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Journal of Physics Conference Series

Developing Fluorescent Nanodiamonds for Quantum Photonics

Igor I. Vlasov, Alexey M. Romshin, Dmitrii G. Pasternak, R. Kh. Bagramov, Vladimir P. Filonenko

Published Jul 1, 2026• 0 citations
Publisher

Abstract

Abstract Single photon sources (SPSs) are one of the key components in quantum communication technology. Here we report on the development of a new approach to the controlled formation of SPSs in nanodiamonds synthesized from hydrocarbons at high pressure and high temperature (HPHT). The conditions of HPHT synthesis were determined, allowing for the highly efficient production of scalable single-photon emitters based on single silicon-vacancy (SiV) centers in individual diamond particles of 250-300 nm in size. A new type of SPSs, emitting in a wide spectral range (500-800 nm) at room temperature, was found in hydrogen-terminated nanodiamonds. The recorded rate of the SPS emission exceeds 1 million photons per second. The HPHT nanodiamonds containing both SiV and the new emitters are a promising material for quantum photonics applications.

DOI
10.1088/1742-6596/3285/1/012005

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Abstract Single photon sources (SPSs) are one of the key components in quantum communication technology. Here we report on the development of a new approach to the controlled formation of SPSs in nanodiamonds synthesized from hydrocarbons at high pressure and high temperature (HPHT). The conditions of HPHT synthesis were determined, allowing for the highly efficient production of scalable single-photon emitters based on single silicon-vacancy (SiV) centers in individual diamond particles of 250-300 nm in size. A new type of SPSs, emitting in a wide spectral range (500-800 nm) at room temperature, was found in hydrogen-terminated nanodiamonds. The recorded rate of the SPS emission exceeds 1 million photons per second. The HPHT nanodiamonds containing both SiV and the new emitters are a promising material for quantum photonics applications.
The prospects of using individual nanodiamond particles as a source of single photons were studied for diamonds of various origin. It was shown that the single photon emitters could be produced on a base of "nitrogen-vacancy" centers in detonation nanodiamond synthesized from graphite-hexogen mixture. Studying meteoritic NDs we have found that single photon emitters based on "silicon-vacancy" centers could be realized even in molecular-sized diamond (less than 2 nm). Currently we are developing a new class of diamond materials, nanodiamonds synthesized from organic compounds at high pressure. In particular, we have demonstrated the possibility of synthesis of nanodiamond from its molecular analogue adamantane, controlling the size of crystallites in a wide range by changing synthesis temperature. A minimum size of obtained diamond particles about 3 nm was reached. Crystal structure of such diamonds is the most perfect in comparison with other classes of diamond materials, therefore they are the most promising material platform for production of single photon emitters.
Fluorescent emitters in diamond are considered to be a valuable resource for fields such as quantum communication, quantum photonics, and biological imaging. In this paper, we report a wide range of narrow bandwidth ( ~ 1.5 nm) spectral emission lines arising from different color centers at room temperature. The defects were created by chemical vapor deposition of thin diamond films grown on silica substrates seeded with nanoparticles of diamond and nickel. These fluorescent lines also possess single or few centers photon statistics. We correlate the zero-phonon lines, observed using confocal microscopy, with previously identified nickel-related centers which have been observed in high-pressure high-temperature diamond, with a Si/Ni complex and silicon vacancy defects. We compare our findings with recent results demonstrating single-photon emission in diamond associated with nickel-related centers to clarify and summarize previous studies concerning this specific dopant. The great variety of emission lines observed in the synthesized material, mainly associated with nickel-related centers, could be an important resource for applications relying on the presence of several emitters of single photons in the same sample. Moreover, the possibility of mass production of these centers in nanodiamonds in colloidal suspension may provide an important resource for biomarking and microscopy.
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The nanodiamond technology has developed the first packaged, single-photon source that operates at room temperature and in well-lit environments, where an ideal single-photon source produces one photon per pulse. These sources are key components for building quantum information systems that can implement quantum-key distribution (QKD) for ultrasecure communications. The optically active color centers in diamond have been found to exhibit attractive optical properties through the nitrogen-vacancy (N-V) center emission ranging 600 to 750 nm, and that have realized the practical sources of single-photon emission. Photo statistics has to be determined to measure the performance of a single-photon source, which can be measured by the autocorrelation function g2 (0) using Hanbury-Brown and Twiss interferometer. The results showed that the SPS 1.01 demonstrates stable single-photon performance without requirement of recalibration.
In fluorescence spectra of nanodiamonds (NDs) synthesized at high pressure from adamantane and other organic compounds, very narrow (~1 nm) lines of unknown origin are observed in a wide spectroscopic range from ~500 to 800 nm. Here, we propose and experimentally substantiate the hypothesis that these mysterious lines arise from radiative recombination of donor-acceptor pairs (DAPs). To confirm our hypothesis, we study the fluorescence spectra of undoped and nitrogen-doped NDs of different sizes, before and after thermal oxidation of their surface. The results obtained with a high degree of confidence allowed us to conclude that the DAPs are formed through the interaction of donor-like substitutional nitrogen present in the diamond lattice, and a 2D layer of acceptors resulting from the transfer doping effect on the surface of hydrogen-terminated NDs. A specific behavior of the DAP-induced lines was discovered in the temperature range of 100-10 K: their energy increases and most lines are split into 2 or more components with decreasing temperature. It is shown that the majority of the studied DAP emitters are sources of single photons, with an emission rate of up to >1 million counts/s at room temperature, which significantly surpasses that of nitrogen-vacancy and silicon-vacancy centers under the same detection conditions. Despite an observed temporal instability in the emission, the DAP emitters of H-terminated NDs represent a powerful room-temperature single-photon source for quantum optical technologies.
Defects in diamond have evolved as unique object for their potential application for Optical imaging and Nano-photonics. High pressure high temperature (HPHT) grown type-Ib diamond particles were milled down to the size of ~ 80 nm and purified to remove iron & graphitic carbon impurities and irradiated with 35 KeV He+ ions to create vacancies in the diamond lattice. Vacancies diffuse close to substitutional nitrogen impurities of nano-diamond particles upon thermal treatment. Characteristic sharp emission of NV centers were observed at 575.5 nm and 637.9 nm corresponding to NV° and NV− charged states in addition to a broad emission in the range 550-750 nm. Structural and photo-physical behavior of these fluorescent diamonds was found to depend on the method of purification adopted. Samples purified through acid reflux were found suitable for bio-imaging applications while, sample purified through air oxidation shows properties desirable for Nano-photonic applications. Photon-correlation measurements of emission from individual diamond nanoparticles using Hanbury Brown and Twiss interferometer (HBT) shows anti-bunching curve with g2(t)= 0 confirming their suitability as single photon source. Such sources of indistinguishable photons are highly desirable for quantum computation and quantum optics applications.