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Nanoscale Magnetic Field Gradients for Quantum Sensing

Toby Mitchell

Published Jul 14, 2025• 0 citations
Publisher
DOI
10.17863/cam.136129

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Abstract The nitrogen vacancy centre in diamond is a leading platform for nanoscale sensing and imaging, as well as quantum information processing in the solid state. To date, individual control of two nitrogen vacancy electronic spins at the nanoscale has been demonstrated. However, a key challenge is to scale up such control to arrays of nitrogen vacancy spins. Here, we apply nanoscale magnetic resonance frequency encoding to realize site-selective addressing and coherent control of a four-site array of nitrogen vacancy spins. Sites in the array are separated by 100 nm, with each site containing multiple nitrogen vacancies separated by ~15 nm. Microcoils fabricated on the diamond chip provide electrically tuneable magnetic field gradients ~0.1 G/nm. Tailored application of gradient fields and resonant microwaves allow site-selective nitrogen vacancy spin manipulation and sensing applications, including Rabi oscillations, imaging, and nuclear magnetic resonance spectroscopy with nanoscale resolution. Microcoil-based magnetic resonance of solid-state spins provides a practical platform for quantum-assisted sensing, quantum information processing, and the study of nanoscale spin networks.
Many-body dynamics constitutes a promising approach for creating correlations between quantum particles which can be used for applications in sensing and metrology. However, utilizing this potential for substantial gains in practical settings is a challenging task with only a very few applications realized to date. Here, we demonstrate an approach to nanoscale magnetic sensing enabled by strongly interacting electronic spins in a room temperature solid. By coherently controlling collective many-body dynamics of a dipolar ensemble of ∼104\sim 10^4∼104 nitrogen-vacancy (NV) centres in diamond with pulsed magnetic field gradients, we demonstrate practical metrological gain up to 7.9(2) dB7.9(2)\,\mathrm{dB}7.9(2)dB for magnetic signal detection and 8.8(3) dB8.8(3)\,\mathrm{dB}8.8(3)dB for magnetic noise sensing, fully accounting for experimental overheads. Finally, we combine these methods to demonstrate a momentum-space-resolved sensing modality that enables detection of spatially correlated magnetic noise at continuously tunable length scales down to 50 nanometers. These observations open the door toward practical applications of interaction-enhanced quantum sensors for nanoscale biological imaging and material characterization.
Solid-state spins in diamond are promising building blocks for quantum computing and quantum sensing, both of which require precise nanoscale addressing of individual spins. To explore the resolution limit of this approach, we demonstrate Fourier magnetic imaging of nitrogen-vacancy centers in diamond under state-of-the-art conditions. We constructed a highly compact experimental platform featuring thermal drift compensation under ambient conditions and generated a pulsed magnetic field gradient of up to 13.5 G/μμμm. By implementing the Fourier magnetic imaging protocol, we achieved localization of a single nitrogen-vacancy center with a spatial resolution of 0.28 ±\pm± 0.10 nm and a magnetic field measurement deviation of 9 nT. This technique holds potential for applications such as localizing spins within proteins and cells.