One of the most intriguing quantum phenomena of light is the wave–particle duality which is related to the inability of the classical wave and particle concepts to fully describe the behavior of quantum objects. Theoretically, the wave features of the electromagnetic field, such as interference, follow from the solution of Maxwell's equations while particle features are a consequence of the field quantization, in which the electromagnetic field is described to consist of discrete energy packets, photons. Due to the wave–particle duality, for example, simultaneous description of optical absorption, emission, and interference of propagating fields has conventionally not been considered feasible using local optical models but has required using Maxwell's equations with stochastic source terms accounting for the wave–particle duality. Also the description of the momentum of light in a medium has been problematic. In the research described in this thesis, the quantized fluctuational electrodynamics (QFED) model is derived based on combining the electromagnetic Green's functions to the field quantization to describe the position dependence of the photon number and local thermal balance in general non-equilibrium conditions, and to separate the electromagnetic field into parts propagating in different directions in resonant structures, which has conventionally been problematic due to interference effects. The QFED method is shown to resolve the previously found anomalies in the canonical commutation relations of photon ladder operators. The QFED method is also used to derive quantum optical field–matter interaction parameters fully capturing the interference, emission, damping, and scattering of propagating photons in stratified media leading to an interference-exact radiative transfer equation (RTE) model. Therefore, the derived interaction parameters solve the problem of simultaneously describing interference and losses in the widely used RTE framework. The particle aspects of light are also studied by directly applying the conservation laws of nature and the special theory of relativity to show that light propagating in a medium must be described as mass-polariton (MP) quasiparticles, covariant coupled states of the field and matter. These quasiparticles are shown to have momentum of the Minkowski form and a nonzero mass that is carried by a mass density wave associated with light. The field–matter interaction related to the MP quasiparticles also leads to the dissipation of photon energy. These particle model results are also derived using a wave-based optoelastic continuum dynamics (OCD) approach following from the electrodynamics of continuous media and the continuum mechanics. The obtained results verify the full agreement between the wave and particle models when they are correctly applied. The key finding that a light pulse propagating in a medium is inevitably associated with an experimentally measurable mass implies a fundamental change in the prevailing perceptions of light.
One of the most intriguing quantum phenomena of light is the wave–particle duality which is related to the inability of the classical wave and particle concepts to fully describe the behavior of quantum objects. Theoretically, the wave features of the electromagnetic field, such as interference, follow from the solution of Maxwell's equations while particle features are a consequence of the field quantization, in which the electromagnetic field is described to consist of discrete energy packets, photons. Due to the wave–particle duality, for example, simultaneous description of optical absorption, emission, and interference of propagating fields has conventionally not been considered feasible using local optical models but has required using Maxwell's equations with stochastic source terms accounting for the wave–particle duality. Also the description of the momentum of light in a medium has been problematic. In the research described in this thesis, the quantized fluctuational electrodynamics (QFED) model is derived based on combining the electromagnetic Green's functions to the field quantization to describe the position dependence of the photon number and local thermal balance in general non-equilibrium conditions, and to separate the electromagnetic field into parts propagating in different directions in resonant structures, which has conventionally been problematic due to interference effects. The QFED method is shown to resolve the previously found anomalies in the canonical commutation relations of photon ladder operators. The QFED method is also used to derive quantum optical field–matter interaction parameters fully capturing the interference, emission, damping, and scattering of propagating photons in stratified media leading to an interference-exact radiative transfer equation (RTE) model. Therefore, the derived interaction parameters solve the problem of simultaneously describing interference and losses in the widely used RTE framework. The particle aspects of light are also studied by directly applying the conservation laws of nature and the special theory of relativity to show that light propagating in a medium must be described as mass-polariton (MP) quasiparticles, covariant coupled states of the field and matter. These quasiparticles are shown to have momentum of the Minkowski form and a nonzero mass that is carried by a mass density wave associated with light. The field–matter interaction related to the MP quasiparticles also leads to the dissipation of photon energy. These particle model results are also derived using a wave-based optoelastic continuum dynamics (OCD) approach following from the electrodynamics of continuous media and the continuum mechanics. The obtained results verify the full agreement between the wave and particle models when they are correctly applied. The key finding that a light pulse propagating in a medium is inevitably associated with an experimentally measurable mass implies a fundamental change in the prevailing perceptions of light.
One of the most intriguing quantum phenomena of light is the wave–particle duality which is related to the inability of the classical wave and particle concepts to fully describe the behavior of quantum objects. Theoretically, the wave features of the electromagnetic field, such as interference, follow from the solution of Maxwell's equations while particle features are a consequence of the field quantization, in which the electromagnetic field is described to consist of discrete energy packets, photons. Due to the wave–particle duality, for example, simultaneous description of optical absorption, emission, and interference of propagating fields has conventionally not been considered feasible using local optical models but has required using Maxwell's equations with stochastic source terms accounting for the wave–particle duality. Also the description of the momentum of light in a medium has been problematic.
In the research described in this thesis, the quantized fluctuational electrodynamics (QFED) model is derived based on combining the electromagnetic Green's functions to the field quantization to describe the position dependence of the photon number and local thermal balance in general non-equilibrium conditions, and to separate the electromagnetic field into parts propagating in different directions in resonant structures, which has conventionally been problematic due to interference effects. The QFED method is shown to resolve the previously found anomalies in the canonical commutation relations of photon ladder operators. The QFED method is also used to derive quantum optical field–matter interaction parameters fully capturing the interference, emission, damping, and scattering of propagating photons in stratified media leading to an interference-exact radiative transfer equation (RTE) model. Therefore, the derived interaction parameters solve the problem of simultaneously describing interference and losses in the widely used RTE framework.
The particle aspects of light are also studied by directly applying the conservation laws of nature and the special theory of relativity to show that light propagating in a medium must be described as mass-polariton (MP) quasiparticles, covariant coupled states of the field and matter. These quasiparticles are shown to have momentum of the Minkowski form and a nonzero mass that is carried by a mass density wave associated with light. The field–matter interaction related to the MP quasiparticles also leads to the dissipation of photon energy. These particle model results are also derived using a wave-based optoelastic continuum dynamics (OCD) approach following from the electrodynamics of continuous media and the continuum mechanics. The obtained results verify the full agreement between the wave and particle models when they are correctly applied. The key finding that a light pulse propagating in a medium is inevitably associated with an experimentally measurable mass implies a fundamental change in the prevailing perceptions of light.; Eras kiehtovimmista valon…
We have recently developed a quantized fluctuational electrodynamics (QFED) formalism to describe the quantum aspects of local thermal balance formation and to formulate the electromagnetic field ladder operators so that they no longer exhibit the anomalies reported for resonant structures. Here we show how the QFED can be used to resolve between the left and right propagating fields to bridge the QFED and the quantum optical input-output relations commonly used to describe selected quantum aspects of resonators. The generalized model introduces a density of states concept describing interference effects, which is instrumental in allowing an unambiguous separation of the fields and related quantum operators into left and right propagating parts. In addition to providing insight on the quantum treatment of interference, our results also provide the conclusive resolution of the long-standing enigma of the anomalous commutation relations of partially confined propagating fields.
At the conceptual level, the quantization procedure replaces the pure particle description of classical mechanics by a particle-wave treatment satisfying the requirements of the fundamental wave–particle dualism. Technically, one can always start from a generalized wave equation and use it as a basis to discuss wave-front propagation in the form of rays following classical particle trajectories, see Sections 2.2.1 and 3.1. Consequently, any wave theory inherently contains that aspect of the wave–particle dualism. Especially, Maxwell's equations of electrodynamic theory include both wave and particle aspects of electromagnetic fields. Hence, it could be that there are no additional “quantum,” i.e., wave–particle dualistic aspects. However, as we discuss in this chapter, Maxwell's equations can be expressed in the framework of Hamilton's formulation of particle mechanics. This then suggests that in addition to the approximate ray-like behavior, electromagnetic fields do have a supplementary level of particle-like properties. Due to the fundamental axiom of wave–particle dualism, the additional particle-like aspects of electromagnetic fields must then also have a wave counterpart that can be axiomatically introduced via the canonical quantization scheme described in Section 3.2.3. Since the spatial dependency in Maxwell's equation contains wave–particle dualism already at the classical level, it is clear that the new level of quantization cannot be a simple real-space feature but has to involve some other space describing the structure of the electromagnetic fields. In fact, this quantization yields several very concrete implications such as quantization of the light energy, elementary fluctuations in the light-field amplitude and intensity, and more.
Classical, semi-classical, and quantum-field descriptions for the interaction of light with matter are systematically discussed. Applications of interest include precise determinations of the linear and the non-linear electromagnetic response relevant to resonant pump-probe optical phenomena, such as electromagnetically induced transparency. In the quantum-mechanical description of matter systems, we introduce a general reduced-density-matrix framework. Time-domain (equation-of-motion) and frequency-domain (resolvent-operator) formulations are developed in a unified and self-consistent manner, using a Liouville-space operator representation. A preliminary semi-classical perturbation treatment of the electromagnetic interaction is adopted, in which the electromagnetic field is described as a classical field satisfying the Maxwell equations. Compact Liouville-space operator expressions are derived for the linear and the general (nth order) non-linear electromagnetic-response tensors describing moving many-electron systems. The tetradic matrix elements of the Liouville-space self-energy operators, which are introduced in the time-domain and frequency-domain formulations, are evaluated for environmental collisional and radiative interactions, in order to provide explicit forms for the quantum kinetic equations and the spectral-line shape formulas. It is emphasized that a quantized-field approach is essential for a fully self-consistent quantum-mechanical description of the interacting light-matter system.
Thus far, we have developed the properties of the electromagnetic field at optical frequencies, based on Maxwell’s equations. These equations further give a classical macroscopic perspective on the coupling of the propagation media to the field, as presented in Chapter 2. The macroscopic properties of a medium are based on averaged microscopic properties. The microscopic energy structure of matter was presented in Chapter 3, covering gases, solids, and liquids by employing mostly quantum models. We now proceed to the next level of development, the dynamic description of the interaction between the optical field and the propagation medium as a function of the field frequency and propagation media variables (e.g., energy structure, temperature, and pressure). In this chapter, the classical electromagnetic field is coupled to discrete frequency oscillators via Newton’s equation of motion. This approach leads to the popular classical oscillator model, often presented in introductory books on lasers. The classical oscillator model is an incomplete theory and can be only a semiempirical model. In the next chapter, a more detailed and comprehensive approach, which also includes statistical and quantum mechanics, is used leading to robust semiclassical and quantum oscillator models. This chapter and the next are the basis for the applied models presented in Part II of this book. Classical electrodynamics is based on Maxwell’s equations, as given in Chapter 2, and the Lorentz force relation, as given below: . . . F = q[E + (v × B)]. (4.1) . . . These equations cover the classical description of the interaction of light and matter. The first term in Eq. 4.1 represents coupling of the electric field to the medium. As discussed in Chapter 2 (Section 2.2), the leading mechanism for this is the electric dipole moment. To see that this is the coupling mechanism in the first term, consider the potential function driving this force, F = −∇V(r) = −∇(−qr · E). The above expression contains the dipole moment, as defined in Chapter 2. The second term in Eq. 4.1 represents coupling of the magnetic field to the medium.
In this introductory chapter we focus on the interaction of optical fields with matter because it forms the basis of signal amplification in all optical amplifiers. According to our present understanding, optical fields are made of photons with properties precisely described by the laws of quantum field theory [1]. One consequence of this wave–particle duality is that optical fields can be described, in certain cases, as electromagnetic waves using Maxwell's equations and, in other cases, as a stream of massless particles (photons) such that each photon contains an energy h ν, where h is the Planck constant and ν, is the frequency of the optical field. In the case of monochromatic light, it is easy to relate the number of photons contained in an electromagnetic field to its associated energy density. However, this becomes difficult for optical fields that have broad spectral features, unless full statistical features of the signal are known [2]. Fortunately, in most cases that we deal with, such a detailed knowledge of photon statistics is not necessary or even required [3, 4]. Both the linear and the nonlinear optical studies carried out during the last century have shown us convincingly that a theoretical understanding of experimental observations can be gained just by using wave features of the optical fields if they are intense enough to contain more than a few photons [5]. It is this semiclassical approach that we adopt in this book. In cases where such a description is not adequate, one could supplement the wave picture with a quantum description.