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European Journal of Physics

Quantum analog of the classical action integral: evaluation using approximate WKB and exact energy eigenvalues in familiar (and not so familiar) bound state problems

Richard W. Robinett

Published Sep 4, 2026• 0 citations
Publisher

Abstract

Abstract Using both WKB approximation methods and complete eigenstate solutions, we examine four standard, textbook level, bound state problems in quantum mechanics. We show how the action integral from the Bohr–Sommerfeld quantization condition, extended to the WKB energy quantization condition, can be expressed in the language of semi-classical and exact quantum results. Relating classical time averaging and quantum expectation value methods, the action integral can be used to connect the average value of speed squared times period across such systems giving ⟨ v 2 ⟩ n τ n = ( n + C ~ ) ( h / m ) , where n is the bound state quantum number ( n = 0 , 1 , 2 , . . . ) supplemented by the Maslov correction ( C ~ ) . We then extend this analysis using exact results for an infinite hierarchy of potentials, one derived from the repeated supersymmetrization of the familiar infinite well, as a more mathematically sophisticated example. These discussions provide a novel pedagogical twist on h as the ‘quantum of action’, accessible at several levels of the undergraduate quantum mechanics curriculum.

DOI
10.1088/1361-6404/aea2f8

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Abstract Using both WKB approximation methods and complete eigenstate solutions, we examine four standard, textbook level, bound state problems in quantum mechanics. We show how the action integral from the Bohr–Sommerfeld quantization condition, extended to the WKB energy quantization condition, can be expressed in the language of semi-classical and exact quantum results. Relating classical time averaging and quantum expectation value methods, the action integral can be used to connect the average value of speed squared times period across such systems giving ⟨ v 2 ⟩ n τ n = ( n + C ~ ) ( h / m ) , where n is the bound state quantum number ( n = 0 , 1 , 2 , . . . ) supplemented by the Maslov correction ( C ~ ) . We then extend this analysis using exact results for an infinite hierarchy of potentials, one derived from the repeated supersymmetrization of the familiar infinite well, as a more mathematically sophisticated example. These discussions provide a novel pedagogical twist on h as the ‘quantum of action’, accessible at several levels of the undergraduate quantum mechanics curriculum.
It is well known in classical mechanics that the frequencies of a periodic system can be obtained rather easily through the action variable, without completely solving the equation of motion. Analogously, the equivalent quantum action variable appearing in the quantum Hamilton–Jacobi formalism can provide the energy eigenvalues of a bound state problem, without the necessity of solving the corresponding Schrödinger equation explicitly. This elegant and useful method is elucidated here in the context of some known and not so well-known solvable potentials. It is also shown how this method provides an understanding as to why approximate quantization schemes such as ordinary and supersymmetric WKB can give exact answers for certain potentials.
WKB theory provides a plausible link between classical mechanics and quantum mechanics in its semi-classical limit. Connecting the WKB wave function across the turning points in a quantum well, leads to the WKB quantization condition. In this work, I focus on some improvements and recent developments related to the WKB quantization condition. First I discuss how the combination of super-symmetric quantum mechanics and WKB, gives the SWKB quantization condition which is exact for a large class of potentials called shape invariant potentials. Next I turn to the fact that there is always a probability of refection when the potential is not constant and the phase of the wave function should account for this refection. WKB theory ignores refection except at turning points. I explain the work of Friedrich and Trost who showed that by including the correct "refection phase" at a turning point, the WKB quantization condition can be made to give exact bound state energies. Next I discuss the work of Cao and collaborators which takes refection of the wave function into account everywhere. We show that Cao's method provides a way to compute the F-T refection phase. Finally I discuss a paper of Fabre and Guery-Odelin who used the exponential potential to study the accuracy of WKB. In their results the accuracy deteriorates as the energy increases, which is inconsistent with Bohr's correspondence principle. Using the Friedrich and Trost method, we resolved this problem.
An algebraic reformulation of the Bohr - Sommerfeld (BS) quantization rule is suggested and applied to the study of bound states in one-dimensional quantum wells. The energies obtained with the present quantization rule are compared to those obtained with the usual BS and WKB quantization rules and with the exact solution of the Schrödinger equation. We find that, in diverse cases of physical interest in molecular physics, the present quantization rule not only yields a good approximation to the exact solution of the Schrödinger equation, but yields more precise energies than those obtained with the usual BS and/or WKB quantization rules. Among the examples considered numerically are the Poeschl - Teller potential and several anharmonic oscillator potentials, which simulate molecular vibrational spectra and the problem of an isolated quantum well structure subject to an external electric field.
Despite the seminal connection between classical multiply periodic motion and Heisenberg matrix mechanics and the massive amount of work done on the associated problem of semiclassical Einstein-Brillouin-Keller (EBK) quantization of bound states, we show that there are, nevertheless, a number of previously unexploited aspects of this relationship that bear on the quantum-classical correspondence. In particular, we emphasize a quantum variational principle that implies the classical variational principle for invariant tori. We also expose the more indirect connection between commutation relations and quantization of action variables. In the special case of a one-dimensional system a different and succinct algebraic derivation of the WKB quantization rule for bound states is given. With the help of several standard models with one or two degrees of freedom, we then illustrate how the methods of Heisenberg matrix mechanics described in this paper may be used to obtain quantum solutions with a modest increase in effort compared to semiclassical calculations. We also describe and apply a method for obtaining leading quantum corrections to EBK results. Finally, we suggest several modified applications of EBK quantization. \textcopyright{} 1996 The American Physical Society.
Solution of the Schrödinger's equation in the zero order WKB approximation is analyzed. We observe and investigate several remarkable features of the WKB0_00​ method. Solution in the whole region is built with the help of simple connection formulas we derive from basic requirements of continuity and finiteness for the wave function in quantum mechanics. We show that, for conservative quantum systems, not only total energy, but also momentum is the constant of motion. We derive the quantization conditions for two and more turning point problems. Exact energy eigenvalues for solvable and some ``insoluble'' potentials are obtained. The eigenfunctions have the form of a standing wave, Ancos⁡(knx+δn)A_n\cos(k_nx+δ_n)An​cos(kn​x+δn​), and are the asymptote of the exact solution.