A transportable 40 Ca + optical clock with 1.6 × 10 − 15 / τ frequency instability enabled by improved magnetic shielding and comb-based frequency stability transfer
Abstract Here, we develop a compact multilayer magnetic shield for a transportable optical clock, achieving shielding factors of up to 10 5 . To improve the frequency stability of the transportable optical clock, we improved the magnetic-field environment of a transportable 40 Ca + ion optical clock (TCIOC) using the newly developed magnetic shielding system and reduced the clock-laser frequency noise by transferring the stability of an ultrastable reference laser through an optical frequency comb. These improvements enabled the coherent interrogation time to be extended from 40 ms to 320 ms . A time-interleaved self-comparison yielded a measured short-term fractional frequency instability of 1.6 × 10 − 15 / τ , close to the estimated quantum projection noise-limited instability of 1.18 × 10 − 15 / τ . Meanwhile, the uncertainty contributions associated with the DC second-order Zeeman shift and the servo error were reduced to 1.1 × 10 − 21 and 4.5 × 10 − 19 . These results provide a practical basis for further improving the performance of transportable optical clocks.
Abstract Here, we develop a compact multilayer magnetic shield for a transportable optical clock, achieving shielding factors of up to 10 5 . To improve the frequency stability of the transportable optical clock, we improved the magnetic-field environment of a transportable 40 Ca + ion optical clock (TCIOC) using the newly developed magnetic shielding system and reduced the clock-laser frequency noise by transferring the stability of an ultrastable reference laser through an optical frequency comb. These improvements enabled the coherent interrogation time to be extended from 40 ms to 320 ms . A time-interleaved self-comparison yielded a measured short-term fractional frequency instability of 1.6 × 10 − 15 / τ , close to the estimated quantum projection noise-limited instability of 1.18 × 10 − 15 / τ . Meanwhile, the uncertainty contributions associated with the DC second-order Zeeman shift and the servo error were reduced to 1.1 × 10 − 21 and 4.5 × 10 − 19 . These results provide a practical basis for further improving the performance of transportable optical clocks.
The fractional uncertainty of the 40Ca+ optical clock in our laboratory has been evaluated to be 2.2×10−17, but it is difficult to evaluate the statistical uncertainty of the output frequency at this level, limited by the frequency stability associated with the quantum projection noise (QPN). A reduction in the stability is required to shorten the averaging time for a certain statistical uncertainty level. To improve the stability, the Ramsey method is introduced in the locking process. To improve the reliability and continuity, we introduce the idea of using auxiliary Rabi probes to avoid fringe slips in the Ramsey interrogation and to automatically search for resonance. The stability of a single 40Ca+ ion frequency standard is improved from 6.3×10−15/τ to 2.5×10−15/τ, where τ is the averaging time in seconds, which is close to the QPN limit for an 80-ms-long Ramsey interrogation. We obtain a stability of 1.5×10−17 at an averaging time of 21 000 s and an uptime rate of 93.8% for a 34-h-long run. These methods can easily be applied to other ion or neutral atom optical clocks.
Entangled states hold the promise of improving the precision and accuracy of quantum sensors. We experimentally demonstrate that spectroscopy of an optical clock transition using entangled states can outperform its classical counterpart. Two ^{40}Ca^{+} ions are entangled in a quantum state with vanishing first-order magnetic field sensitivity, extending the coherence time of the atoms and enabling near-lifetime-limited probe times of up to 550 ms. In our protocol, entangled ions reach the same instability as uncorrelated ions, but at half the probe time, enabling faster cycle times of the clock. We run two entangled ^{40}Ca^{+} ions as an optical clock and compare its frequency instability with a ^{87}Sr lattice clock. The instability of the entangled ion clock is below a clock operated with classically correlated states for all probe times. We observe instabilities below the theoretically expected quantum projection noise limit of two uncorrelated ions for interrogation times below 100 ms. The lowest fractional frequency instability of 7×10^{-16}/sqrt[τ/1 s] is reached for 250 ms probe time, limited by residual phase noise of the probe laser. This represents the lowest instability reported to date for a ^{40}Ca^{+} ion clock.
Progress of the 40Ca+ ion optical clock based on the 42S1/2 – 3d 2D5/2 electric quadrupole transition is reported. By setting the drive frequency to the “magic” frequency Ω 0, the frequency uncertainty caused by the scalar Stark shift and second-order Doppler shift induced by micromotion is reduced to the 10−19 level. By precisely measuring the differential static scalar polarizability Δα 0, the uncertainty due to the blackbody radiation (BBR) shift (coefficient) is reduced to the 10−19 level. With the help of a second-order integrating servo algorithm, the uncertainty due to the servo error is reduced to the 10−18 level. The total fractional uncertainty of the 40Ca+ ion optical clock is then improved to 2.2× 10−17, whereas this value is mainly restricted by the uncertainty of the BBR shift due to temperature fluctuations. The state preparation is introduced together with improvements in the pulse sequence, and furthermore, a better signal to noise ratio (SNR) and less dead time are achieved. The clock stability of a single clock is improved to 4.8 × 10 − 15 / τ ( in seconds ) .
At the time of writing, state of the art stationary optical clocks reach 10 −18 sys- tematic fractional frequency uncertainty, which allows for the search of new physics beyond the standard model and lays the foundation for new applications such as chronometric leveling, where height differences relative to the geoid are derived from frequency comparisons among optical clocks. Transportable optical clocks allow for chronometric leveling between distant lo- cations which are not connected by a direct line of sight but via length stabilized optical fiber. Moreover, they facilitate frequency comparisons between distant sta- tionary clocks via subsequent side-by-side comparisons without the necessity of a long-range fiber connection. A transportable optical clock employing a single 40Ca+ ion has been reported and a neutral atom 87Sr lattice clock has been employed in a chronometric leveling campaign. However, these clocks report an estimated systematic fractional frequency uncertainty in the high 10^−17 range, which limits their height resolution to a level of approximately 1 m. 27Al+ has one of the smallest blackbody radiation shifts, small linear and quadratic Zeeman shifts and a negligible quadrupole shift, which makes it a candidate for a highly accurate optical clock. This thesis reports on the development, set-up, and characterization of a transportable 27Al+ clock setup with 40Ca+ as logic ion. The setup is simple, modular, compact, and mechanically stable. Ions of both species are generated via pulsed laser ablation and subsequent photoionization. They are confined in a multi-layer trap with segmented loading and experiment zones. Using a single 40Ca+ ion as probe, heating rates of below 10 quanta per second have been measured in all three directions for trap frequencies around 2π × 2 MHz, and pulsed sideband cooling to mean motional quantum numbers below 0.1 quanta was demonstrated. Imaging close to the diffraction limit with a signal to noise ratio of 800 for 300 ms exposure time on a sCMOS camera was achieved using a single NA = 0.51 biaspheric lens. Simultaneously, a state discrimination error below 10^−5 in 100 µs was obtained using a PMT. From the excess micromotion second order Doppler shift, secular motion second order Doppler shift, BBR shift, and background gas collision shift, a partial systematic fractional frequency uncertainty of 1.7 × 10^−18 was inferred, which is equivalent to a height resolution of ca. 2 cm. Moreover, a highly stable mechanical monolithic enhancement cavity for SHG has been developed and demonstrated to withstand accelerations of 3 g rms for 30 min. It has been operated for an uninterrupted period of 130 h without decay in output power in the mid-UV due to O2 -purging, its sealed design, and material selection, which solves the often observed crystal degradation in UV applications. The cavity has been employed in the 27Al+ logic laser system. In conclusion, it has been shown that an 27Al+ ion quantum logic optical clock operated in the present transportable setup could reach an estimated systematic fractional frequency uncertainty of 1.7 × 10^−18 , provided that all other shifts, such as the second order Zeeman shift, are negligible. This paves the way towards chronometric leveling with an unprecedented height resolution of about 2 cm.
A number of optical frequency standards have been evaluated with fractional uncertainties between ${10}^{\ensuremath{-}17}$ and ${10}^{\ensuremath{-}18}$. Reduction of the statistical uncertainty of a clock comparison to this level is challenging, requiring the best possible stability to avoid excessively long averaging times. We report recent improvements of our 88Sr+ single-ion standard that have reduced its 1-s Allan deviation from $1\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}14}$ to $3\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}15}$, yielding an order of magnitude decrease in averaging time for a given statistical uncertainty level. Among the improvements made are the implementation of a clear-out laser that transfers the ion from the metastable state to the ground state at each cycle, followed by a state preparation step that transfers the ion to the ground-state magnetic sublevel of the probed transition. With these changes, the ion clock transition interacts with the probe laser at every interrogation cycle. The stability of our optical standard is essentially limited by the quantum projection noise for pulse lengths up to $\ensuremath{\approx}100$ ms.
Direct comparison of multi-ion optical clocks based on 40Ca+ and 88Sr+
We report the first direct frequency comparison between two multi-ion optical clocks based on the S1/2 to D5/2 transition in \Ca and \Sr ions. Using linear chains of up to nine \Ca ions and six \Sr ions, we demonstrate improved stability as a function of the number of ions that are contributing to the laser frequency stabilization servo. The measured joint fractional frequency stability of the two clocks reaches 1.37(12)×10−15 at one second, placing an upper bound on the same stability of one of the clocks at 9.6(8)×10−16 in one second. We measured the frequency ratio of the two clocks to be RSr/Ca=1.082076536381896986(18), where the systematic uncertainty is primarily limited by the room temperature blackbody radiation. Our direct measurement represents an order of magnitude improvement compared to existing indirect frequency ratio measurements. Furthermore, by combining our results with recent absolute frequency measurements of the \Sr transition, referenced to a primary frequency standard, we refined the absolute frequency of the \Ca transition to νCa+=411042129776400.21(4) Hz, reducing its uncertainty by a factor of three. This study presents the first direct comparison between two multi-ion optical clocks, highlighting their significant potential for future applications in fundamental physics tests, geodesy, and precision metrology.