Open quantum system dynamics traditionally described by a quantum master equation can be effectively reformulated in the Liouville space of vectorised density matrices. Despite an extensive use of the Liouville space framework to describe quantum states evolution, its application to quantum metrology is not well explored. Several papers have studied a Liouville-space generalisation of the quantum Fisher information, called the dissipative quantum Fisher information (DQFI). We perform a comparative study between the quantum Fisher information (QFI) in Hilbert space and DQFI, deriving an explicit relation between the two quantities for qubit, qudit, and harmonic oscillator systems. The derived relations are nontrivial, and depend on the state's purity. We show that for a single qubit, the QFI can be efficiently recovered from the DQFI via a simple mapping, while in higher dimensions the expression becomes convoluted and does not convert to a compact form. We find examples where the DQFI is neither an upper nor lower bound for the Hilbert space QFI, and suggest that the informational content of the DQFI itself cannot be straightforwardly interpreted. Our results clarify the limitations of the Liouville space based approach and structural differences with the QFI in the context of quantum parameter estimation problem.
Open quantum system dynamics traditionally described by a quantum master equation can be effectively reformulated in the Liouville space of vectorised density matrices. Despite an extensive use of the Liouville space framework to describe quantum states evolution, its application to quantum metrology is not well explored. Several papers have studied a Liouville-space generalisation of the quantum Fisher information, called the dissipative quantum Fisher information (DQFI). We perform a comparative study between the quantum Fisher information (QFI) in Hilbert space and DQFI, deriving an explicit relation between the two quantities for qubit, qudit, and harmonic oscillator systems. The derived relations are nontrivial, and depend on the state's purity. We show that for a single qubit, the QFI can be efficiently recovered from the DQFI via a simple mapping, while in higher dimensions the expression becomes convoluted and does not convert to a compact form. We find examples where the DQFI is neither an upper nor lower bound for the Hilbert space QFI, and suggest that the informational content of the DQFI itself cannot be straightforwardly interpreted. Our results clarify the limitations of the Liouville space based approach and structural differences with the QFI in the context of quantum parameter estimation problem.
In this thesis, I focus on the quantum Fisher information (QFI) - a central quantity in parameter estimation theory for quantum systems, which provides a lower bound on the precision one can achieve. In the first part of the thesis, I explore a Lie algebraic approach to evaluate the quantum Fisher information for unitary dynamics. I show how the Lie algebra associated with the unitary evolution, together with the initial state, allows one to compute various quantities of interest, circumventing the computation of the time-evolved state. In particular, I apply this shortcut approach to calculate the QFI and use it for the QFI evaluation in various prototype models, both finiteand infinite-dimensional. In the second part of the thesis, I shift focus to non-unitary dynamics, such as those described by a quantum master equation. In this setting, I theoretically study the description of open system dynamics in the Liouville space of vectorized density matrices and investigate the so-called dissipative quantum Fisher information (DQFI) within that framework. Specifically, I demonstrate how the metric defined in Liouville space differs from its counterpart in Hilbert space. I establish a map between the Hilbert space QFI and the Liouville dissipative quantum Fisher information for qubit and qudit systems, expressed via the quantum state’s purity. Furthermore, I discuss the physical meaning of the DQFI by studying its behavior under completely positive trace-preserving (CPTP) maps. The present results demonstrate that the Lie algebraic approach provides a computationally efficient framework for the QFI evaluation. This approach allows to avoid the explicit solution of quantum dynamics, and remains well-defined in cases when conventional approaches like WeiNorman expansion exhibit singularities.
The dissipative quantum Fisher information (DQFI) for a dynamic map with a general parameter in an open quantum system is investigated, which can be regarded as an analog of the quantum Fisher information (QFI) in the Liouville space. We first derive a general dissipative generator in the Liouville space, and based on its decomposition form, find the DQFI stems from two parts. One is the dependence of eigenvalues of the Liouvillian supermatrix on the estimated parameter, which shows a linear dependence on time. The other is the variation of the eigenvectors with the estimated parameter. The relationship between this part and time presents rich characteristics, including harmonic oscillation, pure exponential gain and attenuation, as well as exponential gain and attenuation of oscillatory type, which depend specifically on the properties of the Liouville spectrum. This is in contrast to that of the conventional generator, where only oscillatory dependencies are seen. Further, we illustrate the theory through a toy model: a two-level system with spin-flip noise. Especially, by using the DQFI, we demonstrated that the exceptional estimation precision cannot be obtained at the Liouvillian exceptional point.
Quantum Fisher information (QFI) quantifies the sensitivity of a quantum state to a parameter change and plays a key role in quantum metrology. Meanwhile, quantum coherence is a crucial resource for quantum information processing. However, despite extensive studies on various aspects of quantum metrology, the interplay between the dynamics of the QFI and quantum coherence remains unexplored. Here, we explore the factorization relationship between the QFI and quantum coherence, both theoretically and experimentally. We prepare pure states in qubit and qutrit systems and apply unitary evolution to investigate this relationship. Our results confirm the factorization law, offering strong evidence for this relationship. Furthermore, we establish a lower bound on the variance of the estimated parameter that does not require the final state information. This approach reveals a deep connection between the QFI and quantum coherence, providing insights into quantum parameter estimation. These findings have potential applications in quantum sensing and quantum metrology.
The dissipative quantum Fisher information (DQFI) for a dynamic map with a general parameter in an open quantum system is investigated, which can be regarded as an analog of the quantum Fisher information in the Liouville space. We first derive a general dissipative generator in the Liouville space, and based on its decomposition form, find the DQFI stems from two parts. One is the dependence of eigenvalues of the Liouvillian supermatrix on the estimated parameter, which shows a linear dependence on time. The other is the variation of the eigenvectors with the estimated parameter. The relationship between this part and time presents rich characteristics, including harmonic oscillation, pure exponential gain and attenuation, as well as exponential gain and attenuation of oscillatory type, which depend specifically on the properties of the Liouville spectrum. This is in contrast to that of the conventional generator, where only oscillatory dependencies are seen. Particularly, we find that the nonunitary parameter encoding process induced by the dissipative generator can be transformed into two unitary encoding processes plus the contribution of the commutator between the two. Further, we illustrate the theory through a toy model: a two-level system with spin-flip noise. Especially, by using the DQFI, we demonstrated that the exceptional estimation precision cannot be obtained for this model at the Liouvillian exceptional point.
In estimating an unknown parameter of a quantum state the quantum Fisher information (QFI) is a pivotal quantity, which depends on the state and its derivate with respect to the unknown parameter. We prove the continuity property for the QFI in the sense that two close states with close first derivatives have close QFIs. This property is completely general and irrespective of dynamics or how states acquire their parameter dependence and also the form of parameter dependence---indeed this continuity is basically a feature of the classical Fisher information that in the case of the QFI naturally carries over from the manifold of probability distributions onto the manifold of density matrices. We demonstrate that, in the special case where the dependence of the states on the unknown parameter comes from one dynamical map (quantum channel), the continuity holds in its reduced form with respect to the initial states. In addition, we show that, when one initial state evolves through two different quantum channels, the continuity relation applies in its general form. A situation in which such a scenario can occur is an open-system metrology where one of the maps represents the ideal dynamics, whereas the other map represents the real (noisy) dynamics. In the making of our main result, we also introduce a regularized representation for the symmetric logarithmic derivative which works for general states even with incomplete rank, and it features continuity similar to the QFI.
The fundamental metrological limits of temperature sensing in open quantum systems remain largely unresolved, particularly regarding the role of non-Gaussian quantum resources. In this letter, we establish analytic bounds on the quantum Fisher information (QFI) for temperature estimation using non-Gaussian states undergoing dissipative bosonic evolution. By focusing on the short-time regime governed by a time-local master equation, we derive precise scaling laws that elucidate when and how non-Gaussian probes decisively outperform Gaussian states under identical energy constraints. Our analysis uncovers a distinct linear-in-time QFI enhancement unique to Fock states, in contrast to the inherently weaker, quadratic scaling of Gaussian probes. These theoretical insights are substantiated through exact numerical simulations and mapped onto experimentally accessible platforms such as circuit QED. Our results not only clarify the quantum thermometric advantage of non-Gaussianity but also chart a realistic pathway toward harnessing it in noisy quantum technologies.