The realization of quantum light sources is crucial for advancing quantum technologies. Two‐dimensional van der Waals (vdW) materials offer a compelling platform for ultracompact entangled photon‐pair sources due to their strong optical nonlinearities and relaxed phase‐matching constraints. Here, the generation of entangled photon pairs from vdW NbOI 2 flakes on Au film via spontaneous parametric down‐conversion (SPDC) process is demonstrated. The observed inverse relationship between second‐order correlation function and pump power and the linear relationship between coincidence rate and pump power confirm the characteristic features of SPDC process. Furthermore, the measured polarization‐dependent coincidence rate shows the anisotropic entangled photon‐pair emission in NbOI 2 crystal. The dependence of coincidence rate on flake thickness is characterized by considering both optical interference and the phase‐matching effects. The demonstrated results open new avenues for the development of on‐chip integrated quantum photonic devices for applications in quantum state engineering, quantum communication, and quantum information processing.
The realization of quantum light sources is crucial for advancing quantum technologies. Two‐dimensional van der Waals (vdW) materials offer a compelling platform for ultracompact entangled photon‐pair sources due to their strong optical nonlinearities and relaxed phase‐matching constraints. Here, the generation of entangled photon pairs from vdW NbOI 2 flakes on Au film via spontaneous parametric down‐conversion (SPDC) process is demonstrated. The observed inverse relationship between second‐order correlation function and pump power and the linear relationship between coincidence rate and pump power confirm the characteristic features of SPDC process. Furthermore, the measured polarization‐dependent coincidence rate shows the anisotropic entangled photon‐pair emission in NbOI 2 crystal. The dependence of coincidence rate on flake thickness is characterized by considering both optical interference and the phase‐matching effects. The demonstrated results open new avenues for the development of on‐chip integrated quantum photonic devices for applications in quantum state engineering, quantum communication, and quantum information processing.
Abstract Two-dimensional (2D) materials have been demonstrated as promising candidates for ultracompact entangled photon sources and on-chip integrated quantum photonic devices. Ferroelectric van der Waals materials have recently emerged as promising ultrathin sources of entangled photons via nonlinear optical processes. Here, the authors compare spontaneous parametric down conversion in NbOBr 2 and NbOI 2 , demonstrating near infrared polarization entangled photon generation and linking performance to crystal structure and optical properties. Our results extend the wavelength range of NbOX 2 -based SPDC sources and demonstrate NbOI 2 is especially suitable for near-infrared SPDC. Polarization entangled state (concurrence of 0.90 ± 0.05) can also be directly generated from NbOI 2 . Besides adding new candidates to the SPDC material library, our work provides new insight for the future generation of integrated quantum materials.
ABSTRACT The recent emergence of van der Waals (vdW) materials with exceptional optical nonlinearity has driven advances in next‐generation nonlinear photonic devices beyond classical optics. While integrating these materials into fiber‐optic platforms offers unprecedented functionalities in quantum systems, realizing telecom‐band in‐line photon‐pair sources based on highly nonlinear vdW materials remains challenging. Here, we report photon‐pair generation centered at telecom wavelength via spontaneous parametric down‐conversion in a fiber‐integrated device incorporating a ferroelectric vdW crystal, SnP 2 S 6 . Benefiting from its giant optical nonlinearity and relaxed phase‐matching across near‐visible to telecom‐band wavelengths, a remarkable nonlinear conversion efficiency of 0.07% is achieved in a few‐micrometer‐thick SnP 2 S 6 film. Moreover, the fiber‐integrated SnP 2 S 6 device delivers high‐quality photon pairs at telecom wavelengths, achieving a detected coincidence rate of 102 counts/s. The coincidence‐to‐accidental ratio reached up to 55 662, which is much larger than that of previous vdW‐material‐based sources. Furthermore, the device generates polarization‐entangled photon pairs, which are verified via quantum state tomography to exhibit fidelities of 0.97 and concurrences of 0.95. This demonstration establishes a scalable, robust fiber‐integrated platform that combines the versatility of vdW materials, paving the way toward low‐loss, functionalized quantum photonic systems for networking, sensing, and computing.
ABSTRACT The next generation of technology is rooted in quantum‐based advancements. The entangled photon pair (EPP) sources play a pivotal role in such a wide range of advancements in quantum‐based device applications, including quantum‐ high‐precision sensors, communication, computing, cryptography, and so on. The bulk nonlinear crystals continue to dominate the current landscape of EPPs generation. However, emerging 2D quantum materials have demonstrated remarkable breakthroughs in both quantum photonics, nonlinear optics, and EPPs generation compared to conventional crystals. Their phase‐matching‐free spontaneous parametric down‐conversion (SPDC), ultrashort coherence length, lowest crystal symmetry, exceptionally large and anisotropic second‐order nonlinear susceptibility (), and seamless compatibility with on‐chip, silicon‐based photonic integration positions them as highly promising candidates for EPPs generation and next‐generation quantum photonic and quantum device technologies. This review article highlights recent breakthroughs and advancements in the generation of EPPs in 2D van der Waals (vdW) materials, with a focus on their applicability to quantum technologies and plausible on‐chip quantum integrated photonic device technology. The article begins by discussing the fundamental principles of EPPs generation. It provides a comprehensive review of the origin and generation of entangled photons in emerging layered vdW materials, alongside various optical quantum characterization techniques. The review then explores key physical parameters of the quantum states associated with EPPs. Additionally, it examines concepts related to the realization of paired photon generation at the quantum limit. The final section focuses on the potential for on‐chip integrated quantum device applications. Beyond highlighting recent advancements in quantum‐based research, the review also outlines the current limitations and future prospects aimed at advancing the field.
Miniaturized quantum light sources that operate directly in optical fibers are an attractive platform for optical quantum technologies. However, most miniaturized spontaneous parametric down- conversion (SPDC) sources still rely on objective-lens-based free-space pumping and collection, which limits compactness, robustness, and direct compatibility with fiber-based systems. Here we demonstrate a lens-free in-line SPDC photon-pair source by integrating a van der Waals NbOI2 flake directly onto the end facet of an optical fiber. In this configuration, the generated photon- pairs are efficiently collected into optical fibers, eliminating the need for bulk free-space collection optics. Despite the limited numerical aperture of the single-mode fiber, efficient photon-pair collection with high purity, characterized by a coincidence-to-accidental ratio of up to ~4600, is achieved in an ultracompact configuration. These results establish van der Waals ferroelectric materials as a promising platform for fiber-integrated quantum light sources and provide a pathway toward compact, alignment-free quantum photonic devices.
Abstract Ultracompact entangled photon sources are pivotal to miniaturized quantum photonic devices. Van der Waals (vdW) nonlinear crystals promise efficient photon-pair generation and on-chip monolithic integration with nanophotonic circuitry. However, it remains challenging to generate maximally entangled Bell states of photon pairs with high purity, generation rate, and fidelity required for practical applications. Here, we realize a polarization-entangled photon-pair source based on spontaneous parametric down conversion in an ultrathin rhombohedral tungsten disulfide (3R-WS 2 ) crystal. This vdW entangled photonic source exhibits a high photon-pair purity with a coincidence-to-accidental ratio of above 800, a generation rate of 31 Hz, and two maximally polarization-entangled Bell states with fidelities exceeding 0.93 and entanglement degree over 0.97. These results stem from scalable optical nonlinearity, enhanced second-order susceptibility by electronic transitions, and a well-defined symmetry-enabled selection rule inherent in 3R-WS 2 . Our polarization entangled photon source can be integrated with photonic structures for generating more complex entangled states, thus paving an avenue for advanced quantum photonic systems toward computation and metrology.
Van der Waals (vdW) ferroelectrics are emerging nonlinear photonic materials that combine large second-order susceptibility \c{hi}(2) with heterostructure compatibility, offering an attractive route toward miniaturized spontaneous parametric down-conversion (SPDC) sources. However, vdW SPDC sources operating under continuous irradiation in air remain limited in low brightness and poor operational stability, as oxygen and moisture exposure, together with pump-induced heating, lead to material degradation and permanent damage. Here we demonstrate an air-stable, bright SPDC source based on ferroelectric NbOI2 enabled by graphene encapsulation. Graphene provides robust environmental protection and can effectively supress pump induced degradation by enhancing heat dissipation. We report a record photon-pair generation absolute rate of 258 Hz and a normalized brightness of 19,900 Hz/(mW.mm). Leveraging this stabilized platform, we further generate polarization entangled photon pairs with 94% fidelity with respect to the maximally entangled Bell states from graphene-encapsulated 90° twisted bilayer NbOI2. Our results establish a practical and air-stable vdW ferroelectric SPDC platform that overcomes key limitations of existing vdW quantum light sources and provides a viable pathway toward scalable, integrated entangled photon sources for on chip quantum photonics.