The effect of bond alternation in the S z - S z coupling ( z -alternation) on the dimerization in an S =1/2 Heisenberg chain is investigated both analytically and numerically. The spin Hamiltonian is transformed into the phase Hamiltonian, and the variational method is used. An analytical study shows that the z -alternation plays an important role and brings about the dimerization when there is no bond alternation in the S x - S x and S y - S y couplings. The results of numerical diagonalization for finite systems support the above analytical conclusion.
The nature of multimagnon excitations in alternating spin/bond ferromagnetic chains are studied using a combination of scaling methods and the recursion method. Two-magnon excitations for a Heisenberg chain with either alternating spin magnitudes,
S and ${S}^{\ensuremath{'}},$ or alternating nearest-neighbor couplings,
J1 and
J2 can be studied using real-space rescaling techniques. These results are then used to investigate three-magnon excitations using the recursion method.