In the spin-first approach to learning quantum mechanics, students explore the 2-state spin Hilbert space before proceeding to wavefunctions and the related infinite-dimensional state space. In this note, we suggest a strategy to help students make this conceptual leap. Approximating continuous space with a finite number of locations, we construct a setting where students' intuition from spin space carries over to a position basis. We derive the position basis representations of the momentum and kinetic energy operators, solve simple bound state problems, and consider limitations to the discrete representation of position.
In the spin-first approach to learning quantum mechanics, students explore the 2-state spin Hilbert space before proceeding to wavefunctions and the related infinite-dimensional state space. In this note, we suggest a strategy to help students make this conceptual leap. Approximating continuous space with a finite number of locations, we construct a setting where students' intuition from spin space carries over to a position basis. We derive the position basis representations of the momentum and kinetic energy operators, solve simple bound state problems, and consider limitations to the discrete representation of position.
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend
This article is a ‘‘sampler,’’ which shows how quantum mechanics may be presented to students in a way that makes apparent how natural quantum mechanics is as a description of the world. The mathematical machinery of Hilbert space, the idea of representing observables by operators, the Schrödinger equation, and the position-momentum uncertainty relation all follow from natural assumptions that students can readily accept. The basic ideas of quantum mechanics are developed from intuitive first principles to the point where one can connect with more traditional treatments of quantum mechanics.
Continuous degrees of freedom The quantum systems we have discussed so far have been described by finite-dimensional Hilbert spaces. Basic measurements on such systems have a finite number of possible outcomes, and a quantum state predicts a discrete probability distribution over these. Now we wish to extend our theory to handle systems with one or more continuous degrees of freedom, such as the position of a particle that can move in one dimension. This will require an extension of our theory to Hilbert spaces of infinite dimension, and to systems with continuous observables. There is a philosophical issue here. How do we know that there really are infinitely many distinct locations for a particle? The short answer is, we don't. It might be that space itself is both discrete (at the tiniest scales) and bounded (at the largest), so that the number of possible locations of a particle is some very large but finite number. If this is the case, then the continuum model for space is nothing more than a convenient approximation. Infinity is just a simplified way of describing a quantity that is immense, but still finite. In this section, we will adopt this view of infinity. We will imagine that any continuous variable is really an approximation of a “true” discrete variable. This idea will motivate the continuous quantities and operations that we need.
In the Paradigms in Physics Curriculum at Oregon State University, we take a spins-first approach to quantum mechanics using a java simulation of successive Stern-Gerlach experiments to explore the postulates. The experimental schematic is a diagrammatic representation that we use throughout our discussion of quantum measurements. With a spins-first approach, it is natural to start with Dirac bra-ket language for states, observables, and projection operators. We also use explicit matrix representations of operators and ask students to translate between the Dirac and matrix languages. The projection of the state onto a basis is represented with a histogram. When we subsequently introduce wave functions, the wave function attains a natural interpretation as the continuous limit of these discrete histograms or a projection of a Dirac ket onto position or momentum eigenstates. We are able to test the students' facility with moving between these representations in later modules.
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation: There are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be the subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. This latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system.