion or, in first instance, is approximated by a harmonic motion. This chapter helps the reader to solve the equation employing an algebraic operator technique, which is based on the Dirac notation. This approach has several definite advantages and exploits the commutation relations among the operators involved and their properties. The chapter transforms the stationary Schrodinger equation into a second-order differential equation and finds the solution to the equation with the aid of a more advanced mathematical technique that involves special functions. The energy of a harmonic oscillator is quantized, with the sequence of values. The difference in energy between adjacent energy levels is equal to the energy of a single photon, ħω.