Microscopic studies on superconducting devices
Yun-Chih Liao
Superconducting circuits are one of the leading candidates for scalable quantum computation, owing to their long coherence time and compatibility with fabrication techniques. Despite their experimental success, the conventional theoretical framework for superconducting circuit quantisation relies on a semiclassical procedure that requantises the phenomenological Ginzburg-Landau order parameter, introducing the postulated canonical relations and leaving the microscopic origins of circuit parameters hidden. In the present thesis, we develop a rigorous and first-principles approach for the quantisation of superconducting circuits, directly grounded in Bardeen-Cooper-Schrieffer (BCS) theory for superconductivity, and extend this framework to investigate the dynamics of the superconducting Higgs amplitude mode. The central methodological contribution of this work is a projective approach, in which the full many-body electronic Hamiltonian of a superconducting system is projected onto a carefully constructed low-energy BCS Hilbert space, HBCS, spanned by phase parameterised BCS ground states. We systematically characterise the kinematic properties of this subspace, quantify the orthogonality and completeness of the phase basis via the BCS overlap and the projection error, and show that the effective dimensionality of the space is scaled as the square root of the number of single electronic modes. This approach does not impose a spontaneously broken symmetry so that it consistently describes quantised circuits that support superpositions of phases, and the canonical commutation relations between phase and number are derived from the underlying fermionic commutation properties, rather than imposed. This establishes the fully quantum mechanical foundation upon which the standard circuit quantisation approach implicitly rests. The projective formalism is subsequently applied to derive the effective Hamiltonian for superconducting circuit elements. For point-like elements, \eg, capacitive islands and Josephson junctions, projection of the fermionic Hamiltonian onto HBCS yields analytical expressions for the charging energy and the Josephson energy in terms of microscopic material parameters. The resulting Hamiltonian reproduces the standard Cooper-pair-box and transmon Hamiltonians, but now on an unambiguous microscopic footing. We further extend the approach to spatially distributed elements. Inductance is derived from the constitutive response to spatially varying phase torsion in a superconducting wire, yielding the lumped-element inductive energy from first principles. This analysis also identifies the emergent low-energy Hilbert space of the inductor. Combining the results, a complete microscopic derivation of the standard superconducting inductance-capacitance-junction (LCJ) circuit Hamiltonian is recovered. The final part of this thesis extends the projective methodology to the superconducting Higgs mode associated to the amplitude dynamics of the superconducting order parameter. A general BCS space parameterised by phase and gap amplitude is constructed, onto which we project the microscopic Hamiltonian. This yields a generalised eigenvalue problem governing the dynamics of the gap amplitude. The Higgs mode of a superconducting island is thereby shown to behave as a quantum harmonic oscillator. We derive the analytical expressions for the superconducting Higgs mass, spring constant, and oscillation frequency of the gap dynamics. While our results reveal a logarithmic correction to the Higgs frequency reported in previous literature, we numerically validate these results, and compute quantum anharmonic corrections to the Higgs frequency for higher excitations. This thesis proposes a novel, formal and quantitative circuit quantisation theory for superconducting circuits, based on which we explore the Higgs amplitude mode dynamics. The approach is capable of resolving the fundamental question about the compactness of superconducting phase and is extendable to cover quasiparticle contributions. This microscopic circuit theory equips us with a new tool to understand superconducting devices at a level of microscopic detail inaccessible to the standard semiclassical framework, paving the way for a principled treatment of quasiparticle losses and the exploration of exotic superconducting circuit elements.
•Aug 21, 2026•0 citations