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Counting the Uncountable: A Narrative Review of Second Quantization and Feynman Diagrams, from Dirac's Oscillators to the Many-Body Problem

Zen Revista, 10 PHYSICS

Published Aug 30, 2026• 0 citations
Publisher

Abstract

Second quantization and its diagrams are field theory's working language: the occupation-number formalism—Dirac's 1927 quantized radiation, Jordan and Wigner's anticommuting fermions, Fock's space—that makes variable particle number natural, and the Feynman diagrams—the space-time pictures of 1949 whose algebra Dyson unified—that make perturbation theory drawable. This article presents a narrative review of the primary literature that built that language, from Dirac's 1927 emission and absorption quantization, Jordan and Wigner's 1928 Pauli equivalence, and Fock's 1932 configuration space, through the QED reconstruction of Tomonaga's 1946 invariant formulation, Schwinger's 1948 magnetic moment, Feynman's 1949 theory of positrons and space-time approach, and Dyson's 1949 unification, Feynman's 1962 lecture volume, Mattuck's 1976 guide to the many-body diagrams, Peskin and Schroeder's 1995 introduction, and Coleman's 2015 many-body synthesis. The synthesis is organized around three themes: the occupation-number settlement, in which variable particle number became formalism—bosonic commutators, fermionic anticommutators, Fock's space; the diagrammatic revolution, in which QED's infinities were organized into pictures with rules—and measured; and the many-body expansion, in which the same diagrams described solids, fluids, and superconductors. It is concluded that second quantization's genius is bookkeeping—particles as excitations—and that the diagrams are the bookkeeping's pictures: perturbation theory made visible, its rules the field's grammar.

DOI
10.5281/zenodo.22166691

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•Jul 25, 2019•0 citations
Second quantization and its diagrams are field theory's working language: the occupation-number formalism—Dirac's 1927 quantized radiation, Jordan and Wigner's anticommuting fermions, Fock's space—that makes variable particle number natural, and the Feynman diagrams—the space-time pictures of 1949 whose algebra Dyson unified—that make perturbation theory drawable. This article presents a narrative review of the primary literature that built that language, from Dirac's 1927 emission and absorption quantization, Jordan and Wigner's 1928 Pauli equivalence, and Fock's 1932 configuration space, through the QED reconstruction of Tomonaga's 1946 invariant formulation, Schwinger's 1948 magnetic moment, Feynman's 1949 theory of positrons and space-time approach, and Dyson's 1949 unification, Feynman's 1962 lecture volume, Mattuck's 1976 guide to the many-body diagrams, Peskin and Schroeder's 1995 introduction, and Coleman's 2015 many-body synthesis. The synthesis is organized around three themes: the occupation-number settlement, in which variable particle number became formalism—bosonic commutators, fermionic anticommutators, Fock's space; the diagrammatic revolution, in which QED's infinities were organized into pictures with rules—and measured; and the many-body expansion, in which the same diagrams described solids, fluids, and superconductors. It is concluded that second quantization's genius is bookkeeping—particles as excitations—and that the diagrams are the bookkeeping's pictures: perturbation theory made visible, its rules the field's grammar.
Scope The book focuses primarily on many-body (or better, many-electron) methods for electron correlation. These include Rayleigh–Schrödinger perturbation theory (RSPT) , particularly in its diagrammatic representation (referred to as many-body perturbation theory , or MBPT ), and coupled-cluster (CC) theory; their relationship to configuration interaction (CI) is included. Further extensions address properties other than the energy, and also excited states and multireference CC and MBPT methods. The many-body algebraic and diagrammatic methods used in electronic structure theory have their origin in quantum field theory and in the study of nuclear matter and nuclear structure. The second-quantization formalism was first introduced in a treatment of quantized fields by Dirac (1927) and was extended to fermion systems by Jordan and Klein (1927) and by Jordan and Wigner (1928). This formalism is particularly useful in field theory, in scattering problems and in the study of infinite systems because it easily handles problems involving infinite, indefinite or variable numbers of particles. The diagrammatic approach was introduced into field theory by Feynman (1949a,b) and applied to many-body systems by Hugenholtz (1957) and by Goldstone (1957). Many-body perturbation theory and its linked-diagram formalism were first introduced by Brueckner and Levinson (1955) and by Brueckner (1955), and were formalized by Goldstone (1957). Other important contributions to the methodology, first in field theory and then in the theory of nuclear structure, are due to Dyson (1949a,b), Wick (1950), Hubbard (1957, 1958a,b) and Frantz and Mills (1960). Applications to the electronic structure of atoms and molecules began with the work of Kelly (1963, 1964a,b, 1968), and molecular applications using finite analytical basis sets appeared in the work of Bartlett and Silver (1974a, b).
The formalism of the second quantization is developed entirely within the framework of the Dirac-Jordan representation theory. The equivalence of this formalism and the methods of ordinary coordinate-spin space is shown, and the equations of "connection" are fully developed. It is shown that the "creation" and "annihilation" operators, and indeed all operators which do not commute with the quantized Hamiltonian and hence whose representatives cannot be explicitly given in a configuration space of a fixed number of dimensions are easily treated in terms of the general representation theory and arise quite naturally. Both types of statistics are considered, and the Fock-Dirac density matrix and self-consistent field are treated as a simple illustration.
This is a self-contained and hopefully readable account on the method of creation and annihilation operators (also known as the Fock space representation or the "second quantization" formalism) for non-relativistic quantum mechanics of many particles. Assuming knowledge only on conventional quantum mechanics in the wave function formalism, we define the creation and annihilation operators, discuss their properties, and introduce corresponding representations of states and operators of many-particle systems. As the title of the note suggests, we cover most topics treated in sections 6.7 and 6.8 of Feynman's "Statistical Mechanics: A Set of Lectures". As a preliminary, we also carefully discuss the symmetry of wave functions describing indistinguishable particles. We note that all the contents of the present note are completely standard, and the definitions and the derivations presented here have been known to many. Although the style of the present note may be slightly more mathematical than standard physics literatures, we do not try to achieve full mathematical rigor.(Note to experts: In particular we here DERIVE the (anti)commutation relations of the creation and annihilation operators, rather than simply declaring them. In this sense our approach is quite close to that of Feynman's. But we here focus on the action of creation/annihilation operators on general NNN body wave functions, while Feynman makes a heavy use of Slater-determinant-type states from the beginning. We hope that our presentation provides a better perspective on the formalism.)
In this chapter we describe a technique to deal with identical particles that is called second quantization . Despite being a technique, second quantization helps a lot in understanding physics. One can learn and endlessly repeat newspaper-style statements particles are fields , fields are particles without grasping their meaning. Second quantization brings these concepts to an operational level. Since the procedure of second quantization is slightly different for fermions and bosons, we have to treat the two cases separately. We start with considering a system of identical bosons, and introduce creation and annihilation operators (CAPs) that change the number of particles in a given many-particle state, thereby connecting different states in Fock space. We show how to express occupation numbers in terms of CAPs, and then get to the heart of the second quantization: the commutation relations for the bosonic CAPs. As a next step, we construct field operators out of the CAPs and spend quite some time (and energy) presenting the physics of the particles in terms of these field operators. Only afterward, do we explain why all this activity has been called second quantization. In Section 3.4 we then present the same procedure for fermions, and we mainly focus on what is different as compared to bosons. The formalism of second quantization is summarized in Table 3.1.
This chapter introduces and applies the method of second quantization, a technique that underpins the formulation of quantum many-particle theories. Second quantization formalism treats systems of bosons or fermions with a fixed or variable number of particles in a unified way. The chapter reviews the key aspects of this formalism. The formalism of second quantization treats systems of bosons with a fixed or variable number of particles in a unified manner. In many physical processes, the particle number does change. Different quantum operators are expressed most naturally in different representations, which make basis changes an essential issue in quantum physics. Quantum field theory is a universal tool that has applications ranging from atomic, molecular, and particle physics to condensed matter and statistical physics as well as modern quantum chemistry. The fundamental difference between classical and quantum mechanics relates to the concept of indistinguishability of identical particles.
Abstract Chapter 2 provides a review of pertinent aspects of the quantum mechanics of systems composed of many particles. It focuses on the foundations of quantum many-particle physics, the many-particle Hilbert spaces to describe large assemblies of interacting systems composed of Bosons or Fermions, which lead to the versatile formalism of second quantization as a convenient and eminently practical language ubiquitous in the mathematical formulation of the theory of many-particle systems of quantum matter. The main objects in which the formalism of second quantization is expressed are the Bosonic or Fermionic creation and annihilation operators that become, in the position basis, the quantum field operators.