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Lecture notes in electrical engineering

5S—5D Two-Photon Spectroscopy in Warm Rubidium Vapour

Adrian Wyngaard, Kessie Govender, Rory Adriaan Pentz, Vipin Balyan

Published Jan 1, 2026• 0 citations
Publisher
DOI
10.1007/978-981-92-1030-5_28

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Heterodyne Doppler-free spectroscopy, previously demonstrated on single-photon resonances (heterodyne saturation spectroscopy), has been extended to two-photon transitions in rubidium (5S-5D and 5S-7S). It provides a simple method of observing the two-photon dispersion lineshape directly. The noticeable sensitivity of this absorption technique, which has been used for an optical measurement of the hyperfine structure of the 5D level, is discussed in comparison with that currently obtained in two-photon-induced fluorescence.
In this paper, we describe two complementary nonlinear spectroscopy methods which both allow one to achieve Doppler-free spectra of atomic gases. First, saturated absorption spectroscopy is used to investigate the structure of the 5S 1/2 → 5P 3/2 transition in rubidium. Using a slightly modified experimental setup, Doppler-free two-photon absorption spectroscopy is then performed on the 5S 1/2 → 5D 5/2 transition in rubidium, leading to accurate measurements of the hyperfine structure of the 5D 5/2 energy level. In addition, electric dipole selection rules of the two-photon transition are investigated, first by modifying the polarization of the excitation laser, and then by measuring two-photon absorption spectra when a magnetic field is applied close to the rubidium vapour. All experiments are performed with the same grating-feedback laser diode, providing an opportunity to compare different high-resolution spectroscopy methods using a single experimental setup. Such experiments may acquaint students with quantum mechanics selection rules, atomic spectra and Zeeman effect.