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Cambridge University Press eBooks

Quantum Mechanics for Quantum Engineers

A. M. Zagoskin

Published Jun 25, 2026• 0 citations
Publisher

Abstract

A concise introduction to theoretical description of quantum systems in general, and qubits in particular, in the presence of decoherence (equations of motion for quantum state vectors and density matrices, Lindblad formalism, Bloch vector and Bloch equations).
DOI
10.1017/9781009463584.003

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The arguments of Chapter 2, as well as of those of subsequent chapters, have as their foundation the formalism based on the state vector of a system of which the evolution is described by the Schrödinger equation. In fact, such an approach is badly suited to the case in which the coupling between an atom and its environment (for example through collisions with other atoms or spontaneous emission into formerly empty modes of the electromagnetic field) cannot be neglected. If the correlations induced by these interactions between the atom and its environment do not concern us and we are only interested in the evolution of the atom, the formalism of the density matrix must be employed. This provides a description at all times of the state of the atom, although a state vector for the atom alone cannot be defined. In this formalism the effect of the environment on the atom is accounted for by the introduction of suitable relaxation terms (Section 2C.1) in the equation of evolution of the density matrix. An important application of the density matrix is to the case of a two-level atomic system for which the relaxation terms lead to its deexcitation to a level of lower energy. We shall show that in this case the density matrix can be represented by a vector, known as the Bloch vector , which will allow us to give simple geometrical pictures of the evolution of the system.

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Quantum Mechanics

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In the Bloch sphere picture, one finds the coefficients for expanding a single-qubit density operator in terms of the identity and Pauli matrices. A generalization to nnn qubits via tensor products represents a density operator by a real vector of length 4n{4}^{n}4n, conceptually similar to a state vector. Here, we study this approach for the purpose of quantum circuit simulation, including noise processes. The tensor structure leads to computationally efficient algorithms for applying circuit gates and performing few-qubit quantum operations. In view of variational circuit optimization, we study ``backpropagation'' through a quantum circuit and gradient computation based on this representation, and generalize our analysis to the Lindblad equation for modeling the (nonunitary) time evolution of a density operator.
By use of a generalized Bloch vector construction, we study the decoherence of a system composed of two interacting qubits in a general noisy environment. In particular, we investigate the effects of correlations in the noise acting on distinct qubits. Our treatment of the two-qubit system by use of the generalized Bloch vector leads to tractable analytic equations for the dynamics of the 4-level Bloch vector and allows for the application of geometrical concepts from the well known 2-level Bloch sphere. We find that in the presence of correlated or anticorrelated noise, the rate of decoherence is very sensitive to the initial two-qubit state, as well as to the symmetry of the Hamiltonian. In the absence of symmetry in the Hamiltonian, correlations only weakly impact the decoherence rate.
The arguments of Chapter 2, as well as of those of subsequent chapters, have as their foundation the formalism based on the state vector of a system of which the evolution is described by the Schrödinger equation. In fact, such an approach is badly suited to the case in which the coupling between an atom and its environment (for example through collisions with other atoms or spontaneous emission into formerly empty modes of the electromagnetic field) cannot be neglected. If the correlations induced by these interactions between the atom and its environment do not concern us and we are only interested in the evolution of the atom, the formalism of the density matrix must be employed. This provides a description at all times of the state of the atom, although a state vector for the atom alone cannot be defined. In this formalism the effect of the environment on the atom is accounted for by the introduction of suitable relaxation terms (Section 2C.1) in the equation of evolution of the density matrix. An important application of the density matrix is to the case of a two-level atomic system for which the relaxation terms lead to its deexcitation to a level of lower energy. We shall show that in this case the density matrix can be represented by a vector, known as the Bloch vector , which will allow us to give simple geometrical pictures of the evolution of the system.