This thesis explores the development and application of laser-cooled mercury atoms for precision measurements relevant to fundamental physics. A primary motivation is the search for a permanent electric dipole moment in mercury, that could shed light on the baryon asymmetry of the universe. We present the design and construction of a custom experimental apparatus for producing and trapping cold mercury atoms, detailing challenges associated with working with mercury in an ultra-high vacuum environment and considering deep-ultraviolet optics. A magneto-optical trap operating on the 1S0-3P1 intercombination line at 254 nm is realized for all seven stable isotopes, achieving atom numbers up to 5x107 and phase-space densities up to 1x10-6 suitable for optical dipole trap loading. Cooling efficiency for all bosonic and fermionic isotopes are characterized over a wide parameter space, and we show sub-Doppler cooling in 199Hg and 201Hg. The successful loading of mercury into a high-power optical dipole trap is demonstrated, forming the basis for future electric dipole moment experiments of laser cooled mercury atoms. Prospects of evaporatively cooling mercury down to quantum degeneracy could allow for a quantum-enhanced metrology tool kit for the planned measurements. Apart from this, we are exploring the use of ultracold fermionic gases made of mercury as a quantum simulator for impurity physics. As a promising versatile and tunable platform for studying impurity-bath interactions, we are assessing the feasibility of observing Friedel oscillations in ultracold quantum gases.Further, we perform precision isotope shift spectroscopy on several dipole-allowed atomic transitions in mercury. Via King plot analysis this allows investigations of the mercury nuclear structure – also relevant for electric dipole moment bounds – and lays the foundation for probing a potential fifth force carrier coupling electrons to neutrons. We also propose upgrades to the machine for improvements in laser cooling, extensions of the spectroscopy search and a proposed experimental setup for probing the atomic electric dipole moment in an optical dipole trap of cold mercury atoms.
This thesis explores the development and application of laser-cooled mercury atoms for precision measurements relevant to fundamental physics. A primary motivation is the search for a permanent electric dipole moment in mercury, that could shed light on the baryon asymmetry of the universe. We present the design and construction of a custom experimental apparatus for producing and trapping cold mercury atoms, detailing challenges associated with working with mercury in an ultra-high vacuum environment and considering deep-ultraviolet optics. A magneto-optical trap operating on the 1S0-3P1 intercombination line at 254 nm is realized for all seven stable isotopes, achieving atom numbers up to 5x107 and phase-space densities up to 1x10-6 suitable for optical dipole trap loading. Cooling efficiency for all bosonic and fermionic isotopes are characterized over a wide parameter space, and we show sub-Doppler cooling in 199Hg and 201Hg. The successful loading of mercury into a high-power optical dipole trap is demonstrated, forming the basis for future electric dipole moment experiments of laser cooled mercury atoms. Prospects of evaporatively cooling mercury down to quantum degeneracy could allow for a quantum-enhanced metrology tool kit for the planned measurements. Apart from this, we are exploring the use of ultracold fermionic gases made of mercury as a quantum simulator for impurity physics. As a promising versatile and tunable platform for studying impurity-bath interactions, we are assessing the feasibility of observing Friedel oscillations in ultracold quantum gases.Further, we perform precision isotope shift spectroscopy on several dipole-allowed atomic transitions in mercury. Via King plot analysis this allows investigations of the mercury nuclear structure – also relevant for electric dipole moment bounds – and lays the foundation for probing a potential fifth force carrier coupling electrons to neutrons. We also propose upgrades to the machine for improvements in laser cooling, extensions of the spectroscopy search and a proposed experimental setup for probing the atomic electric dipole moment in an optical dipole trap of cold mercury atoms.
Mercury is the heaviest stable atom that could be laser cooled, and have a large nuclear charge number. So it has a distinct advantage in quantum precision measurement such as fine-structure constant α and permanent electric dipole moment. Due to its insensitivity of black body radiation, atomic mercury is a good candidate of optical clock. Here we report our recent development of laser cooling of neutral mercury atom. By cooling the mercury source to about -70°C, an ultra-high vacuum system was realized to produce ultracold mercury atoms. The commercial frequency quadrupled semiconductor laser is locked on the cooling transition (1S0-3P1 transition, wavelength of 253.7 nm) by sub-Doppler frequency modulation spectroscopy. By the modification with feed-forward method, the UV laser becomes faster tunable and more stable. A folded beam configuration was used to realize the magneto-optical trap (MOT) because of the shortage of cooling laser power, and the ultracold mercury atoms were observed by fluorescence detection. All of six rich abundant isotopes have been observed, and the atom number is about 1.5×106 with density of 3.5×109 /cm3 for 202Hg. With optical shutter and the programmable system to control the time sequence, the temperature of ultracold atoms can be measured by time of flight method. To enhance the laser power, a 1014.8 nm fiber laser amplifier was developed, which can work at room temperature. After two stages of frequency doubling, about 75 mW of 253.7 nm UV laser were generated, and the saturated absorption spectroscopy of mercury atom was also observed. More power of UV laser could help to trap more atoms in the future. These works laid a good foundation to realize the mercury lattice clock.
We present a realization of a magneto-optical trap of mercury atoms on the $^{1}S_{0}\ensuremath{\rightarrow}^{3}P_{1}$ intercombination line. We report on trapping of all stable mercury isotopes. We characterize the effect of laser detuning, laser intensity, and gradient field on the trapping performance of our system. The atom number for the most abundant isotope 202Hg is $5\ifmmode\times\else\texttimes\fi{}{10}^{7}$ atoms. Moreover, we study the difference in cooling processes for bosonic and fermionic isotopes. We observe agreement with the Doppler cooling theory for the bosonic species and show sub-Doppler cooling for the fermionic species. We reach a phase-space density of a few parts in ${10}^{\ensuremath{-}7}$, which constitutes a promising starting condition for dipole trap loading and evaporative cooling.
This thesis presents the development of an experimental apparatus designed to investigate the ultracold collisional properties for mixtures of Cs and Yb, with a long-term view to the creation of ultracold CsYb molecules via indirect cooling methods. The unpaired electron spin that is inherent to molecules of this form gives rise to a magnetic dipole moment in addition to a ground state electric dipole moment. This enables extra control over molecular interactions and should enable the experimental simulation of spin lattice models. We focus on the implementation of a system designed to controllably laser cool and optically trap Yb. The first step in this system is the production of a magneto-optical trap (MOT) on the triplet 1S0 to 3P1 transition of Yb. With careful control over the cooling beam detunings and power, gravitational-assisted Doppler cooling allows samples of Yb to be prepared at 22 uK. This regime of enhanced Doppler cooling is investigated and proves to be a crucial step to ensuring good transfer of cold Yb to optical traps. The construction and characterisation of single and crossed beam optical dipole traps for Yb are discussed. The single beam optical trap has been used to verify a model for the optical trapping of Yb in its ground state. This trap has also been utilised as a tool for the measurement of the light shift on the 1S0 to 3P1 transition at a wavelength of 1070~nm. In the main experimental sequence, Yb atoms are loaded from the magneto-optical trap into the crossed optical dipole trap, allowing evaporative cooling ramps to quantum degeneracy to be performed. This highly-reproducible system typically forms Bose-Einstein condensates with 2 x 10^5 174Yb atoms. This thesis additionally reports on the progress made towards measurements of the interspecies scattering length for 133Cs and Yb isotopes. We present two approaches that are being developed in tandem: rethermalisation in a conservative trap, and two-photon photoassociation. Progress towards rethermalisation measurements has focussed on developing systems for the efficient transfer of Cs to an optical trap. For photoassociative measurements, a laser system has been developed and tested by producing one-photon photoassociation spectra of Cs2.
Simulating highly correlated quantum systems with classical computers exceed their capa- bilities as the system size increases. In analog quantum simulators, the system of interest is mimicked by another quantum system in a highly controllable and accessible environ- ment. Even though quantum simulations with ultracold atoms have been demonstrated successfully, ultra-low temperature regimes are experimentally challenging to achieve and still remain to be explored. New approaches to realizing ever lower temperatures, especially in Fermi systems, have been and continue to be a constant pursuit in Atomic, Molecular, and Optical Physics (AMO). Within this thesis, a new quantum gas experiment of fermionic 6Li and bosonic 166Er is presented and first results on sympathetic cooling of Li to quantum degeneracy by Er are demonstrated. The experimental apparatus is described in detail with a focus on the Li subsystem of the dual-species experiment. Standard and further developed laser cooling techniques used to produce a Magneto-Optical Trap (MOT) of Li are characterized, along with their associated vacuum system stages. In this context, a combined Optical Pumping / Transversal Cooling (OP/TC) technique of the atomic beam on the D1-line is presented, and an enhancement of the MOT loading rate by one order of magnitude is demonstrated. The architecture and building blocks of the laser system for providing resonant light at 671 nm for laser cooling of Li are detailed, and laser locking techniques for frequency stabilization and light amplification by injection locking of high-power laser diodes are presented. Special focus is placed on the introduction and characterization of a new laser- diode-independent injection locking technique, keeping spectrally pure amplified light by a periodic slave current optimization routine executed by a microcontroller. The system has been submitted for patent approval. In further steps of optical cooling of Li, a non-standard free-space Gray Molasses (GM) technique based on intensity ramps, providing temperatures as low as 13 µK, is presented. The non-standard technique is characterized and compared to the standard pulse GM approach, which typically achieves 50 µK only. Cooling steps for preparing an ultracold Li cloud in the glass cell start from an Optical Dipole Trap (ODT) loaded by a compressed Magneto-Optical Trap (cMOT) and consecutive evaporation into a 1D transport lattice of counter propagating 1064 nm laser beams. By detuning one of the lattice beams, optical transport over 1 m to the glass cell with an efficiency of 74% is demonstrated. In a combined ErLi sequence, the two species are transported to the glass cell together and loaded to 1064 nm ODTs. Sympathetic cooling of Li by forced evaporation of Er to T/TF = 0.77 ± 0.10 next to the production of an Er BEC are presented. To conclude, this work introduces a new promising dual-species quantum gas experiment and its ability for providing sympathetic cooling of Li by Er to quantum degeneracy is demon- strated. These findings are an encouraging foundation for achieving higher degeneracies by refined experimental control in pursuit of penetrating unexplored temperature regimes in quantum simulators.
Ultracold polar molecules have emerged as promising platforms for quantum simulation, quantum information science, precision measurements of fundamental symmetry violations, and quantum chemistry. Over the past decade, rapid progress in direct laser cooling of molecules has enabled new capabilities such as magneto-optical traps (MOTs), sub-Doppler cooling, and optical dipole traps (ODTs), expanding the quantum toolbox with ultracold molecules of complex internal structures and strong dipolar interactions. This thesis presents the design, construction, and operation of an experiment on ultracold strontium monofluoride (88Sr19F) molecules, demonstrating state-of-the-art techniques for molecular laser cooling and trapping. The apparatus integrates a broad range of technical sub-systems, including cryogenics, ultra-high vacuum, optics, electronics, and automated laboratory control software. SrF molecules produced in a slowed cryogenic buffer gas beam are captured into a dual-frequency MOT. Subsequent Λ-enhanced gray molasses cooling reduces the molecule temperature to as low as 5 μK. A novel blue-detuned MOT is also implemented to further compress the molecular cloud, increasing the density by a factor of ∼ 400. At this high density, SrF molecules are efficiently loaded into an ODT, a tight, conservative trap with long lifetimes. Population transfer between different rotational levels is achieved via optical pumping and coherent microwave control, yielding ∼ 0.8 ms coherence time in Rabi oscillation and ∼ 90 % transfer efficiency. This thesis also describes the development of an ultracold rubidium (87Rb) atom experiment, in which a loading rate of ∼ 10^10 atoms/s into a radio-frequency (RF) MOT is demonstrated. A modular two-dimensional MOT serves as the Rb source and can be seamlessly integrated into the SrF apparatus, opening the possibility for future studies of co-trapping and sympathetic cooling of SrF molecules with atoms. The results presented in this thesis establish an experimental foundation for exploring new frontiers in ultracold molecular physics.
Ultracold mixture experiments hold the promise of providing new insights into many-body quantum systems as well as ultracold chemistry and few-body phenomena. The work presented in this thesis dealt with the construction of a new apparatus for the production and study of ultracold gases of fermionic lithium-6 and bosonic caesium-133. These isotopes offer a wide tunability in their interaction strength, both in inter-species and intra-species collisions, through magnetic Feshbach resonances. Additionally, the widely different resonance frequencies of lithium and caesium enables independent control of each of the species. With this apparatus, Bose-Einstein condensates (BEC) containing 10^4 lithium Feshbach molecules are routinely produced. The cooling system for caesium has been developed in parallel and important steps towards producing ultracold caesium gases have been made. An optical dipole trap has been loaded with 2x10^6 caesium atoms and evaporative cooling towards quantum degeneracy can now be pursued. Laser, vacuum, magnetic and control systems have been developed for the implementation of this experiment. Light produced with this laser system was used to laser cool atoms, create conservative dipole traps as well as to provide means of imaging atomic clouds. Additionally, a system to produce strong magnetic fields of up to 1400 G has been established in order to exploit the wide tunability in the atomic interactions. Software that was developed for the computerised control system facilitated the coordination of all the components involved in the experimental sequence. Measurements and calculations that showcase the functionality of relevant parts of the setup are presented in this thesis. In this experiment, lithium and caesium atoms are obtained from a novel type of Zeeman slower and are loaded into a magneto-optical trap (MOT). The system is capable of doing this independently for each of the atomic species as well as sequentially. After the MOT has been loaded with atoms, they are transferred into a conservative far-off-resonance optical dipole trap. By adjusting the interactions between atoms and lowering the depth of the dipole trap, efficient evaporative cooling of lithium was carried out from which a molecular BEC was obtained. Time-of-flight measurements were used to characterise the condensate and study its expansion dynamics.