Coherence–Entropy Relation Beyond Markovianity in a Dephasing Qubit and Its Use
Humberto Arrabal
Abstract
We derive a closed-form relation between the von Neumann entropy rate and the coherence dynamicsof a qubit undergoing pure dephasing without assuming Markovianity. For fixed populations,the entropy rate is expressed solely in terms of the ℓ1-coherence and its time derivative. The Markovianexponential decay is recovered as a limiting case. In non-Markovian regimes, the relationpredicts intervals of negative entropy production associated with coherence revivals. In realisticquantum devices, deviations from the ideal relation provide a direct diagnostic of non-ideal dephasing,enabling detection and mitigation of noise and relaxation effects from coherence measurementsalone.