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Journal of Research in Science and Engineering

Dynamics of Two-Body Systems

Twisha Choudhary

Published Mar 27, 2026• 0 citations
Publisher

Abstract

This study presents a comprehensive analysis of the two-body central-interaction problem in quantum mechanics. We investigate the Schrödinger equation for two particles interacting through a central potential, and derive the radial and angular parts of the wave function. The energy eigenvalues and Eigen functions are obtained for various central potentials, including the Coulomb, harmonic oscillator, and square well potentials.

DOI
10.53469/jrse.2026.08(03).02

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This study presents a comprehensive analysis of the two-body central-interaction problem in quantum mechanics. We investigate the Schrödinger equation for two particles interacting through a central potential, and derive the radial and angular parts of the wave function. The energy eigenvalues and Eigen functions are obtained for various central potentials, including the Coulomb, harmonic oscillator, and square well potentials.
The quantum mechanical two-body problem is analyzed. Separating the center of mass from the relative motion Hamiltonian and focusing on “central potentials,” the stationary Schrödinger equation for the relative motion in spherical coordinates is split into radial and angular equations. The universal angular equation is identified as the eigenvalue equation of the angular momentum operator, whose proper solutions are the spherical harmonics. For fixed interparticle distance, the two-body system is mapped on a “rigid rotor” Hamiltonian, whose eigenstates coincide with the angular momentum eigenstates. In diatomic molecules, timescale separation between fast vibrations (radial motion) and slow rotations (angular motion) enables one to invoke a rigid rotor approximation for interpreting rotational absorption spectrum in the microwave regime. Deviations from the predictions of the rigid rotor model and their manifestation in experiments are analyzed by explicit solution of the stationary Schrödinger equation for two particles in the presence of vibration–rotation coupling.
This chapter presents a detailed examination of a number of relatively simple problems pertaining to the scattering and bound states of two structureless particles interacting through a central field. It describes the spectrum of the angular momentum operators by a method that does not refer at all to the structure of the system. The spherical harmonics are the eigenfunctions appropriate to a single particle that can be described by the three classical degrees of freedom, or for a pair of such particles in their center-of-mass frame. The formulation of collision theory that is based on the one-body Schrodinger equation with a Hermitian interaction. The chapter introduces and discusses the observables pertaining to the two-body problem and explores the eigenvalues and eigenfunctions of these observables. Since the degeneracies of the energy spectrum are a consequence of the symmetries of the Hamiltonian, they can be determined experimentally by destroying this symmetry.
Part 1: the need for the quantum mechanics quantization of radiation the special theory of relativity wave-particle duality the nature of matter waves the uncertainty principle the Bohr atom. Part 2 Schrodinger's equation: the postulates of quantum mechanics the wave equation the wave equation in three dimensions the time-independent Schrodinger equation stationary states normalisation probability flux physical constraints on the wave-function wave packets Gaussian wave-packets and the uncertainty principle. Part 3 One-dimensional potential wells: potential wells the one-dimensional infinite square well discussion of infinite square-well results eigenvalue equations the finite square well finite square well eigenfunctions the control of the wave-function by the wave equation numerical integration of Schrodinger's equation continuum solutions of the square-well potential interpretation of unbound-particle wave functions the double potential well the quantum bouncer electric fields and the tilted well the harmonic oscillator - introduction the quantum oscillator discussion of harmonic oscillator eigenvalues and eigenfunctions the classical probability density more potential wells. Part 4 Schrodinger's equation in three dimensions: particle in a three dimensional box degeneracy Schrodingers equation in spherical polar coordinates - the hydrogen atom normalisation. Part 5 Formal development of quantum mechanics: eigenvalues equations, operators and measurements the momentum operator, eigenvalues and eigenfunctions the position operator and its eigenfunctions Hermitian operators orthogonality of eigenfunctions the expansion postulate example - the b-decay of tritium expectation values compatibility of observables - commutators non-commuting operators time-dependence of expectation values - Ehrenfest's theorem abstract operators - the parity operator, matrix mechanics. Part 6 Angular momentum: angular momentum operators angular momentum commutators angular momentum eigenvalues and eigenfunctions interpretation of angular momentum eigenvalues interpretation of angular momentum eigenfunctions the Stern-Gerlach apparatus and electron spin spin operators - the Pauli Spin matrices the Zeeman effect measurements in quantum mechanics. Part 7 Spherically symmetric potential wells: the rigid rotator the radial equation the hydrogen atom and hydrogen like ions the isotropic harmonic oscillator molecular vibrations - the Morse potential the spherical square well general properties of spherically symmetric potential wells. (Part contents)
We extend a method previously presented for the three-body problem with attractive interparticle potentials to the case of repulsive interparticle potentials, with periodic boundary conditions on each particle. As before, we decompose the wave function into three parts, and from the Schrödinger equation write equations for these parts. We observe that, in one-dimension and for δ-function potentials,these equations can be easily solved numerically, and we present these solutions for potential“strengths” ranging from zero to infinity. We then discuss a more general method for solving these equations, which method involves expansions in a certain set of two-body functions. This general method is not necessarily limited to either one dimension or δ-function potentials, but, as a check on it, we do apply it to that case and get good agreement with the previous numerical results. As a further exploration of the method, we apply it to square well potentials in one dimension. In an Appendix we discuss the set of two-body functions that we use.