Direct motional coupling of opposite-charge trapped-ion pairs could provide a pathway to extend ultra-low temperatures and quantum control to negative ions that lack the suitable electronic energy structures required for direct laser cooling. Because positive and negative ions cannot be confined within a single electrostatic potential well, I investigate a configuration where single ions are trapped in close proximity within separate potential wells to couple their motion. I analytically and numerically evaluate the electrostatic trapping requirements. As a concrete implementation, I present an optimized segmented surface Paul trap design to couple an antimatter hydrogen molecular ion () and a beryllium ion (). A motional coupling frequency of 5 kHz can be achieved at an ion–ion separation of 35m, with an ion height of 50m, axial trap frequencies of 4 MHz, and static trap voltages with a magnitude of . Finally, I outline three applications for this technique: quantum logic spectroscopy of for matter-antimatter comparisons, the preparation of cold neutral deuterium atoms via near-threshold photo-detachment of for optical trapping, and quantum information processing using equal-mass opposite-charge ion pairs.
Direct motional coupling of opposite-charge trapped-ion pairs could provide a pathway to extend ultra-low temperatures and quantum control to negative ions that lack the suitable electronic energy structures required for direct laser cooling. Because positive and negative ions cannot be confined within a single electrostatic potential well, I investigate a configuration where single ions are trapped in close proximity within separate potential wells to couple their motion. I analytically and numerically evaluate the electrostatic trapping requirements. As a concrete implementation, I present an optimized segmented surface Paul trap design to couple an antimatter hydrogen molecular ion () and a beryllium ion (). A motional coupling frequency of 5 kHz can be achieved at an ion–ion separation of 35m, with an ion height of 50m, axial trap frequencies of 4 MHz, and static trap voltages with a magnitude of . Finally, I outline three applications for this technique: quantum logic spectroscopy of for matter-antimatter comparisons, the preparation of cold neutral deuterium atoms via near-threshold photo-detachment of for optical trapping, and quantum information processing using equal-mass opposite-charge ion pairs.
Abstract Direct motional coupling of opposite-charge trapped-ion pairs could provide a pathway to extend ultra-low temperatures and quantum control to negative ions that lack the suitable electronic energy structures required for direct laser cooling. Because positive and negative ions cannot be confined within a single electrostatic potential well, I investigate a configuration where single ions are trapped in close proximity within separate potential wells to couple their motion. I analytically and numerically evaluate the electrostatic trapping requirements. As a concrete implementation, I present an optimized segmented surface Paul trap design to couple an antimatter hydrogen molecular ion ( H ¯ 2 − ) and a beryllium ion ( 9 Be + ). A motional coupling frequency of 5 kHz can be achieved at an ion–ion separation of 35 μ m, with an ion height of 50 μ m, axial trap frequencies of 4 MHz, and static trap voltages with a magnitude of ≈ 20 V . Finally, I outline three applications for this technique: quantum logic spectroscopy of H ¯ 2 − for matter-antimatter comparisons, the preparation of cold neutral deuterium atoms via near-threshold photo-detachment of D − for optical trapping, and quantum information processing using equal-mass opposite-charge ion pairs.
This Dissertation details the development of state-of-the-art hybrid atom-ion trapping architecture and technique towards increasing the quantum control of matter and the detection of chemical processes at cold temperatures. Experimental work discussed herein is performed primarily using the second-generation of the MOTion trap, a hybrid atom-ion trap consisting of a co-located magneto-optical trap (MOT) and a linear quadrupole trap (LQT), with which 40Ca and a variety of atomic and molecular ions (Yb+, Ba+, BaCl+, and others) can be co-trapped and cooled. Such a device enables the immersion of laser-cooled, ionic Coulomb crystals in diffuse gases of laser-cooled, highly-polarizable neutral atoms, allowing for studies in sympathetic cooling, cold atom-ion chemistry, and nonequilbrium collisional dynamics.In the first of these studies, I discuss our method of sympathetic cooling in which we use a laser-cooled gas of Ca atoms to sympathetically cool BaCl+ ions confined in the LQT. Because of the large polarizability of Ca, this method is found to be extremely efficient at cooling the notoriously difficult vibrational degree of freedom. This technique opens the door to research with general, ultracold, highly-localized molecular ions in the quantum ground-state which are not able to be produced using the more traditional methods of Doppler-cooling or photoassociation.In the study of cold chemistry in the hybrid trap, I characterize a fundamental reaction, known as charge exchange, at the single-particle level in which an electron is transferred from a neutral atom to an atomic ion during an inelastic collision. This low-temperature process is thought to be foundational to the chemistry leading to the formation of stars, planets and interstellar clouds in our universe. Herein I discuss how improved experimental architecture has enabled the determination of reaction rate constants for individual electronic states of the reactants.Our theoretical study of the collisional processes in hybrid atom-ion traps has led to the discovery of surprising nonequilibrium physics which exists in the hybrid trap environment. Herein I outline the collisional dynamics between neutral atoms and atomic ions in the presence of a time-dependent confining potential and describe how these dynamics manifest themselves in the emergence of nonequilbrium phenomena as indicated by bifurcations in steady-state energies of trapped ions. I show how the these dynamics can potentially limit the efficiency and overall viability of using neutral buffer gases to sympathetically cool the translational motion of trapped ions to ultracold temperatures.In addition to these experimental studies, the development of architecture is discussed with focus given to the implementation of a novel time-of-flight mass spectrometer (TOF-MS) for use with hybrid atom-ion traps as well as standard LQTs. This simple, modular device couples radially with the LQT and enables the straightforward mass analysis of trapped species without complications derived from typical experimental difficulties, engineering constraints, and financial concerns. With this robust device we precisely characterize chemical processes which can take place in these hybrid atom-ion traps. Additionally, I describe how this new architecture is used to perform the action spectroscopy of several previously unstudied molecular ions in order to further establish the field of cold molecular ion research and the widespread use of hybrid atom-ion traps.
A two-ion pair in a linear Paul trap is extensively used in the research of the simplest quantum-logic system; however, there are few quantitative and comprehensive studies on the motional mode coupling of two-ion systems yet. This study proposes a method to investigate the motional mode coupling of sympathetically cooled two-ion crystals by quantifying three-dimensional (3D) secular spectra of trapped ions using molecular dynamics simulations. The 3D resonance peaks of the 40Ca+–27Al+ pair obtained by using this method were in good agreement with the 3D in- and out-of-phase modes predicted by the mode coupling theory for two ions in equilibrium and the frequency matching errors were lower than 2%. The obtained and predicted amplitudes of these modes were also qualitatively similar. It was observed that the strength of the sympathetic interaction of the 40Ca+–27Al+ pair was primarily determined by its axial in-phase coupling. In addition, the frequencies and amplitudes of the ion pair’s resonance modes (in all dimensions) were sensitive to the relative masses of the ion pair, and a decrease in the mass mismatch enhanced the sympathetic cooling rates. The sympathetic interactions of the 40Ca+–27Al+ pair were slightly weaker than those of the 24Mg+–27Al+ pair, but significantly stronger than those of 9Be+–27Al+. However, the Doppler cooling limit temperature of 40Ca+ is comparable to that of 9Be+ but lower than approximately half of that of 24Mg+. Furthermore, laser cooling systems for 40Ca+ are more reliable than those for 24Mg+ and 9Be+. Therefore, 40Ca+ is probably the best laser-cooled ion for sympathetic cooling and quantum-logic operations of 27Al+ and has particularly more notable comprehensive advantages in the development of high reliability, compact, and transportable 27Al+ optical clocks. This methodology may be extended to multi-ion systems, and it will greatly aid efforts to control the dynamic behaviors of sympathetic cooling as well as the development of low-heating-rate quantum logic clocks.
Abstract Efficient cooling of trapped charged particles is essential in many fundamental physics experiments, for high-precision metrology, and for quantum technology. Until now, ion-ion coupling for sympathetic cooling or quantum state control has been limited to ion species with accessible optical transitions or has required close-range Coulomb interactions. To overcome this limitation and further develop scalable quantum control techniques, there has been a sustained desire to extend laser-cooling techniques to particles in macroscopically separated traps, opening quantum control techniques to previously inaccessible particles such as highly charged ions, molecular ions, and antimatter particles. Here, we demonstrate sympathetic cooling of a single proton by laser cooled Be+ ions stored in a spatially separated Penning trap. The two traps are connected by a superconducting LC circuit that enables energy exchange over a distance of 9 cm. We simultaneously demonstrate the cooling of a resonant mode of a macroscopic LC circuit with laser-cooled ions and sympathetic cooling of an individually trapped proton, reaching temperatures far below the environment temperature. Importantly, as this technique does not rely on the direct Coulomb interaction but rather on image-current interactions, it can be easily applied to an experiment with antiprotons, facilitating improved precision in matter-antimatter comparisons and dark matter searches.
In this tutorial we review the physical implementation of quantum computing using a system of cold trapped ions. We discuss systematically all the aspects for making the implementation possible. Firstly, we go through the loading and confining of atomic ions in the linear Paul trap, then we describe the collective vibrational motion of trapped ions. Further, we discuss interactions of the ions with a laser beam. We treat the interactions in the travelling-wave and standing-wave configuration for dipole and quadrupole transitions. We review different types of laser cooling techniques associated with trapped ions. We address Doppler cooling, sideband cooling in and beyond the Lamb-Dicke limit, sympathetic cooling and laser cooling using electromagnetically induced transparency. After that we discuss the problem of state detection using the electron shelving method. Then quantum gates are described. We introduce single-qubit rotations, two-qubit controlled-NOT and multi-qubit controlled-NOT gates. We also comment on more advanced multi-qubit logic gates. We describe how quantum logic networks may be used for the synthesis of arbitrary pure quantum states. Finally, we discuss the speed of quantum gates and we also give some numerical estimations for them. A discussion of dynamics on off-resonant transitions associated with a qualitative estimation of the weak coupling regime and of the Lamb-Dicke regime is included in the Appendix.
This dissertation details of the construction of and experiments performed in a hybrid system consisting of a cold neutral atomic magneto-optical trap (MOT) contained within a linear radio-frequency quadrupole ion trap (LQT). The combination of these two workhorses of atomic physics facilitates a variety of developing science such as the controlled investigation of ion-neutral quantum chemistry and the production of ground-state molecular ions. While the primary focus of this work is the production of ultracold molecular ions via sympathetic cooling, there has been investigation of cold (T ~ mK) ion-neutral charge exchange processes in two different ion-neutral pair systems. In addition, a possible method of producing ultracold homonuclear molecular ions via a photo-associative ionization (PAI) pathway is studied in the MOT. The LQT traps ions in spatial overlap with a 40Ca MOT constituting an ultracold buffer gas purposed to sympathetically cool molecular ions.An effective, general method of producing ground-state molecular ions would open a field of physics allowing, for example, precise measurements of molecular transitions which are uniquely sensitive to parity violation, or the possible variation of fundamental constants. Another promising application of cold molecular ions is an implementation of a quantum computing architecture by coupling micro-fabricated strip-line resonators to the microwave rotational transition found in many diatomic molecular ions. The molecular ion BaCl+ is chosen to be used in proof-of-principle sympathetic cooling experiments. Ultimately, a vibrational internal state thermometry experiment shows that the Ca MOT performs very efficiently at quenching the vibrational motion of the BaCl+ molecular ion.As a product of overcoming experimental challenges, this thesis discusses several experiments to characterize trapping and reaction dynamics in the hybrid system. For example, charge transfer measurements are performed with two different laser-cooled atomic ion species, Yb+ and Ba+, which are allowed and disallowed ground-state reaction, respectively. Controlled measurements of these inelastic processes test the cutting edge of quantum theory of ion-neutral interaction in both the ground-state and under optical excitation.