This thesis presents a collection of projects spanning different sub-fields of quantum science, undertaken with the goal of understanding and advancing quantum technologies. Broadly, it can be divided into two thematic parts — parameter estimation and open system dynamics. Each project addresses inverse and ill-posed problems in Physics, which lie at the heart of developing robust and scalable quantum devices.A central theme in quantum technology is the challenge of inference of microscopic system parameters from limited, indirect observations. The first part of the thesis investigates this through the problem of Hamiltonian reconstruction via local measurements. Indirect estimation of couplings in quantum systems relies on the measurement of the spectrum and the overlap of eigenvectors with some reference state. For a one-dimensional chain, this data can be obtained by local measurement on one end of the chain, thereby reducing the need for full Hamiltonian tomography. Information about couplings is extracted from the temporal data obtained by measuring the expectation values of the time evolution 𝑒−𝑖𝐻𝑡 for a reference state. In Chapter 3, we analyze the robustness of this estimation scheme under perturbations arising from beyond nearest neighbour interactions. We show that the error scales linearly with the strength of such interactions and on average, the error increases with the distance of interaction between sites.Chapter 4 examines whether coupling information can be extracted from local thermal measurements, using expectation values of the Gibbs state at varying temperatures rather than temporal data. We develop a procedure to obtain the coefficients of the Taylor expansion of these expectation values and relate them to the Hamiltonian parameters. For very small chains, this mapping can be carried out analytically, while for larger systems it reveals the algebraic structure that links local measurements to the underlying couplings and highlights the trade-offs between measurement resources, numerical stability, and identifiability. The analysis also clarifies how additional local fields or self-interaction terms enhance the information content of thermal data, suggesting a role for local thermal probes as practical tools for Hamiltonian verification and parameter estimation.Building on the ideas of controlling and inferring information about a quantum system, we now turn to active intervention through adaptive measurement. In Chapter 5, we develop a process tensor driven procedure for cooling the spin bath that is coupled to a nitrogen vacancy (NV) center in diamond. By modeling the sequence of intermediate quantum instruments acting on a correlated system-environment process, we optimize a pair of completely positive (CP) maps to maximize the population in a lower-energy state. Unlike existing approaches that rely solely on positive operator valued measures (POVMs), our method encompasses a broader class of CP maps, including adaptive feed-forward and mixed operations. We explicitly account for initial correlation between system and environment and distinguish between the controllable and uncontrollable parts of the dynamics. Our framework supports non-Markovian operations and benchmarks them against optimal Markovian strategies. The optimization is performed via Semi-definite Programming (SDP), ensuring global optimality. We also assess robustness to Hamiltonian noise and provide a proposal for implementation using NV center in diamonds.Finally, Chapter 6 explore the relaxation dynamics of topological qubits, focusing on a tetron qubit formed from two uncoupled Kitaev chains coupled to a finite fermionic bath. Using the correlation matrix formalism for purely quadratic couplings, we show that the relaxation is fundamentally independent of temperature when either the bath is large, or the zero-mode energy of the system is close to zero. This challenges a key assumption in the field that cooling enhances coherence. Interestingly, we find that introducing glassy disorder into the system slows down relaxation, offering a potential route to prolong qubit lifetimes.Collectively, these studies form a coherent narrative around extraction, control and utilization of quantum information under fundamental constraints. By tackling such inverse and often ill-posed problems, this thesis contributes new tools and insights essential for the realization of future quantum technologies.
This thesis presents a collection of projects spanning different sub-fields of quantum science, undertaken with the goal of understanding and advancing quantum technologies. Broadly, it can be divided into two thematic parts — parameter estimation and open system dynamics. Each project addresses inverse and ill-posed problems in Physics, which lie at the heart of developing robust and scalable quantum devices.A central theme in quantum technology is the challenge of inference of microscopic system parameters from limited, indirect observations. The first part of the thesis investigates this through the problem of Hamiltonian reconstruction via local measurements. Indirect estimation of couplings in quantum systems relies on the measurement of the spectrum and the overlap of eigenvectors with some reference state. For a one-dimensional chain, this data can be obtained by local measurement on one end of the chain, thereby reducing the need for full Hamiltonian tomography. Information about couplings is extracted from the temporal data obtained by measuring the expectation values of the time evolution 𝑒−𝑖𝐻𝑡 for a reference state. In Chapter 3, we analyze the robustness of this estimation scheme under perturbations arising from beyond nearest neighbour interactions. We show that the error scales linearly with the strength of such interactions and on average, the error increases with the distance of interaction between sites.Chapter 4 examines whether coupling information can be extracted from local thermal measurements, using expectation values of the Gibbs state at varying temperatures rather than temporal data. We develop a procedure to obtain the coefficients of the Taylor expansion of these expectation values and relate them to the Hamiltonian parameters. For very small chains, this mapping can be carried out analytically, while for larger systems it reveals the algebraic structure that links local measurements to the underlying couplings and highlights the trade-offs between measurement resources, numerical stability, and identifiability. The analysis also clarifies how additional local fields or self-interaction terms enhance the information content of thermal data, suggesting a role for local thermal probes as practical tools for Hamiltonian verification and parameter estimation.Building on the ideas of controlling and inferring information about a quantum system, we now turn to active intervention through adaptive measurement. In Chapter 5, we develop a process tensor driven procedure for cooling the spin bath that is coupled to a nitrogen vacancy (NV) center in diamond. By modeling the sequence of intermediate quantum instruments acting on a correlated system-environment process, we optimize a pair of completely positive (CP) maps to maximize the population in a lower-energy state. Unlike existing approaches that rely solely on positive operator valued measures (POVMs), our method encompasses a broader class of CP maps, including adaptive feed-forward and mixed operations. We explicitly account for initial correlation between system and environment and distinguish between the controllable and uncontrollable parts of the dynamics. Our framework supports non-Markovian operations and benchmarks them against optimal Markovian strategies. The optimization is performed via Semi-definite Programming (SDP), ensuring global optimality. We also assess robustness to Hamiltonian noise and provide a proposal for implementation using NV center in diamonds.Finally, Chapter 6 explore the relaxation dynamics of topological qubits, focusing on a tetron qubit formed from two uncoupled Kitaev chains coupled to a finite fermionic bath. Using the correlation matrix formalism for purely quadratic couplings, we show that the relaxation is fundamentally independent of temperature when either the bath is large, or the zero-mode energy of the system is close to zero. This challenges a key assumption in the field that cooling enhances coherence. Interestingly, we find that introducing glassy disorder into the system slows down relaxation, offering a potential route to prolong qubit lifetimes.Collectively, these studies form a coherent narrative around extraction, control and utilization of quantum information under fundamental constraints. By tackling such inverse and often ill-posed problems, this thesis contributes new tools and insights essential for the realization of future quantum technologies.
Quantum systems are the foundation of quantum technology development. To harness these systems, one must extract information from them and be able to control their dynamics. This thesis presents a body of work, containing both published and unpublished papers, that focuses on two key research areas: quantum continuous measurement and quantum bath sensing. While these topics may seem distinct, they are fundamentally connected through the framework of open quantum systems. As such, this thesis is structured into two parts. The first part of this thesis is dedicated to diffusive continuous quantum measurement, where the system of interest is continuously monitored through a coupled Markovian bath or meter. A key challenge in this context is the numerical errors introduced in quantum trajectory simulations caused by the finite time resolution ( 𝑡) in real experiments. To address this, we propose a systematic framework to assess theoretical tools used in processing measurement records. Focusing on a single Lindblad channel, we analyze the errors of existing measurement (or Kraus) operators in literature, in orders of 𝑡 under conditions that ensure valid average evolution (complete positivity, convex linearity, and trace preservation). We also analyze a stronger condition: finding the order at which these existing measurement operators match the Lindblad equation. Based on these analyzes, we propose a Kraus operator that satisfies the conditions for valid quantum evolution and matches the Lindblad master equation to second order in 𝑡, surpassing all existing approaches. Moreover, to evaluate how well our operator reproduces exact quantum trajectories, we analyze two qubit measurement examples where exact maps can be derived: 𝑧-basis measurement and fluorescence (dissipative) measurement. We show analytically that our proposed operator achieves the smallest average trace distance to the exact quantum trajectories compared to existing methods. Finally, we extend this Kraus operator to multiple Lindblad channels with a driving Hamiltonian. We test our analytical findings numerically using the two qubit examples, considering both single and multiple Lindblad channels with a driving Hamiltonian. The numerical results confirm our theoretical predictions. The second part of this thesis focuses on quantum bath sensing, where we use a quantum system (qubit) to extract information about its surrounding baths. Specifically, we develop protocols to detect nonclassical pure-dephasing noise in a single-qubit system coupled to temporally correlated (non-Markovian) baths. Inspired by the Ramsey protocol, we introduce a coherent intervention (𝜋 2 -pulse) within the protocol, which can reveal the quantum noise - noise correlations affecting the probe qubit that originate from quantum degrees of freedom. Our protocols are simple, experimentally viable, and rigorously derived for general bath models. Using an exactly solvable bosonic bath model, we analyse how key noise parameters respond to fixed control schemes, identifying the optimal strategy for detecting the quantum noise. From the perspective of bath dynamics, we further decompose the qubit-bath state, demonstrating that only Gaussian components of the bath contribute to quantum noise, highlighting the bath's role in system dynamics. Finally, we extend the modified Ramsey protocol by incorporating multi-axis 𝜋 2 pulse and demonstrate that it can emulate the modified Ramsey protocol with any completely positive trace-preserving intervention. This applies to both Gaussian and non-Gaussian baths under the pure-dephasing assumption.
Improved control and manipulation of quantum systems lies at the heart of modern quantum science and technology, with broad applications ranging from quantum metrology to quantum information science and many-body physics. In this thesis, I will introduce a novel framework for robust Hamiltonian engineering in interacting spin systems, which enables the efficient design of Floquet engineering pulse sequences for qubit and qudit systems that out-perform state-of-the-art control methods by orders of magnitude. As applications of this framework, we utilize a high density ensemble of nitrogen vacancy (NV) centers in diamond, and demonstrate significantly improved control over the disordered, interacting many-body spin system. This enabled the first solid state spin ensemble quantum sensor operating beyond the sensitivity limit imposed by interactions between sensing particles, as well as the observation and understanding of novel dynamical many-body phenomena, including discrete time crystalline order and thermalization dynamics in long-range interacting XXZ spin models.
Quantum measurements lie at the core of quantum information processing, enabling tasks ranging from state reconstruction and parameter estimation to sensing and computation. As quantum technologies scale and become increasingly precise, a central question emerges: what does it mean for a quantum measurement to be good? This thesis addresses this question by developing quantitative, operational, and physically grounded frameworks for assessing the quality and informational power of quantum measurements.The first part of the thesis focuses on the intrinsic quality of quantum measurements independent of any particular input state. Adopting the formalism of quantum resource theories, measurements are treated as resources ordered under classical post-processing, which cannot increase informational content. Restricting attention to informationally complete measurements, we employ frame theory to introduce a novel resource monotone termed completeness stability, defined as the minimum eigenvalue of a suitably scaled frame operator. We establish its operational significance by showing that the average error in quantum state tomography and the average variance in shadow tomography are tightly bounded by the inverse of the completeness stability. Maximizing this monotone identifies weighted complex projective 2-designs, including symmetric informationally complete POVMs and mutually unbiased bases, as optimal measurement configurations.The second part of the thesis extends these ideas to quantum parameter estimation, where measurement performance necessarily depends on correlations between the measurement and the encoded quantum state. By introducing a state-dependent inner product on operator space, we develop an operator-theoretic formulation in which both the classical and quantum Fisher information arise naturally from a single frame operator associated with the measurement and the reference state. Within this framework, the spectral properties of the frame operator provide a complete characterization of estimation performance. The maximum and minimum eigenvalues identify the best- and worst-case parameter-encoding directions, respectively, yielding sharp bounds on the achievable ratio of classical and quantum Fisher information. This establishes a direct connection between informational completeness, estimation robustness, and resource-theoretic monotonicity.The final part of the thesis returns to foundational questions concerning quantum measurement and arrival time. Using Bohmian mechanics, we develop a microscopic, first-principles account of the Hong–Ou–Mandel effect, a paradigmatic two-particle interference phenomenon. By analyzing particle trajectories guided by the wave function, we show how bosonic bunching and fermionic anti-bunching emerge dynamically from the guiding equation without invoking wave-function collapse. Beyond reproducing the Hong–Ou–Mandel dip, we demonstrate how experimental parameters such as barrier strength, phase velocity, and path asymmetry influence both coincidence probabilities and temporal correlations.Taken together, this thesis provides a unified treatment of quantum measurement quality across operational, metrological, and dynamical regimes. By bridging resource theory, frame theory, Fisher information, and trajectory-based quantum dynamics, it offers new insights into the structure, limitations, and physical interpretation of quantum measurements in both applied and foundational contexts.
The pursuit of large-scale quantum computers poses two separate, though related, challenges: the need to develop robustly controllable quantum hardware; and the need to develop quantum algorithms which use it to perform meaningful compu-tations. In this thesis, we explore a selection of topics related to both of these challenges. Specifically, we focus on quantum state preparation for nuclear spin ensembles, and simu-lation algorithms for spin-orbit coupling Hamiltonians. We present a collection of indirect-measurement-based initialisation protocols for 13C baths coupled in parallel to nitrogen-vacancy defects in diamond, in a strong external field. We find that the probabilistic nature of the measurement, combined with the damaging effects of unwanted measurement outcomes, limits the utility of such protocols as means of steering the bath into some desired subspace. As a means of imparting purity into an initially incoherent bath state, the protocols appear more promising, with purity tending to increase with the number of measurements irrespective of their outcomes. We subsequently attempt to mitigate the shortcomings of these protocols by applying a corrective unitary transformation to the bath following each measurement. We find these compound protocols to indeed be capable of mapping the bath state to an arbitrary target subspace (with unit probability) given a sufficient degree of bath control; in the case where the bath control is limited, we provide lower bounds on the protocol’s success probability. We additionally show that qualitatively equivalent results can be attained using a bounded number of unitary corrections, albeit with an efficiency overhead. Finally, we turn our attention to the problem of quantum simulation, with a focus on systems possessing both spin and orbital degrees of freedom. We propose three protocols which allow the simulation of arbitrary spin-orbit coupling interactions using a model system undergoing a controlled discrete-time quantum walk (DTQW). The number of DTQW steps required to execute this simulation is found to be at most quadratic in the dimension of the simulated Hilbert space.
Recent experimental progress in the preparation and control of quantum systems has brought to light the importance of Quantum State Tomography (QST) in validating the results. In this thesis we investigate several aspects of QST, whose central problem is to devise estimation schemes for the recovery of an unknown state, given an ensemble of n independent identically prepared systems. The key issues in tackling QST for large dimensional systems is the construction of physically relevant low dimensional state models, and the design of appropriate measurements. Inspired by compressed sensing tomography, in chapters 4, 5 we consider the statistical problem of estimating low rank states (r ≪ d) in the set-up of Multiple Ions Tomography (MIT), where r and d are the rank and the dimension of the state respectively. We investigate how the estimation error behaves with a reduction in the number of measurement settings, compared to ‘full’ QST in two setups - Pauli and random bases measurement designs. We study the estimation errors in this ‘incomplete’ measurement setup in terms of a concentration of the Fisher information matrix. For the random bases design we demonstrate that O(r logd) settings suffice for the mean square error w.r.t the Frobenius norm to achieve the optimal O(1/n) rate of estimation. When the error functions are locally quadratic, like the Frobenius norm, then the expected error (or risk) of standard procedures achieves this optimal rate. However, for fidelity based errors such as the Bures distance we show that no ‘compressive’ recovery exists for states close to the boundary, and it is known that even with conventional ‘full’ tomography schemes the risk scales as O(1/√n) for such states and error functions. For qubit states this boundary is the surface of the Bloch sphere. Several estimators have been proposed to improve this scaling with ‘adaptive’ tomography. In chapter 6 we analyse this problem from the perspective of the maximum Bures risk over all qubit states. We propose two adaptive estimation strategies, one based on local measurements and another based on collective measurements utilising the results of quantum local asymptotic normality. We demonstrate a scaling of O(1/n) for the maximum Bures risk with both estimation strategies, and also discuss the construction of a minimax optimal estimator. In chapter 7 we return to the MIT setup and systematically compare several tomographic estimators in an extensive simulation study. We present and analyse results from this study, investigating the performance of the estimators across various states, measurement designs and error functions. Along with commonly used estimators like maximum likelihood, we propose and evaluate a few new ones. We finally introduce two web-based applications designed as tools for performing QST simulations online.
In this Thesis I present the results of four research projects I carried out during my Ph.D. training at SISSA. The broad topic of my research was the mechanism of relaxation in isolated, integrable quantum systems. Roughly speaking, integrable quantum systems are one-dimensional lattice models or field theories that feature an extensively large number of conservation laws beyond energy and momentum conservation, which greatly influence their dynamical behaviour. Integrable systems have enjoyed a considerable interest in the last decade, mainly due to the development of ultracold atomic techniques. These techniques made it possible to implement experimentally a wealth of one-dimensional quantum models whose significance had been purely theoretical before. The theoretical interest in integrable systems stems in part from the fact that in many aspects they are exactly solvable. Exact analytical formulas are available for their spectrum and their equilibrium thermodynamic properties, creating an incentive to study analytically their non-equilibrium behaviour as well. Exact results for the dynamics of integrable systems may serve as a benchmark for confirming theories in statistical mechanics or testing approximative methods. To this day, computing analytically the entire time evolution of observables in a genuinely interacting integrable system is prohibitively difficult in general. In this Thesis, I concentrate on the description of the system at long times after it is brought out of equilibrium. Homogeneous, translationally invariant integrable systems are expected to relax to a stationary state, in which local observables are described by a generalization of the Gibbs ensemble that takes into consideration all the conservation laws beyond the energy. Two of the projects presented here concern this relaxed state. In Chapter 2, a method is presented for computing the Rényi entropies of the Generalized Gibbs Ensemble describing the relaxed state in the integrable Heisen- berg XXZ spin chain. Rényi entropies provide information about the relaxed state and its entanglement properties, going beyond the ordinary von Neumann thermo- dynamic entropy. The method presented there is very general; in principle it works in any integrable model and any translationally invariant thermodynamic macrostate. An alternative to the GGE in describing relaxed states after a quantum quench is the Quench Action approach. This approach is based on the explicit analytical knowledge of the overlaps between the initial state and the Hamiltonian eigenstates. In Chapter 3, this approach is generalized to a spin-1 integrable spin chain, the SU(3) invariant Lai–Sutherland model. The evolution of entanglement is then studied using the quasiparticle picture, which features ballistically propagating classical particle pairs carrying entanglement. If the requirement of translational invariance of the initial state is relaxed, various transport phenomena arise in integrable systems. The evolution of slowly varying, smoothly distributed states is described by a generalization of hydrodynamics, which takes into consideration the infinitely many local conservation laws. At the scale of non-diffusive, ballistic transport, the main feature of this generalized hydrodynamics (GHD) is the existence of continuity equations for the occupation number of each mode. Further two projects are presented in this Thesis which are concerned with GHD.I n Chapter 4, a numerical method is presented for computing the evolution of entanglement entropies within GHD. This method combines the quasiparticle picture of entanglement with a molecular dynamics simulation of GHD, the so-called fleagas. Numerical evidence is shown that this method reproduces previously known analytical results in GHD. Its versatility is demonstrated by computing another entanglement-related quantity, the mutual information, for which no analytical results are available. Finally, in Chapter 5, the GHD framework is generalized to a system of spin-1/2 fermions with repulsive contact interaction, the Yang–Gaudin model. It is shown that at low temperatures, the dynamics of the system is described by the superposition of two uncoupled, inhomogeneous conformal field theories. This fact can be interpreted as a separation of the spin and the charge degrees of freedom of the system.