Second law of thermodynamics in closed quantum many-body systems

Ping-Xing, Chen, Jianming +5 more

Yuuya Chiba, Yasushi Yoneta, Ryusuke Hamazaki +1 more

The second law of thermodynamics for adiabatic operations -- constraints on state transitions in closed systems under external control -- is one of the fundamental principles of thermodynamics. On the other hand, it is recently established that even pure quantum states can represent thermal equilibrium. However, pure quantum states do not satisfy the second law in that they are not passive, i.e., work can be extracted from them if arbitrary unitary operations are allowed. It therefore remains unresolved how quantum mechanics can be reconciled with thermodynamics. Here, based on our key quantum-mechanical notions of thermal equilibrium and adiabatic operations, we address the emergence of the second law for adiabatic operations in the thermodynamics limit. We first introduce infinite-observable macroscopic thermal equilibrium (iMATE); a quantum state, including pure states, is in iMATE if the expectation values of all additive observables agree with their equilibrium values. We also introduce a macroscopic operation as unitary evolution generated by a time-dependent additive Hamiltonian, which is regarded as corresponding to adiabatic operations. Employing these concepts, we show that no extensive work can be extracted from any quantum state in iMATE through any macroscopic operations. Furthermore, we introduce a quantum-mechanical form of entropy density such that it agrees with thermodynamic entropy density for any quantum state in iMATE. We then prove that for any initial state in iMATE, this entropy density cannot be decreased by any macroscopic operations, followed by a time-independent relaxation process. Our theory thus proves two different forms of the second law, by adopting macroscopically reasonable classes of observables, equilibrium states, and operations. We also discuss the time scales of macroscopic operations in these results.

Masahito Ueda

Jochen Gemmer B, Alexander Otte, Günter Mahler A

We reinterpret the microcanonical conditions in the quantum domain as constraints for the interaction of the "gas subsystem" under consideration and its environment ("container"). The time average of a purity measure is found to equal the average over the respective path in Hilbert space. We then show that for typical (degenerate or nondegenerate) thermodynamical systems almost all states within the allowed region of Hilbert space have a local von Neumann entropy S close to the maximum and a purity P close to its minimum, respectively. Typically, thermodynamical systems should obey the second law.

Takahiro Sagawa

We review a general theory of thermodynamics of information processing. The background of this topic is the recently-developed nonequilibrium statistical mechanics and quantum (and classical) information theory. These theories are closely related to the modern technologies to manipulate and observe small systems; for example, macromolecules and colloidal particles in the classical regime, and quantum-optical systems and quantum dots in the quantum regime. First, we review a generalization of the second law of thermodynamics to the situations in which small thermodynamic systems are subject to quantum feedback control. The generalized second law is expressed in terms of an inequality that includes the term of information obtained by the measurement, as well as the thermodynamic quantities such as the free energy. This inequality leads to the fundamental upper bound of the work that can be extracted by a “Maxwell's demon”, which can be regarded as a feedback controller with a memory that stores measurement outcomes. Second, we review generalizations of the second law of thermodynamics to the measurement and information erasure processes of the memory of the demon that is a quantum system. The generalized second laws consist of inequalities that identify the lower bounds of the energy costs that are needed for the measurement and the information erasure. The inequality for the erasure leads to the celebrated Landauer's principle for a special case. Moreover, these inequalities enable us to reconcile Maxwell's demon with the second law of thermodynamics. In these inequalities, thermodynamic quantities and information contents are treated on an equal footing. In fact, the inequalities are model-independent, so that they can be applied to a broad class of information processing. Therefore, these inequalities can be called the second law of “information thermodynamics”.

Sebastian Deffner, Steve Campbell