The quasiparticle density observed in low-temperature superconducting circuits is several orders of magnitude larger than the value expected at thermal equilibrium. The tunneling of this excess of quasiparticles across Josephson junctions is recognized as one of the main loss and decoherence mechanisms in superconducting qubits. Here we present a unified impedance theory that accounts for quasiparticle energy loss in circuit regions both far from and near to (across) junctions. Our theory leverages the recent experimental demonstration that the excess quasiparticles are in quasiequilibrium [Connolly et al., Phys. Rev. Lett. 132, 217001 (2024)] and uses a generalized fluctuation-dissipation theorem to predict the amount of charge and flux noise generated by them. We compute the resulting energy relaxation time
T1 in transmon qubits with and without junction asymmetric gap engineering, and show that quasiparticles residing away from junctions can play a dominant role in the former case. They also may provide an upper limit for resonator quality factors if the density of amorphous two-level systems is reduced. In addition, we show that charge noise from quasiparticles leads to flux noise that is logarithmic in frequency, giving rise to a ``nearly white'' contribution that is comparable to the flux noise observed in flux qubits. This contrasts with amorphous two-level systems, whose associated flux noise is shown to be super-Ohmic. We discuss how this quasiparticle flux noise can limit ${T}_{2}^{\ensuremath{\ast}}$ coherence times in flux-tunable qubits. The final conclusion is that asymmetric gap engineering can greatly reduce noise and increase coherence times in superconducting qubits.
Impurity spins randomly distributed at the surfaces and interfaces of superconducting wires are known to cause flux noise in superconducting quantum interference devices (SQUIDs), providing a dominant mechanism for decoherence in flux-tunable superconducting qubits. While flux noise is well characterized experimentally, the microscopic model underlying spin dynamics remains a great puzzle. The main problem is that first-principles theories based on an integration of the quantum Heisenberg equations of motion for interacting spins are too computationally expensive to capture spin diffusion over large length scales, hindering comparisons between microscopic models and experimental data. In contrast, third-principles approaches lump spin dynamics into a single phenomenological spin-diffusion operator $D{\ensuremath{\nabla}}^{2}$ that is not able to describe the quantum noise regime and connect to microscopic models and different disorder scenarios such as spin clusters. Here we propose an intermediate ``second-principles'' method to describe general spin dissipation and flux noise in the quantum regime. It leads to the interpretation that flux noise arises from the density of paramagnon excitations at the edge of the superconducting wire, with paramagnon-paramagnon interactions leading to spin diffusion, and interactions between paramagnons and other degrees of freedom such as phonons, electrons, and two-level systems leading to spin energy relaxation. At high frequency $\ensuremath{\omega}$, we obtain an upper bound for flux noise, showing that the (super)Ohmic noise observed in experiments is not originating from interacting spin impurities. We apply the method to Heisenberg models in two-dimensional square lattices with a random distribution of vacancies, with nearest-neighbor spins coupled by a constant exchange. Explicit numerical calculations of flux noise show that it follows the observed power law $A/{\ensuremath{\omega}}^{\ensuremath{\alpha}}$, with amplitude
A and exponent $\ensuremath{\alpha}$ depending on temperature and inhomogeneities such as spatial confinement and disorder. These results are compared to experiments in niobium and aluminum devices. The method establishes a connection between flux noise experiments and microscopic Hamiltonians with the goal of identifying relevant microscopic mechanisms and guiding strategies for reducing flux noise.
The simplest model for superconductor electrodynamics are the London equations, which treats the impact of electromagnetic fields on the current density as a localized phenomenon. However, the charge carriers of superconductivity are quantum mechanical objects, and their wavefunctions are delocalized within the superconductor, leading to non-local effects. The Pippard equation is the generalization of London electrodynamics which incorporates this intrinsic non-locality through the introduction of a new superconducting characteristic length, \xi_0, called the Pippard coherence length. When building nano-scale superconducting devices, the inclusion of the coherence length into electrodynamics calculations becomes paramount. In this thesis, we provide numerical calculations of various electrodynamic quantities of interest in the non-local regime, and discuss their implications for building superconducting devices. We place special emphasis on Superconducting QUantum Inteference Devices (SQUIDs), and their usage as flux quantum bits (qubits) in quantum computation. One of the main limitations of these flux qubits is the presence of intrinsic flux noise, which leads to decoherence of the qubits. Although the origin of this flux noise is not known, there is evidence that it is related to spin impurities within the superconducting material. We present calculations which show that the flux noise in the non-local regime is signi cantly different from the local case. We also demonstrate that non-local electrodynamics greatly affect the self-inductance of the qubit.
Superconducting Quantum Interference Devices (SQUIDs) and other superconducting circuits are limited by intrinsic flux noise with spectral density
1/fα with
α<1 whose origin is believed to be due to spin impurities. Here we present a theory of flux noise that takes into account the vectorial nature of the coupling of spins to superconducting wires. We present explicit numerical calculations of the flux noise power (spectral density integrated over all frequencies) for electron impurities and lattice nuclear spins under several different assumptions. The noise power is shown to be dominated by surface electron spins near the wire edges, with bulk lattice nuclear spins contributing
∼5% of the noise power in aluminum and niobium wires. We consider the role of electron spin phase transitions, showing that the spin-spin correlation length (describing e.g. the average size of ferromagnetic spin clusters) greatly impacts the scaling of flux noise with wire geometry. Remarkably, flux noise power is exactly equal to zero when the spins are polarized along the flux vector direction, forming what we call a poloidal state. Flux noise is non-zero for other spin textures, but gets reduced in the presence of correlated ferromagnetic fluctuations between the top and bottom wire surfaces, where the flux vectors are antiparallel. This demonstrates that engineering spin textures and/or inter-surface correlation provides a method to reduce flux noise in superconducting devices.
For over three decades, the presence of magnetic flux noise with a power spectral density scaling roughly as
SPhi(f)propto1/falpha, where
alphalesssim1, has been known to limit the low-frequency performance of dc superconducting quantum interference devices (SQUIDs). In recent years, experiments indicate that this same noise persists to frequencies up to 1~GHz and is a dominant source of dephasing in flux-sensitive superconducting quantum bits (qubits). Thus, the reduction of flux noise presents a major hurdle towards the successful realization of scalable quantum computers that are based on flux-based qubits. In this thesis, we present experimental measurements, theoretical analyses, and numerical simulations that support a more detailed understanding of both the microscopic and macroscopic properties of flux noise.Our experimental work begins with flux noise measurements of a large number of SQUIDs in the temperature range from 0.1~K to 4~K. We report on measurements of ten SQUIDs with systematically varied geometries and show that
alpha increases as the temperature is lowered; in so doing, each spectrum pivots about a nearly constant frequency. The mean square flux noise, inferred by integrating the power spectra, grows rapidly with temperature and at a given temperature is approximately independent of the outer dimension of a given SQUID washer. We show that these results are incompatible with a model based on the random reversal of independent, spins that are located at the surface of the SQUID washer.In the course of our flux noise measurements, we became aware of a spurious contribution to low-frequency critical current noise in Josephson junctions---normally attributed to charge trapping in the barrier---arising from temperature instabilities inherent in cryogenic systems. These temperature fluctuations modify the critical current via its temperature dependence. By computing cross-correlations between measured temperature and critical current noise in Al-AlOx-Al junctions, we show that, despite excellent temperature stability, temperature fluctuations induce observable critical current fluctuations. Particularly, because
1/f critical current noise has decreased with improved fabrication techniques in recent years, it is important to understand and eliminate this additional noise source.Next, we introduce a numerical method of calculating the mean square flux noise
Phisq from independently fluctuating spins on the surface of thin-film loops of arbitrary geometry. By reciprocity,
Phisq is proportional to
langleBbf(rbf)2rangle, where
Bbf(rbf) is the magnetic field generated by a circulating current around the loop and
rbf varies over the loop surface. By discretizing the loop nonuniformly, we efficiently and accurately compute the current distribution and resulting magnetic field, which may vary rapidly across the loop. We use this method to compute
Phisq in a number of scenarios in which we systematically vary physical parameters of the loop. We compare our simulations to an earlier analytic result predicting that
PhisqproptoR/W in the limit where the loop radius
R is much greater than the linewidth
W. We further show that the previously neglected contribution of edge spins to
Phisq is significant---even dominant---in narrow-linewidth loops.To calculate theoretical dephasing rates in qubits, we consider flux noise with a spectral density
SPhi(f)=A2/(f/1 hboxHz)alpha, where
A is of the order of 1~
muPhi0,hboxHz−1/2 and
0.6leqalphaleq1.2;
Phi0 is the flux quantum. For a qubit with an energy level splitting linearly coupled to the applied flux, our calculations of the dependence of the pure dephasing time
tauphi of Ramsey and echo pulse sequences on
alpha for fixed
A show that
tauphi decreases rapidly as
alpha is reduced. We find that
tauphi is relatively insensitive to the noise bandwidth,
f1leqfleqf2, for all
alpha provided the ultraviolet cutoff frequency
f2>1/tauphi. We calculate the ratio
tauphi,E/tauphi,R of the echo (
E) and Ramsey (
R) sequences, and the dependence of the decay function on
alpha and
f2. We investigate the case in which
SPhi(f0) is fixed at the ``pivot frequency''
f0neq1~Hz while
alpha is varied, and find that the choice of
f0 can greatly influence the sensitivity of
tauphi,E and
tauphi,R to the value of
alpha.Finally, we conclude with a brief review of our principal results and conclusions. We also comment on promising avenues of future research.
Superconducting quantum interference devices (SQUIDs) and other superconducting circuits are limited by intrinsic flux noise with spectral density $1/{f}^{\ensuremath{\alpha}}$ with $\ensuremath{\alpha}<1$ whose origin is believed to be due to spin impurities. Here, we present a theory of flux noise that takes into account the vectorial nature of the coupling of spins to superconducting wires. We present explicit numerical calculations of the flux-noise power (spectral density integrated over all frequencies) for electron impurities and lattice nuclear spins under several different assumptions. The noise power is shown to be dominated by surface electron spins near the wire edges, with bulk lattice nuclear spins contributing $\ensuremath{\sim}5%$ of the noise power in aluminum and niobium wires. We consider the role of electron spin phase transitions, showing that the spin-spin correlation length (describing, e.g., the average size of ferromagnetic spin clusters) greatly impacts the scaling of flux noise with wire geometry. Remarkably, the flux-noise power is exactly equal to zero when the spins are polarized along the flux-vector direction, forming what we call a poloidal state. Flux noise is nonzero for other spin textures, but gets reduced in the presence of correlated ferromagnetic fluctuations between the top and bottom wire surfaces, where the flux vectors are antiparallel. This demonstrates that engineering spin textures and/or intersurface correlation provides a method to reduce flux noise in superconducting devices.