It is shown that non-stationary solutions of the Schrödinger equation, which describes the quantum dynamics of a particle in the field of a one-dimensional delta potential (1DDP), are divided into two classes: some define pure states that have no free dynamics as
t→∓∞; others define states with asymptotically free dynamics but represent mixed states in whose space the asymptotic superselection rule holds. That is, according to the Schrödinger equation, {\it pure scattering} states predicted by the conventional model of this scattering process do not exist. On mixed scattering states, the Hamiltonian with 1DDP is defined only in superselection sectors. The scattering process with one-sided incidence of a particle on 1DDP represents a decoherence process in a closed system.
The Schrödinger equation is reformulated as a universal continuity equation, which connects between changes in the particles probability density distribution to probability current densities (fluxes). The formulation of particle conservation in terms of stationary fluxes enables one to associate stationary wave functions also to open quantum systems characterized by stationary particle currents. These functions are (improper) solutions of the stationary Schrödinger equation, obtained under scattering boundary conditions. These boundary conditions can be fulfilled for any positive asymptotic kinetic energy, hence, the energy spectrum of the scattering states is continuous. We demonstrate flux calculations in scattering through a one-dimensional potential energy well/barrier, focusing on transmission and reflection probabilities. Nonclassical phenomena such as transmission at energies below a potential energy barrier (quantum tunneling), or reflections at energies above a potential energy well are analyzed. The phenomenon of full transmission through a double barrier structure (resonant tunneling) is introduced in the context of nanoscale transport.
As is stated, the modern mathematical (
C∗-algebraic) scattering theory for the formal Hamiltonian with a one-dimensional short-range potential, developed on the basis of the operational definition of observables, describes unitary asymptotically free dynamics. But, as it s shown in this paper by the example of the
δ-potential, this Hamiltonian can describe either unitary asymptotically not free dynamics (endless interaction process) or non-unitary asymptotically free dynamics (scattering process). In the case of scattering, the unboundedness of the position operator plays a key role. Each solution to the Schrodinger equation, describing the scattering process with a one-sided incidence of a particle on the barrier, is non-unique in the limit
t→∞, when it is a superposition of unconnected states (left and right out-asymptotes) localized in the disjoint spatial regions located on opposite sides of the barrier --- it describes non-unitary quantum dynamics. Measurement of the coordinates of the transmitted and reflected particles using one experimental setup of finite dimensions, as is assumed in the operational approach, is impossible. We need two such setups --- one for the transmitted particles, and the other for the reflected ones. Thus, such a solution is a mixed vector state --- this process is governed by the asymptotic superselection rule.