For finite-dimensional bipartite systems with additive endpoint Hamiltonians, the ergotropic gap measures the work advantage of global over independent local cyclic unitary control. We express this gap through mutual information and the Gibbs-relative entropies of the local and global passive states. The balance retains local passive-state corrections for arbitrary marginals and reduces to the established locally thermal ergotropy identity when those corrections vanish. Dropping the global correction gives a separability-independent upper bound whose exact slack is the global passive-state free-energy excess. We show that optimizing the reference temperature is equivalent to matching the Gibbs entropy to the joint-state entropy. The optimized result is precisely the equal-entropy Gibbs bound on global ergotropy minus the local ergotropies, rather than a new thermodynamic bound. We characterize saturation and temperature endpoints, including degenerate ground spaces. Werner states yield a unique implicit crossover with a separability-based majorization bound and a small-correlation bound-to-gap ratio approaching 3/2. Structured and random two-qubit comparisons illustrate complementary performance. We also specify pointwise quantum-battery applicability and the obstruction from persistent interactions.
For finite-dimensional bipartite systems with additive endpoint Hamiltonians, the ergotropic gap measures the work advantage of global over independent local cyclic unitary control. We express this gap through mutual information and the Gibbs-relative entropies of the local and global passive states. The balance retains local passive-state corrections for arbitrary marginals and reduces to the established locally thermal ergotropy identity when those corrections vanish. Dropping the global correction gives a separability-independent upper bound whose exact slack is the global passive-state free-energy excess. We show that optimizing the reference temperature is equivalent to matching the Gibbs entropy to the joint-state entropy. The optimized result is precisely the equal-entropy Gibbs bound on global ergotropy minus the local ergotropies, rather than a new thermodynamic bound. We characterize saturation and temperature endpoints, including degenerate ground spaces. Werner states yield a unique implicit crossover with a separability-based majorization bound and a small-correlation bound-to-gap ratio approaching 3/2. Structured and random two-qubit comparisons illustrate complementary performance. We also specify pointwise quantum-battery applicability and the obstruction from persistent interactions.
Continuous-variable quantum thermodynamics in the Gaussian regime provides a promising framework for investigating the energetic role of quantum correlations, particularly in optical systems. In this Letter, we introduce an entropy-free criterion for entanglement detection in bipartite Gaussian states, rooted in a distinct thermodynamic quantity: ergotropy-the maximum extractable work via unitary operations. By defining the "relative ergotropic gap," which quantifies the disparity between global and local ergotropy, we derive two independent analytical bounds that distinguish entangled from separable states. These bounds coincide for a broad class of quantum states, making the criterion both necessary and sufficient in such cases. Unlike entropy-based measures, our ergotropic approach captures fundamentally different aspects of quantum correlations and entanglement, particularly in mixed continuous-variable systems. We also extend our analysis beyond the Gaussian regime to certain non-Gaussian states and observe that Gaussian ergotropy continues to reflect thermodynamic signatures in entangled states, albeit with some limitations. These findings establish a direct operational link between entanglement and energy storage, offering an experimentally accessible approach to entanglement detection in continuous-variable optical platforms.
The paradigm of extracting work from an isolated quantum system through a cyclic Hamiltonian process is a topic of immense research interest. The optimal work extracted under such a process is termed ergotropy [Europhys. Lett. 67, 565 (2004)]. Here, in a multiparty scenario, we consider only a class of such cyclic processes that can be implemented locally, giving rise to the concept of local ergotropy. Eventually, the presence of quantum correlations results in a nonvanishing thermodynamic quantity called an ergotropic gap, measured by the difference between global and local ergotropy. However, the converse does not hold in general, i.e., its nonzero value does not necessarily imply the presence of quantum correlations. For arbitrary multiparty states, we quantify this gap. We also evaluate the difference between maximum global and local extractable work for arbitrary states when the system is no longer isolated but put in contact with a bath of the same local temperature.
We develop a thermodynamic characterization of multimode entanglement in pure continuous-variable systems by quantifying the gap between globally and locally extractable work (ergotropy). For arbitrary pure multimode Gaussian states, we prove that the 2-local ergotropic gap is a faithful entanglement monotone across any bipartition and constitutes a functionally independent upper bound to the Renyi-2 entanglement entropy. We further introduce the k-ergotropic score, the minimum k-local ergotropic gap, and show that it faithfully quantifies multimode entanglement across k partitions. For pure three-mode Gaussian states, we derive its closed-form relation with the geometric measure for genuine multimode entanglement (k=2), and total Gaussian multimode entanglement (k=3). For systems with more than three modes, the k-ergotropic score becomes a functionally independent measure of multimode entanglement to the standard geometric measures. Our results reveal a direct operational hierarchy linking Gaussian multimode entanglement to work extraction under locality constraints, and provide a computable and experimentally accessible thermodynamic framework for characterizing quantum correlations.
Extracting work from quantum system is one of the important areas in quantum thermodynamics. As a significant thermodynamic quantity, the ergotropy gap characterizes the difference between the global and local maximum extractable works. We derive an analytical upper bound of the ergotropic gap with respect to [Formula: see text] tripartite separable states. This bound also provides a necessary criterion for the separability of tripartite states. Detailed examples are presented to illustrate the efficiency of this separability criterion.
Although entropy is a necessary and sufficient quantity to characterize the order of work content for equal energetic (EE) states in the asymptotic limit, for the finite quantum systems, the relation is not so linear and requires detailed investigation. Toward this, we have considered a resource theoretic framework taking the energy preserving operations (EPOs) as free, to compare the amount of extractable work from two different quantum states. Under the EPO, majorization becomes a necessary criterion for state transformation. It is also shown that the passive-state energy is a concave function, and, for EE states, it becomes proportional to the ergotropy in absolute sense. Invariance of the passive-state energy under unitary action on the given state makes it an entanglement measure for the pure bipartite states. Furthermore, due to the nonadditivity of passive-state energy for the different system Hamiltonians, one can generate Vidal^{'}s monotones which would give the optimal probability for pure entangled state transformation. This measure also quantifies the ergotropic gap which is employed to distinguish some specific classes of three-qubit pure entangled states.
Complete dynamics and entropy balances of all proper subsystems need not determine global irreversibility. A three-qubit construction keeps one initial product state and every one- and two-qubit reduced semigroup fixed while changing only the organisation of energy-preserving shared phase events. The global entropy production changes, and the thermodynamic ranking of the full system against its proper subsystems reverses. Both trajectories remain separable, every compared score is positive, and interval bounds certify the opposite rankings.The comparison uses the finite-window Thermodynamic Criterion Index, the entropy reduction per unit outward entropy transfer. An exact lift identity determines when relational-information change exceeds the component deficit and the signed nonadditivity of entropy transfer. With common lower-order marginals and equal global export, a larger increment of irreducible higher-order information means an exactly equal reduction of global entropy production. At a common temperature and for an additive Hamiltonian, that information has a precise nonequilibrium free-energy value.Within the parity-contact model, fixed lower-order dynamics leave an explicit physical fibre of higher-order generators. Selective control inside this fibre changes a chosen collective decay rate. Two controllers with equal amounts of parity correlation can produce opposite thermodynamic rankings. Finite adaptive protocols confined to any fixed proper subsystem with private memory cannot identify the change; outcomes jointly retained from all three sites can reveal it. A certified pair of compatible generators gives nonzero lower bounds on the minimax absolute errors for global entropy production and the full-versus-proper yield gap, even with exact lower-order data. Complete lower-order descriptions therefore leave a physically controllable coordinate of global irreversibility undetermined.