A Consideration of the Square of Angular Momentum: L^2 = L(L+1)

Jochen Autschbach

Abstract This chapter treats rotations in three dimensions and the angular momentum quantum mechanically. The angular momentum is a 3-vector that plays the same role in the kinetic energy of rotating particles as the linear momentum 3-vector plays in the kinetic energy for translational motion. The quantum operator for the three components do not commute, i.e. the full vector cannot be known. Each component commutes with the operator for the square-length of the angular momentum vector, and therefore one opts for calculating the square-length and one of the components, z, referred to as the projection. The angular momentum is quantized. The (azimuthal) quantum number ℓ = 0,1,2,3… quantifies the square-length as ℓ(ℓ+1), and the projection is quantified by the (magnbetic) quantum number mℓ = -ℓ…ℓ in integer steps. The eigenfunctions are called spherical harmonics. A ‘rigid rotor’ model is set up to treat the rotational spectrum of a diatomic molecule.

David J. Morin

Feng Jian-chun

The solution of spherical function is given in the paper,and it is applied reasonably in the problem of eigenvalue of angular momentum square operator.

P. D. Gupta

Lele FAN, Feng Wang, Tianhai ZENG

The recent two papers have successively proposed the concepts and more precise expressions of strict conservation or statistical conservation of physical quantities, which are different from the expression of a conserved quantity in quantum mechanics. The Hamiltonian operator of the system discussed in this paper are independent of time, so it is commutative with the operators of an angular momentum itself, its component and its square, so that all these quantities are conserved quantities. In an isolated composite system, one of the angular momentum components of the total system are strictly conserved, while the angular momentum components of the subsystems can only be conserved statistically, both of which can be expressed in terms of eigenvalues and eigenfunctions. Generally, angular momentum itself does not have eigenvalues and eigenfunctions, so it cannot be expressed as strict conservation in terms of these concepts. Although there are eigenvalues and eigenfunctions for the square of angular momentum, they cannot express strict conservation either. And they can only be expressed as statistical conservation.