We discuss the axiomatic basis of quantum mechanics and show that it is neither general nor consistent, since its axioms are incompatible with each other and moreover it does not incorporate the magnetic quantization as in the cyclotron motion. A general and consistent system of axioms is conjectured which incorporates also the magnetic quantization. 1 The neccessity of quantum mechanics (QM) was a result of experimental data for the energy spectrum of atoms which could not be explained in accord with the laws of classical mechanics. Nevertheless in the axiomatic basis of QM there are axioms which are not supported by the experimental results, since the whole system of axioms (1) is introduced only as a ”plausible generalization ” of the first axiom [1]:
We discuss the axiomatic basis of quantum mechanics and show that it is neither general nor consistent, since its axioms are incompatible with each other and moreover it does not incorporate the magnetic quantization as in the cyclotron motion. A general and consistent system of axioms is conjectured which incorporates also the magnetic quantization. 1 The neccessity of quantum mechanics (QM) was a result of experimental data for the energy spectrum of atoms which could not be explained in accord with the laws of classical mechanics. Nevertheless in the axiomatic basis of QM there are axioms which are not supported by the experimental results, since the whole system of axioms (1) is introduced only as a ”plausible generalization ” of the first axiom [1]:
The list of basic axioms of quantum mechanics as it was formulated by von Neumann includes only the mathematical formalism of the Hilbert space and its statistical interpretation. We point out that such an approach is too general to be considered as the foundation of quantum mechanics. In particular in this approach any finite-dimensional Hilbert space describes a quantum system. Though such a treatment might be a convenient approximation it can not be considered as a fundamental description of a quantum system and moreover it leads to some paradoxes like Bell's theorem. I present a list from seven basic postulates of axiomatic quantum mechanics. In particular the list includes the axiom describing spatial properties of quantum system. These axioms do not admit a nontrivial realization in the finite-dimensional Hilbert space. One suggests that the axiomatic quantum mechanics is consistent with local realism.
Quantum physics consists of a formal core that is universally agreed upon (basically being a piece of mathematics with suggestive names for concepts matching related concepts of experimental culture) and an interpretational halo (trying to make this relation more precise) that remains highly disputed even after more than 90 years of modern quantum physics. The latter is the subject of the interpretation of quantum mechanics (see Part II), where many interpretations coexist and compete for the attention of those interested in what quantum physics really means. In this chapter, an axiomatic introduction to the undisputed formal core of quantum physics is given. The axioms described present nonrelativistic quantum statistical mechanics in the Schrödinger picture. The relativistic case is outside the scope of these axioms, as it must be treated by quantum field theory; see Chapter 7. As in any axiomatic setting (necessary for a formal discipline), there are a number of different but equivalent sets of axioms or postulates that can be used to define formal quantum physics. Since they are equivalent, their choice is a matter of convenience. The choice presented here is a formulation featuring three aspects: It emphasises the similarity of quantum mechanics and classical mechanics, gives most direct access to statistical mechanics, and is free from allusions to measurement. The reason for the first is that this similarity serves as a guide to meaning. From the axiomatic setting for quantum mechanics presented below, classical mechanics (in the Koopman setting discussed in Section 7.10) is obtained by simply restricting the operators to be diagonal, so that all operations happen pointwise on the diagonal elements. Thus, multiplication is commutative, and one can identify operators and functions. In particular, the density operator degenerates into a probability density. Therefore, the quantum case appears as a generalization of the classical case allowing for noncommutativity, so that both q-observables and the density operator are (usually infinite-dimensional) operators. The reason for the second is that statistical mechanics is the main tool for applications of quantum physics to the macroscopic systems we are familiar with. The reason for the third is that realistic measurements constitute a complex process involving macroscopic detectors, hence should be explained by quantum statistical mechanics rather than be part of the axiomatic foundations themselves. (This is in marked contrast to other foundations, and distinguishes the present system of axioms.)
Following previous works by E. Prugovečki [Physica A 91A, 202 (1978) and Stochastic Quantum Mechanics and Quantum Space–time (Reidel, Dordrecht, 1986)] on common features of classical and quantum mechanics, we develop a unified mathematical framework for classical and quantum mechanics (based on L2-spaces over classical phase space), in order to investigate to what extent quantum mechanics can be obtained as a simple modification of classical mechanics (on both logical and analytical levels). To obtain this unified framework, we split quantum theory in two parts: (i) general quantum axiomatics (a system is described by a state in a Hilbert space, observables are self-adjoints operators, and so on) and (ii) quantum mechanics proper that specifies the Hilbert space as L2(Rn); the Heisenberg rule [pi,qj]=−iℏδij with p=−iℏ∇, the free Hamiltonian H=−ℏ2Δ/2m and so on. We show that general quantum axiomatics (up to a supplementary “axiom of classicity”) can be used as a nonstandard mathematical ground to formulate physical ideas and equations of ordinary classical statistical mechanics. So, the question of a “true quantization” with “ℏ” must be seen as an independent physical problem not directly related with quantum formalism. At this stage, we show that this nonstandard formulation of classical mechanics exhibits a new kind of operation that has no classical counterpart: this operation is related to the “quantization process,” and we show why quantization physically depends on group theory (the Galilei group). This analytical procedure of quantization replaces the “correspondence principle” (or canonical quantization) and allows us to map classical mechanics into quantum mechanics, giving all operators of quantum dynamics and the Schrödinger equation. The great advantage of this point of view is that quantization is based on concrete physical arguments and not derived from some “pure algebraic rule” (we exhibit also some limit of the correspondence principle). Moreover spins for particles are naturally generated, including an approximation of their interaction with magnetic fields. We also recover by this approach the semi-classical formalism developed by E. Prugovečki [Stochastic Quantum Mechanics and Quantum Space–time (Reidel, Dordrecht, 1986)].
With all its remarkable achievements, Quantum Mechanics as established in the fundamental papers written by Heisenberg, de Broglie, Schro¨dinger, Dirac, etc. contains some inconsistencies and internal contradictions. Quantum mechanics deals with quantum processes in which the number and the type of particles do not vary during their interaction, but only their energy and momentum states. The formalism of Quantum Mechanics is not capable of describing neither the variation of the number of particles, nor the transformation of one type of particle into another type. Even if in some cases the number of particles is allowed to change, this is somewhat forced and inconsistent. For example, Quantum Mechanics is not able to give a satisfactory explanation of the spontaneous emission, in which an electron situated on an excited energy level emits a quanta γ and decays to a lower energy level.
Our purpose in this chapter is to present the key concepts of quantum mechanics in the language of Hilbert spaces. The reader who has not previously met the physical ideas motivating quantum mechanics, and some of the more elementary applications of Schrödinger's equation, is encouraged to read any of a number of excellent texts on the subject such as [1–4]. Otherwise, the statements given here must to a large extent be taken on trust – not an altogether easy thing to do, since the basic assertions of quantum theory are frequently counterintuitive to anyone steeped in the classical view of physics. Quantum mechanics is frequently presented in the form of several postulates, as though it were an axiomatic system such as Euclidean geometry. As often presented, these postulates may not meet the standards of mathematical rigour required for a strictly logical set of axioms, so that little is gained by such an approach. We will do things a little more informally here. For those only interested in the mathematical aspects of quantum mechanics and the role of Hilbert space see [5–8]. Many of the standard applications, such as the hydrogen atom, will be omitted here as they can be found in all standard textbooks, and we leave aside the enormous topic of measurement theory and interpretations of quantum mechanics. This is not to say that we need be totally comfortable with quantum theory as it stands. Undoubtedly, there are some philosophically disquieting features in the theory, often expressed in the form of socalled paradoxes.