We had previously shown [T. Yarman et al., Results Phys. 10 (2018) 818–821] that the classical adiabatic relation pV 5/3=Constant for an ideal monatomic gas admits a direct quantum-mechanical formulation in terms of Planck’s constant and confinement-dependent quantum-state indices. This result suggests that macroscopic thermodynamic scaling laws reflect an underlying quantum-state structure. In the present work, we revisit this quantum-state scaling framework and discuss how it may provide a complementary language for thermodynamic accessibility and macroscopic irreversibility. In particular, we emphasize the conceptual distinction between microscopic reversibility, the arrow of time, and operational macroscopic irreversibility. Within this perspective, irreversibility may be interpreted in terms of asymmetries in accessible quantum-state configurations under changing confinement and energy conditions, while the underlying microscopic equations remain formally time-reversal symmetric. At the same time, the concept of operationally inaccessible microscopic quantum reconstruction, such as that with regards to fission, naturally emerges. Still, we do not claim to replace Boltzmannian, correlation-based, or information-theoretic approaches. Rather, the present study proposes a complementary quantum-state scaling perspective for discussing thermodynamic accessibility and the macroscopic evolution of complex systems. Even so, within the present framework, these practical limitations on thermodynamic accessibility do not necessitate a breakdown of formal microscopic reversibility; rather, they align with the Boltzmannian view that macroscopic reversals remain formally possible yet are rendered overwhelmingly inaccessible in practice.
We had previously shown [T. Yarman et al., Results Phys. 10 (2018) 818–821] that the classical adiabatic relation pV 5/3=Constant for an ideal monatomic gas admits a direct quantum-mechanical formulation in terms of Planck’s constant and confinement-dependent quantum-state indices. This result suggests that macroscopic thermodynamic scaling laws reflect an underlying quantum-state structure. In the present work, we revisit this quantum-state scaling framework and discuss how it may provide a complementary language for thermodynamic accessibility and macroscopic irreversibility. In particular, we emphasize the conceptual distinction between microscopic reversibility, the arrow of time, and operational macroscopic irreversibility. Within this perspective, irreversibility may be interpreted in terms of asymmetries in accessible quantum-state configurations under changing confinement and energy conditions, while the underlying microscopic equations remain formally time-reversal symmetric. At the same time, the concept of operationally inaccessible microscopic quantum reconstruction, such as that with regards to fission, naturally emerges. Still, we do not claim to replace Boltzmannian, correlation-based, or information-theoretic approaches. Rather, the present study proposes a complementary quantum-state scaling perspective for discussing thermodynamic accessibility and the macroscopic evolution of complex systems. Even so, within the present framework, these practical limitations on thermodynamic accessibility do not necessitate a breakdown of formal microscopic reversibility; rather, they align with the Boltzmannian view that macroscopic reversals remain formally possible yet are rendered overwhelmingly inaccessible in practice.
We present a unified operational framework for the arrow of time grounded in irreversible information loss. While microscopic physical laws are time-reversal invariant, macroscopic irreversibility arises when systems overwrite metastable records. We show that recent reversible quantum-control experiments do not reverse time, but instead operate in regimes where no logically irreversible record is created. To formalize this, we introduce the **forgetting rate** (Ξcr), a coarse-grained rate defined on physically selected metastable record states (e.g., pointer states, memory registers, or macroscopic configurations). Unlike standard entropy production, which is expressed in terms of microscopic transition asymmetry, (Ξcr) captures the **rate of irreversible record overwriting**. In this formulation, entropy production obeys the lower boundS˙irr≥kBΞcr,consistent with Landauer's principle but expressed at the level of record dynamics. Within this framework, thermodynamic, quantum-measurement, psychological, and cosmological arrows emerge as substrate-dependent manifestations of Ξcr>0. Temporal asymmetry is therefore not a single global property, but a distributed feature of physical information-processing systems. The approach naturally explains the decoupling of arrows in composite systems and identifies experimentally accessible regimes where irreversibility can be locally suppressed. This work does not introduce a new microscopic law but provides a unifying, operational reformulation that connects information thermodynamics, decoherence theory, and memory dynamics through a single coarse-grained rate.
This work presents a conceptual and mathematical framework addressing the longstanding tension between microscopic reversibility in quantum mechanics and macroscopic irreversibility in thermodynamics. Rather than modifying unitary quantum dynamics or invoking ad hoc coarse-graining procedures, the paper proposes that the thermodynamic arrow of time arises as an information-theoretic consequence of the physical limitations of observers. The central hypothesis, termed the Holographic Shannon–Landauer (HSL) framework, models the observer as a finite-bandwidth quantum channel (a Completely Positive Trace-Preserving map). Within this framework, entropy is redefined not as an intrinsic property of matter, but as the quantum relative entropy between the true global quantum state and the state accessible to a bandwidth-limited observer. By formalizing observation as a channel-capacity–constrained physical process, the work derives a Bandwidth–Entropy Monotonicity Theorem, demonstrating that reduced observational resolution necessarily leads to increased observed entropy via the data processing inequality. The Second Law of Thermodynamics emerges naturally from the dynamical spreading of entanglement into degrees of freedom inaccessible to the observer, rather than from any fundamental time asymmetry in the underlying laws. This manuscript is intended as a foundational and unifying perspective, connecting quantum thermodynamics, information theory, and observer-dependent physics. It is archived here as a citable preprint to establish priority and provide a stable reference point for subsequent technical developments and potential journal submissions.
Loschmidt's paradox asks why macroscopic irreversibility is universal despite the time-reversal symmetry of microscopic dynamics. We argue that irreversibility is not a property of the dynamics but of accessibility: chaotic evolution drives phase-space structure below the quantum resolution scale ℓℏ, at a critical time tc=λ−1ln(δ0/ℓℏ), after which the time-reversed microstate exists as a valid solution of Hamilton's equations but cannot be selected by any physically admissible operation. The mechanism operates entirely within the semiclassical regime tc≤tE, where classical geometry is exact. This provides a dynamical resolution of the Loschmidt paradox.
The quantum foundation is established using a Krylov-complexity framework: we prove that for any H(t)=H(−t), the quantum Lyapunov exponent satisfies λLforward=λLbackward. The arrow of time is not in the dynamics. The mechanism predicts sigmoid fidelity decay, logarithmic scaling of tc with λ−1, and ensemble-size independence of the inaccessibility threshold -- all consistent with three decades of Loschmidt echo experiments and confirmed in a stadium-billiard simulation reported here. Underlying everything: quantum mechanics conserves information exactly. Entropy, defined as the logarithm of the multiplicity Ω -- the number of possibilities consistent with the available information -- can only increase when information becomes operationally inaccessible. The second law reflects not a breakdown of microscopic reversibility, but the dynamical inaccessibility of the information required to reverse it.
The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and thermodynamics, with a particular focus on minimizing entropy production in finite-time processes. By employing tools from quantum information theory and geometric thermodynamics, we tackle the challenge of deriving irreversible thermodynamic behavior from the reversible microscopic framework of quantum mechanics. We begin with a comprehensive review of the laws of thermodynamics, setting the stage for the subsequent analyses. We introduce novel developments in quantum thermodynamics through a generalized framework for geometric thermodynamics, which enables the derivation of finite-time corrections beyond the Markovian regime. Building on this foundation, we extend Landauer's principle by incorporating a finite-time correction that highlights the necessity of strong coupling for optimal information erasure processes. This result underscores the emergence of Planckian time as a fundamental speed limit to thermalization. Additionally, we explore how collective effects can be harnessed to reduce energy dissipation in thermodynamic operations, revealing that classical correlations between systems can significantly mitigate dissipation, though this may pose new questions regarding the third law of thermodynamics. Finally, we optimize thermodynamic processes in mesoscopic systems, including quantum dot engines and information engines. These findings not only enhance our understanding of the fundamental limits of irreversibility but also open new avenues for research. Future works will focus on fully exploiting collective effects, aligning these with the third law of thermodynamics, and understanding the thermodynamic consistency of master equations.
Planck found, when attempting to describe the way in which hot bodies glow, that energy at microscopic scales often comes in discrete chunks. Thus began the long and intimate relationship between the field of thermodynamics, which explores our ability to manipulate heat and other energy transfers between macroscopic systems, and quantum mechanics, which explains the dynamics of individual microscopic systems. Even as both our technology and our theoretical investigations have extended to ever-smaller devices, our understanding of quantum effects on thermodynamics has remained almost exclusively limited to the quantized nature of energy. There is much more, however, to quantum theory than energy quantization. In this thesis we focus on the property of quantum coherence, the ability of quantum systems to emulate Schrodinger’s cat and somehow be neither dead nor alive, but something completely different altogether. We provide a simple and elegant formulation for the processing of coherence in thermodynamics, relying on the fact that thermodynamical processes possess an underlying time-translation symmetry. This fact allows us to quantify the ways in which coherence can play an active role, facilitating otherwise impossible thermodynamic transformations. We argue that coherence should be thought of as a distinctly quantum-mechanical thermodynamic resource. By considering an isolated quantum system connected, for some period of time, to a thermal bath, we give fundamental limitations on how coherence can be irreversibly manipulated. These limitations are related to those dictated on energy transfer by the second law of thermodynamics. Others topics that are investigated here is what is the role of correlations at the smallest scales and the conversion of quantum coherence into work. It has long been appreciated that thermodynamics is subtly interlinked with the notion of information. This work provides evidence that, to apply the laws of thermodynamics to the smallest systems around us, we must develop deeper insights into the nature of quantum information.
The goal of this thesis is to define the concept of coarse-graining in quantum systems through measurements and to develop a unified mathematical framework for macroscopic states, operations, correlations, and entropy.Within this framework, irreversible phenomena arise from the loss of statistical information that is accessible to macroscopic observers.To achieve this goal, we rigorously define macroscopicity.This thesis investigates observational entropy, a concept that unifies Boltzmann entropy, Gibbs entropy, von Neumann's macroscopic entropy, and diagonal entropy.Our approach to explaining how irreversibility arises in isolated quantum systems is based on this unified perspective.When the initial state is "macroscopic," we use Petz's theory of statistical sufficiency to show that observational entropy strictly increases with unitary time evolution.Furthermore, we show that, for any initial state, the probability of the system's observational entropy increasing and rapidly reaching its maximum value under random unitary time evolution is extremely high.Specifically, we demonstrate that when measurements on a quantum system are sufficiently coarse-grained relative to its size, its initial state (whether pure or mixed) becomes indistinguishable from the maximally mixed state through random time evolution.We show that this holds not only for random time evolutions sampled according to the Haar measure, but also for approximate 2-designs, which are considered more physically realistic models.Next, we extend this framework by introducing positive operator-valued measures (POVMs) and quantum prior states.This allows us to construct a unified inferential framework for macroscopic states.A macroscopic state can be characterized using equivalent algebraic and constructive formulations based on quantum statistical sufficiency.This approach is based on the concept of an observational deficit, which quantifies the degree to which a state is "irretrodictable" relative to prior and measurement.This structure is formulated as an "inferential reference frame" that encapsulates the observer's informational perspective.Furthermore, we treat macroscopic states as free states and construct the resource theory of microscopicity.This theory unifies existing theories of coherence, athermality and asymmetry.Finally, we extend this framework to the study of quantum correlations under observational constraints.This enables us to show that quantum correlations, such as entanglement and quantum discord, are context-dependent resources that depend on the observer's reference frame.I would like to express my deepest gratitude to my supervisor,