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McGill Science Undergraduate Research Journal

Time-independent perturbation theory: degeneracy lifted to the second order

Juan Álvarez Ruiz, Meijian Li

Published Apr 10, 2026• 0 citations
Publisher

Abstract

Although the fundamental principles of time-independent perturbation theory are well-established and widely applied, the specific treatment of degeneracy lifted to the second order remains largely unexplored. This work fills the gap by presenting a systematic derivation of time-independent perturbation theory that accounts for the added complexity introduced by non-trivial degeneracies. We provide a general procedure and corresponding formulae for calculating state and energy corrections to any order, with degeneracy lifted to the second order. Additionally, we apply these formulae to solve a prototype problem of the dressed quark system. This work not only advances the theoretical framework but also provides practical tools for tackling complex problems in quantum physics.

DOI
10.26443/msurj.v21i1.302

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Although the fundamental principles of time-independent perturbation theory are well-established and widely applied, the specific treatment of degeneracy lifted to the second order remains largely unexplored. This work fills the gap by presenting a systematic derivation of time-independent perturbation theory that accounts for the added complexity introduced by non-trivial degeneracies. We provide a general procedure and corresponding formulae for calculating state and energy corrections to any order, with degeneracy lifted to the second order. Additionally, we apply these formulae to solve a prototype problem of the dressed quark system. This work not only advances the theoretical framework but also provides practical tools for tackling complex problems in quantum physics.
Exactly solvable models in quantum mechanics are very rare.However, perturbation theory is a powerful tool to research the complex quantum systems and is widely used in theoretical physics and chemistry.For the particle weakly perturbed by the surrounding environment, its energy eigenstate and eigenvalue are separately calculated up to the first-order and second-order perturbation approximations in the undergraduate textbook of quantum mechanics.Whereas in reality, we have to calculate the high-order perturbation correction terms occasionally.Along the same lines of the low-order perturbation correction terms of energy eigenvalues and eigenstate for stationary state perturbation theory in the non-degenerate case, the third-order and fourth-order perturbation correction terms are strictly attained in this paper.Moreover, it points out the essence of perturbation theory and provides its derivation ideas.Students are no longer afraid of tedious derivation and can derive any-order perturbation correction.These results can serve as an extension and supplement for the quantum mechanics textbooks.Furthermore, it is very helpful for students to deeply understand quantum perturbation theory.
Abstract Quantum perturbation is an important tool for developing approximate solutions to quantum problems that cannot be solved exactly. This chapter provides a brief, systematic development of both time-independent and time-dependent quantum perturbation theory and the physical interpretation of its results, including both first- and second-order corrections. A quartic perturbation of the simple harmonic oscillator is used to illustrate time-independent perturbation theory. A spin-1/2 system subject to an oscillating field is used in time-dependent perturbation theory to describe the absorption and emission of energy from the quantum system.
Rayleigh-Schrödinger time-independent perturbation theory is a key method in quantum mechanics for solving problems where the Hamiltonian of a quantum system cannot be exactly solved. By expanding the solutions in series, this method allows one to obtain approximations for quantum states and eigen-energies, especially for systems where the interactions or perturbing forces are small compared to the principal part of the Hamiltonian. This is crucial for understanding complex phenomena, predicting the behaviours of atomic and molecular systems, and calculating corrections to basic theoretical models, thereby improving the accuracy of quantum predictions. In this work, we will show that using the unitary operators, we arrive at the equations giving the different order of corrections of both energy as well as wave functions of the time-independent perturbation theory. Our approach closely mirrors the famous formalism of Rayleigh-Schrodinger perturbation theory (RSPT). The use of unitary operators simplifies the derivation of higher-order corrections, making the process more accurate and accessible to researchers. This technique harnesses the potential of unitary operators within a perturbation series framework. By combining these two powerful techniques, we offer a comprehensive framework for addressing normalization challenges in quantum mechanical calculations. This methodology not only facilitates a deeper understanding of perturbation theory but also serves as a pedagogical stepping stone, encouraging postgraduate researchers to apply their foundational knowledge and acquired skills in practical problem-solving situations with confidence. This is therefore a second proof or a new method to derive the fundamental equations of Rayleigh Schrodinger perturbation Theory RSPT using the unitary transformations.
Abstract In this chapter we review time-independent and time-dependent perturbation theory in quantum mechanics. We begin with Rayleigh-Schrödinger perturbation theory for small corrections to the Hamiltonian for non-degenerate and degenerate spectra, which leads us to a discussion of avoided crossings. We then apply these methods to calculate the fine-structure corrections for the energy levels of the hydrogen atom, including the relativistic correction to the kinetic energy, the spin-orbit correction, and the Darwin term. We then turn to the effect of weak constant magnetic fields: for the resulting Zeeman effect we distinguish between the anomalous Zeeman effect and the Paschen-Back effect. In the context of the corresponding Stark effect for electric fields we introduce the Wigner-Eckart theorem and calculate perturbations to first and second order. We then turn to time-independent problems and discuss the Born-von Neumann series for the propagator, time-ordered integrals, the interaction picture, before explaining Fermi’s golden rule.
In many situations in physics, the Hamiltonian of a given system is so complicated that the solution to the stationary Schrodinger equation is practically impossible or very difficult. Therefore, some approximation methods are required. This chapter presents the time-independent perturbation theory, the procedure of finding corrections to non-degenerate eigenvalues and eigenvectors to a part of the Hamiltonian of a given system. The perturbation theory is appropriate when the Hamiltonian can be split into two parts. The perturbation theory can be applied to analyze the quantum properties of particles trapped in two closely coupled potential wells. By closely coupled wells, it is meant that these two wells are separated by a barrier. This is a typical situation in the studies of quantum dynamics of Bose–Einstein condensates. Using the first-order perturbation theory, one can find the eigenvalues and eigenvectors.