This thesis explores interference effects in classical and quantum optics through two independent theoretical frameworks, establishing electromagnetic interference as a unifying and physically measurable mechanism governing light-matter interactions. Both frameworks demonstrate how reflection-induced phase shifts and field coherence jointly govern measurable observables, providing a rigorous theoretical foundation for high-precision measurement, innovative sensing, and emerging applications in quantum information science. In the classical optics framework, reflectivity serves as the primary observable linking material parameters to changes in the reflected field. Using Fabry-Perot cavities, we demonstrate that phase-coherent back-reflection from target molecules, without any direct contact with the resonator, modifies the minima of the reflection spectrum, enabling remote, label-free detection while preserving cavity stability. In the quantum optics framework, we recast the Jaynes-Cummings model from a microscopic, first-principles derivation rather than a phenomenological ansatz. This yields quantitative predictions for the spontaneous emission rate across a continuous range of cavity geometries, showing that the cavity emission rate equals the free-space rate in conventional resonators, and exceeds it by a factor of approximately 20,000 in plasmonic nanocavities. For multiple emitters, the framework captures ultralong-range dipole-dipole interactions mediated by a mirror, with tunable superradiant and subradiant decay rates. This analysis further reveals a spatial-temporal correspondence between the collective decay rate and the temporal coherence of the emitted field, providing a unified interpretive framework for collective light-matter coupling, and opens a direct route to non-invasive distance sensing in nanophotonic systems.
This thesis explores interference effects in classical and quantum optics through two independent theoretical frameworks, establishing electromagnetic interference as a unifying and physically measurable mechanism governing light-matter interactions. Both frameworks demonstrate how reflection-induced phase shifts and field coherence jointly govern measurable observables, providing a rigorous theoretical foundation for high-precision measurement, innovative sensing, and emerging applications in quantum information science. In the classical optics framework, reflectivity serves as the primary observable linking material parameters to changes in the reflected field. Using Fabry-Perot cavities, we demonstrate that phase-coherent back-reflection from target molecules, without any direct contact with the resonator, modifies the minima of the reflection spectrum, enabling remote, label-free detection while preserving cavity stability. In the quantum optics framework, we recast the Jaynes-Cummings model from a microscopic, first-principles derivation rather than a phenomenological ansatz. This yields quantitative predictions for the spontaneous emission rate across a continuous range of cavity geometries, showing that the cavity emission rate equals the free-space rate in conventional resonators, and exceeds it by a factor of approximately 20,000 in plasmonic nanocavities. For multiple emitters, the framework captures ultralong-range dipole-dipole interactions mediated by a mirror, with tunable superradiant and subradiant decay rates. This analysis further reveals a spatial-temporal correspondence between the collective decay rate and the temporal coherence of the emitted field, providing a unified interpretive framework for collective light-matter coupling, and opens a direct route to non-invasive distance sensing in nanophotonic systems.
Coupling between quantum emitters and modes of light is foundational to studies of quantum systems. Coherent interactions between matter and light have greatly advanced the development of quantum technologies. When an ensemble of atoms interacts with light that is confined within a cavity---a resonator for photons---light also mediates atom-atom interactions, leading to collective phenomena that cannot be extrapolated from microscopic behaviors. Understanding how interactions among quantum particles lead to macroscopic phenomena, such as phase transitions and breaking of symmetries, remains a challenge in modern physics. In this dissertation, I present results addressing this challenge in the context of mesoscopic arrays of optical-tweezer-trapped atoms interfaced with a high-finesse optical cavity. In particular, the physics we investigate arises from the collective scattering of light. Utilizing the ability to place atoms with nanometer-scale precision, we engineer superradiant and subradiant states, where control over interference of the emission from multiple atoms leads to collectively enhanced or suppressed amounts of scattered light. Building on this work, we investigate the emergence of optomechanical self-organization, mediated by superradiance in the cavity electromagnetic field. By coupling atoms to the same cavity mode, the atoms exert forces on one another through the exchange of photons, leading them to autonomously order themselves spatially. We characterize mesoscopic fluctuations and their effect on symmetry-breaking dynamics associated with self-organization. Finally, we extend this framework to theoretically investigate how the phase of the atom-cavity coupling can be altered to generate higher symmetries. Our analysis reveals first-order phase transitions and instabilities induced by non-reciprocal forces. Altogether, this work establishes a path towards realizing mesoscopic systems of complex phases of matter in cavity quantum electrodynamics with unprecedented programmability.
The interaction between light and matter has captivated physicists for centuries, from early studies of vision and refraction in ancient Greece to the development of quantum mechanics and quantum electrodynamics in the past century. While the response of a single quantum emitter to light is well understood, the radiative properties of an ensemble of closely spaced emitters are far more intricate. Coupling to a shared electromagnetic environment induces coherent and dissipative interactions between emitters, giving rise to a collective response that cannot be captured by treating them independently. In the regime of few excitations, the system hosts delocalized subradiant states, that is, coherent superpositions that are largely decoupled from the electromagnetic field and thus decay at suppressed rates. While this weak coupling makes subradiant states attractive for quantum technologies, it also renders them difficult to manipulate. At higher excitation densities, the intrinsic nonlinearity of emitters and the exponential growth of the Hilbert space make theoretical and numerical descriptions of the system and its dynamics increasingly challenging. This thesis explores two fundamental questions: How can subradiant and dark states be selectively accessed and harnessed for practical applications in quantum technologies? And how can interacting ensembles of quantum emitters be efficiently simulated to uncover their many-body physics? The first part of the thesis develops protocols for controlling and addressing dark states in free-space and waveguide-coupled atomic arrays, demonstrating their utility in quantum storage and the deterministic generation of entangled photonic states. Incorporating atomic motion, we further show that collective subradiant states can enhance cooling in dense atomic arrays, offering new avenues for controlling motional dynamics. In the second part, we introduce cumulant expansions of the equations of motion as a powerful tool to analytically and numerically investigate collective decay in the many-body regime. We first examine the collective decay of fully excited atomic arrays in free space, characterizing the onset and scaling of the superradiant burst across different geometries. In collaboration with experiments on ultracold erbium atoms in optical lattices, we provide the first direct observations of many-body collective effects in free-space ordered arrays, including early-time superradiant bursts, late-time subradiant tails, and the emergence of atomic correlations throughout the dynamics. Finally, we theoretically and numerically explore the transient formation of multi-excitation subradiant states, and demonstrate how the existence of multiple dissipation channels suppresses steady-state superradiance in extended arrays.
Quantum properties like coherence and entanglement can lead to enhanced performance characteristics in a wide range of applications including quantum computation, quantum memory storage, optical sensing, and energy harvesting. Entanglement is very sensitive to static and dynamical disorder. Similarly, the generation of highly-entangled states requires strong coupling or strong driving fields. Satisfying all of these requirements is generally quite difficult. In the first part of this thesis, we present an approach to overcome these limitations through the use of exotic light-matter states in hyperbolic media which provide a new approach to control quantum correlations and interatomic interactions. We reveal a class of excited-state, long-range interactions, referred to as Super-Coulombic interactions that are singular along a material-dependent resonance angle. In practical systems, the Super-Coulombic interaction achieves dipole-dipole coupling that is orders of magnitude larger than conventional approaches, while also occurring across a large frequency bandwidth making it robust to static energy-level disorder. This unique hyperbolic response is not only naturally occurring, found in materials like h-BN, BiTe2, BiSe2, and mono-layered black phosphorus, but can also be designed with artificial nanostructured materials (metamaterials) to create the desired hyperbolic dispersion across different parts of the electromagnetic spectrum. Our theoretical prediction motivated an intense search for the effect and was confirmed by an experimental demonstration at room temperature. To obtain agreement with experimental results, we present a rigorous theoretical framework that takes into account ensemble effects, finite-sized effects, and dimensional effects that arise from confined geometries ultimately modifying the Super-Coulombic spatial scaling law. In the second part of this thesis, we solve an outstanding theoretical problem dealing with the control of resonance energy transfer in nanophotonic environments in both the incoherent and coherent coupling limits. Resonance energy transfer is a fundamental process that is the subject of intense research across all sciences. For example, in chemistry for drug delivery and chemical monitoring, in engineering for photovoltatic and up-conversion devices, and in biology for exciton transport within photosynthetic complexes. First, we consider the disordered and weak coupling limit of resonance energy transfer often encountered in chemistry. We propose new design principles for enhancing and suppressing the energy transfer rate and efficiency quantitatively captured by a simple image dipole model. Our theory explains a wide range of experimental results which have been the subject of an ongoing debate for the past 15 years. Second, we present our recent result aimed at understanding the fundamental role of entanglement and quantum coherence in resonance energy transfer. To uncover the role of these effects, we develop a unified theory of energy transfer valid from the incoherent to quantum coherent coupling regimes. Ultimately, our theory reveals a fundamental bound ηmax = γa for energy transfer efficiency arising from γd+γa the spontaneous emission rates γd and γa of the donor and acceptor. This bound provides an upper limit to the efficiency of energy transfer regardless of quantum coherence or entanglement, suggesting new design principles for achieving near-unity energy transfer efficiency in coherent systems. The result has important implications for the two-chromophore model found in photosynthetic complexes and paves the way for nanophotonic analogues of efficiency-enhancing environments mimicking biological photosynthetic systems.
We explore the quantum-metrological potential of subwavelength-spaced emitter arrays coupled to a one-dimensional nanophotonic waveguide. In this system, strong dipole--dipole interactions profoundly modify the collective optical response, leading to the emergence of ultranarrow subradiant resonances. Through an eigenmode analysis of the effective non-Hermitian Hamiltonian, we derive the decay rate of the most subradiant state, which, within the present model and geometry, exhibits an N−3 scaling with even--odd oscillatory behavior in the deep-subwavelength regime. This scaling is directly observable in the single-photon scattering spectrum, enabling the detection of minute changes in atomic separation with a figure of merit that scales as $ N^3 $. The quantum Fisher information (QFI) scales as N6 and can be closely approached by measuring spectral shifts near the steepest slope of the most subradiant resonance. These enhancements remain robust under realistic positional disorder, confirming that dipole--dipole-engineered subradiance provides a viable resource for quantum metrology. Our work bridges collective waveguide-QED physics and high-precision sensing, opening a route toward scalable quantum sensors on integrated nanophotonic platforms.
In this study, we present the superradiance effects of N identical molecular emitters inside Fabry–Pérot (FP) cavity systems in the framework of macroscopic quantum electrodynamics. The proposed theory can estimate the enhancement of spontaneous emission rates, including the effects of cavity geometry and material dielectric properties. Moreover, our study connects the multichromophoric excitation energy transfer theory and the Tavis–Cummings model via identical cooperative decay rates and dipole–dipole shifts. For molecules resonant with the cavity photon mode, we find that the enhancement is not exactly proportional to N even in a perfect FP cavity due to the effects of electrostatic dipole–dipole interactions. Moreover, in a silver FP cavity, our simulation shows that the enhancement saturates for a large N, indicating that the cavity photon mode can lead to only the collective emission of a limited number of molecules. For molecules in the proximity of the silver mirror, we demonstrate that under specific conditions, the subradiance of molecular emitters can occur through surface plasmon polaritons. Our study not only provides new insights into the mechanism of superradiance effects but also demonstrates that collective effects such as superradiance and subradiance can be controlled by manipulating the dielectric environments.
When multiple quantum emitters couple to a common electromagnetic environment, interference in their collective radiative dynamics gives rise to superradiance and subradiance. In regimes where coherent interactions and collective dissipation compete, the microscopic many-body dynamics and quantum correlations among the emitters that underlie superradiance and subradiance are theoretically challenging and remain experimentally elusive, even though collective emission has been observed in many physical systems. Here, we realize a superconducting qubit array coupled to a common microwave waveguide that mediates collective dissipation, with simultaneous access to coherent interactions and microscopic measurements of many-body dynamics. Engineered qubit-waveguide couplings with tunable amplitude and phase enable control of collective interference and the resulting super- and subradiant states. Leveraging site-resolved control and readout, we directly observe the microscopic decay dynamics of multi-qubit states across different excitation manifolds and track the evolution of populations and tunable quantum correlations. We reveal collective decay in regimes beyond the ideal Dicke model, where strong qubit-qubit interactions stabilize superradiance and subradiance against local dephasing and reshape decay pathways through spatially and spectrally structured many-body eigenstates. Our results establish a flexible platform for exploring collective phenomena in many-body quantum optics and driven-dissipative approaches to robust quantum information processing.