We discuss zero-temperature quantum spin chains in a uniform magnetic field, with axial symmetry. For integer or half-integer spin,
S, the magnetization curve can have plateaus and we argue that the magnetization per site
m is topologically quantized as $n(S\ensuremath{-}m)\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}\mathrm{integer}$ at the plateaus, where
n is the period of the ground state. We also discuss conditions for the presence of the plateau at those quantized values. For
S=3/2 and
m=1/2, we study several models and find two distinct types of massive phases at the plateau. One of them is argued to be a ``Haldane gap phase'' for half-integer
S.
The ground-state properties of a spin
S=1/2 tetrameric Heisenberg antiferromagnetic chain with alternating couplings
AF1-AF2-AF1-F (AF and F denote antiferromagnetic and ferromagnetic couplings, respectively) are studied by means of the density-matrix renormalization-group method. Two plateaus of magnetization
m are found at
m=0 and 1/4. It is shown that in such a spin-1/2 AF system, there is a gap from the singlet ground state to the triplet excited states in the absence of a magnetic field. The spin-spin correlation function decays exponentially, and the gapped states have a nonvanishing string order, which measures a hidden symmetry in the system. By a dual transformation, the string order is transformed into a ferromagnetic order and the hidden symmetry is unveiled to be a ${Z}_{2}\ifmmode\times\else\texttimes\fi{}{Z}_{2}$ discrete symmetry, which is fully broken in the gapped states. This half-integer spin Heisenberg AF chain is in a Haldane-like phase suggesting that the present findings extend the substance of Haldane's scenario. A valence-bond-solid state picture is also proposed for the gapped states.
According to Haldane’s conjecture, there is a spin gap of the excitation spectrum in integer Heisenberg spin chains whereas half-integer spin chains have a gapless excitation spectrum. In an earlier publication (Hung and Gong 2005 Phys. Rev. B 71 054413), the Haldane gap and other properties of the spin-1 system are explained using a spin-1/2 alternating bond chain model. The ferromagnetic–ferromagnetic–antiferromagnetic Heisenberg spin-1/2 chain is expected to behave similarly to the uniform spin-3/2 Heisenberg chain for strong ferromagnetic coupling. And the general nonuniform spin-1/2 chain may be used to explain the properties of the integer and half-integer high spin- S chains, consistently. In this paper, we provide a detailed numerical verification for the above problems.