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Self-consistent Quantum Kinetics of Condensate and Non-condensate via a Coupled Equations of Motion Formalism

Nick P. Proukakis

Published Dec 31, 2001• 0 citations
Publisher

Abstract

This paper extends an earlier quantum kinetics treatment for dilute, weakly interacting, partially Bose-Einstein condensed gases, presented by the author elsewhere (Proukakis N P and Burnett K 1996 J. Res. Natl Inst. Stand. Technol. 101 457), by consistently treating the dynamics of the uncondensed atoms to the same level of approximation as the condensed atoms. Our method is based on a hierarchy of coupled equations of motion for the condensate mean field and fluctuations around this mean field, truncated to second order in the (effective two-body) interatomic potential, and with suitable decoupling approximations for higher-order correlations. By applying perturbation theory in the Hartree-Fock-Bogoliubov basis, we re-derive the quantum kinetic theory of Walser et al (Walser R, Williams J, Cooper J and Holland M 1999 Phys. Rev. A 59 3878), which further indicates the consistency of our treatment with the Kadanoff-Baym non-equilibrium Green function formalism for trapped gases.

DOI
10.25405/ncl.34578240

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This paper extends an earlier quantum kinetics treatment for dilute, weakly interacting, partially Bose-Einstein condensed gases, presented by the author elsewhere (Proukakis N P and Burnett K 1996 J. Res. Natl Inst. Stand. Technol. 101 457), by consistently treating the dynamics of the uncondensed atoms to the same level of approximation as the condensed atoms. Our method is based on a hierarchy of coupled equations of motion for the condensate mean field and fluctuations around this mean field, truncated to second order in the (effective two-body) interatomic potential, and with suitable decoupling approximations for higher-order correlations. By applying perturbation theory in the Hartree-Fock-Bogoliubov basis, we re-derive the quantum kinetic theory of Walser et al (Walser R, Williams J, Cooper J and Holland M 1999 Phys. Rev. A 59 3878), which further indicates the consistency of our treatment with the Kadanoff-Baym non-equilibrium Green function formalism for trapped gases.
This paper extends an earlier quantum kinetics treatment for dilute, weakly interacting, partially Bose-Einstein condensed gases, presented by the author elsewhere (Proukakis N P and Burnett K 1996 J. Res. Natl Inst. Stand. Technol. 101 457), by consistently treating the dynamics of the uncondensed atoms to the same level of approximation as the condensed atoms. Our method is based on a hierarchy of coupled equations of motion for the condensate mean field and fluctuations around this mean field, truncated to second order in the (effective two-body) interatomic potential, and with suitable decoupling approximations for higher-order correlations. By applying perturbation theory in the Hartree-Fock-Bogoliubov basis, we re-derive the quantum kinetic theory of Walser et al (Walser R, Williams J, Cooper J and Holland M 1999 Phys. Rev. A 59 3878), which further indicates the consistency of our treatment with the Kadanoff-Baym non-equilibrium Green function formalism for trapped gases.
Using the Kadanoff-Baym nonequilibrium Green's-function formalism, we derive the self-consistent Hartree-Fock-Bogoliubov (HFB) collisionless kinetic equations and the associated equation of motion for the condensate wave function for a trapped Bose-condensed gas. Our work generalizes earlier work by Kane and Kadanoff for a uniform Bose gas. We include the off-diagonal (anomalous) pair correlations, and thus we have to introduce an off-diagonal distribution function in addition to the normal (diagonal) distribution function. This results in two coupled kinetic equations. If the off-diagonal distribution function can be neglected as a higher-order contribution, we obtain the semiclassical kinetic equation recently used by Zaremba, Griffin, and Nikuni (based on the simpler Popov approximation). We discuss the static local equilibrium solution of our coupled HFB kinetic equations within the semiclassical approximation. We also verify that a solution is the rigid in-phase oscillation of the equilibrium condensate and noncondensate density profiles, oscillating with the trap frequency.
We discuss the equivalence of two nonequilibrium kinetic theories that describe the evolution of a dilute, Bose-Einstein condensed atomic gas in a harmonic trap. The second-order kinetic equations of Walser et al. [Phys. Rev. A 63, 013607 (2001)] reduce to the Gross-Pitaevskii equation and the quantum Boltzmann equation in the low- and high-temperature limits, respectively. These kinetic equations thus describe the system in equilibrium (finite temperature) as well as in nonequilibrium (real time). We have found this theory to be equivalent to the nonequilibrium Green's function approach originally proposed by Kadanoff and Baym and more recently applied to inhomogeneous trapped systems by Imamovi\ifmmode \acute{c}\else \'{c}\fi{}-Tomasovi\ifmmode \acute{c}\else \'{c}\fi{} and Griffin [in Progress in Nonequilibrium Green's Functions, edited by M. Bonitz (World Scientific, Singapore, 2000), p. 404].
Using the Kadanoff-Baym non-equilibrium Green's function formalism, we derive kinetic equations for the non-condensate atoms at finite temperatures which include the effect of binary collisions between atoms. The effect of collisions is included using the second-order self-energy given by the Beliaev (gapless) approximation. We limit our discussion to finite temperatures where we can use the single-particle Hartree-Fock spectrum for the excited atoms. In this limit, we can neglect the off-diagonal propagators (g~12\tilde{g}_{12}g~​12​ and g~21\tilde{g}_{21}g~​21​). As expected, this leads to the kinetic equations and collision integrals used in recent work by Zaremba, Nikuni, and Griffin (ZNG) [1]. We also derive a consistent equation of motion for the condensate wavefunction, involving a finite-temperature generalization of the well-known Gross-Pitaevskii equation which includes a dissipative term, as well as the mean field of the non-condensate.
In contrast with Chapter 2, in this chapter we include the dynamics of the thermal cloud. As noted in Chapter 1, we treat the noncondensate atoms using the simplest microscopic model approximation that captures the important physics. In particular, we consider only temperatures high enough ( T ≥ 0.4 T BEC ) that the noncondensate atoms can be described by a particle-like Hartree–Fock (HF) spectrum. To extend the analysis to very low temperatures is in principle straightforward (see Chapter 7). However, the details are more complicated since the excitations of the thermal cloud take on a collective aspect (i.e. a Bogoliubov-type quasiparticle spectrum must be used). In trapped Bose gases, the HF single-particle spectrum gives a good approximation down to much lower temperatures than in the case of uniform Bose gases, as first emphasized by Giorgini et al . (1997). In Section 3.1, we derive a generalized form of the Gross–Pitaevskii equation for the Bose order parameter Φ( r , t ) that is valid at finite temperatures. It involves terms that are coupled to the noncondensate component (the thermal cloud) and thus its solution in general requires one to know the equations of motion for the dynamics of the noncondensate atoms. In Section 3.2 we restrict ourselves to finite temperatures high enough that the noncondensate atoms can be described by a quantum kinetic equation for the single-particle distribution function f ( p, r , t ). A detailed microscopic derivation of this kind of kinetic equation is given in Chapters 6 and 7 using the Kadanoff–Baym Green's function formalism. A characteristic feature of a Bose-condensed gas is that the kinetic equation governing f ( p, r , t ) involves a collision integral C 12 [ f , Φ] describing collisions between condensate and noncondensate atoms.
We give an overview of the current theory of collective modes in trapped atomic gases at finite temperatures, when the dynamics of the condensate and non-condensate must both be considered. A simple introduction is given to the quantum field formulation of the dynamics of an interacting Bose-condensed system, based on equations of motion for the condensate wavefunction and single-particle Green's functions for the non-condensate atoms. We discuss the nature of excitations in the mean-field collisionless region, including the Beliaev second-order approximation for the self-energies. We also sketch the derivation of coupled two-fluid hydrodynamic equations using a simple kinetic equation which includes collisions between condensate and non-condensate atoms.