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Laser Physics Letters

Complexity of finite statistical systems

Vyacheslav I. Yukalov, Elizaveta P. Yukalova

Published Oct 1, 2026• 0 citations
Publisher

Abstract

Abstract The paper advances a novel notion–Complexity of Statistical Systems which is applicable to both, infinite systems in the thermodynamic limit as well as to finite systems, such as the systems of trapped atoms and molecules. The notion takes into account the level of ordering and the strength of correlations in the system. Illustrations are given by presenting calculations of complexity for finite systems with Bose–Einstein condensate and for superfluid systems.

DOI
10.1088/1612-202x/aeb111

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Texts and readings in physical sciences•Jan 1, 2011•2 citations
Abstract The paper advances a novel notion–Complexity of Statistical Systems which is applicable to both, infinite systems in the thermodynamic limit as well as to finite systems, such as the systems of trapped atoms and molecules. The notion takes into account the level of ordering and the strength of correlations in the system. Illustrations are given by presenting calculations of complexity for finite systems with Bose–Einstein condensate and for superfluid systems.
It is well known that the mathematically accurate description of ordering and related symmetry breaking in statistical systems requires to consider the thermodynamic limit. But the order does not appear from nowhere, and yet before the thermodynamic limit is reached, there should exist some kind of preordering that appears and grows in the process of increasing the system size. The quantitative description of growing order, under the growing system size, is developed by introducing the notion of {\it order indices}. The rigorous proof of the phase transition existence is a separate difficult problem that is not the topic of the present paper. We illustrate the approach resorting to several models in the mean-field approximation, which makes it possible to demonstrate the notion of order indices for finite systems in a clear way. We show how the order grows on the way to the thermodynamic limit for Bose-Einstein condensation, arising superconductivity, magnetization, and crystallization phenomena.
A measure of correlations for statistical systems is advanced, called correlation index. The measure is general, being applicable to quantum and classical, equilibrium and nonequilibrium statistical systems. After formulating the general notion of correlation indices for arbitrary trace-class operators, the calculation of the correlation indices are illustrated by several examples of density operators and reduced density matrices. The computation of the correlation indices for equilibrium systems is exemplified for bosonic systems with the Bose-Einstein condensate, superconducting systems, and for spin systems. Correlation indices for nonequilibrium systems are considered for nonlinear dynamics of spin and pseudospin systems.
We derive an exact recursion formula for the calculation of thermodynamic functions of finite systems obeying Bose-Einstein statistics. The formula is applicable for canonical systems where the particles can be treated as noninteracting in some approximation, e.g., like Bose-Einstein condensates in magnetic traps. The numerical effort of our computation scheme grows only linearly with the number of particles. As an example, we calculate the relative ground-state fluctuations and specific heats for ideal Bose gases with a finite number of particles enclosed in containers of different shapes.
This paper presents a study of the grand canonical Bose-Einstein (BE) statistics for a finite number of particles in an arbitrary quantum system. The thermodynamical quantities that identify BE condensation---namely, the fraction of particles in the ground state and the specific heat---are calculated here exactly in terms of temperature and fugacity. These calculations are complemented by a numerical calculation of fugacity in terms of the number of particles, without taking the thermodynamic limit. The main advantage of this approach is that it does not rely on approximations made in the vicinity of the usually defined critical temperature, rather it makes calculations with arbitrary precision possible, irrespective of temperature. Graphs for the calculated thermodynamical quantities are presented in comparison to the results previously obtained in the thermodynamic limit. In particular, it is observed that for the gas trapped in a three-dimensional box, the derivative of specific heat reaches smaller values than what was expected in the thermodynamic limit---here, this result is also verified with analytical calculations. This is an important result for understanding the role of the thermodynamic limit in phase transitions and makes possible to further study BE statistics without relying neither on the thermodynamic limit nor on approximations near critical temperature.
The notion of fluctuation indices, characterizing thermodynamic stability of statistical systems, is advanced. These indices are especially useful for investigating the stability of nonuniform and trapped atomic assemblies. The fluctuation indices are calculated for several systems with Bose-Einstein condensate. It is shown that: the ideal uniform Bose-condensed gas is thermodynamically unstable; trapped ideal gases are stable for the confining dimension larger than two; trapped gases, under the confining dimension two, are weakly unstable; harmonically trapped gas is stable only for the spatial dimension three; one-dimensional harmonically trapped gas is unstable; two-dimensional gas in a harmonic trap represents a marginal case, being weakly unstable; interacting nonuniform three-dimensional Bose-condensed gas is stable. There are no thermodynamically anomalous particle fluctuations in stable Bose-condensed systems.
The basic concepts of statistical mechanics and its application to many-body systems, phase transitions and critical phenomena will be discussed briefly in this chapter. We will be using these ideas frequently in the subsequent lectures. Statistical mechanics describes the thermodynamic behaviour of macroscopic systems from the laws which govern the behaviour of the constituent elements at the microscopic level. The microscopic elements can be atoms, molecules, dipole moments or magnetic moments, etc. A macroscopic system is generally composed of a large number of these elements (of the order of Avogadro number N A ≈ 6.022 × 1023 per mole). Each element may have a large number of internal degrees of freedom associated with different types of motion such as translation, rotation, vibration etc. The constituent elements may interact with the external field applied to the system. There can also be very complex interaction among the constituent elements. The macroscopic properties of a system in the thermodynamic limit is thus determined by the properties of the constituent molecules, their interaction with external field as well as interaction among themselves. For a system of N elements, volume V and density ρ, the thermodynamic limit is defined as lim N → ∞, lim V → ∞ keeping ρ = N/V finite. In this limit, the extensive properties of the system become directly proportional to the size of the system (N or V), while the intensive properties become independent of the size of the system.